A Hf-doped dual-phase high-entropy alloy: phase evolution and wear features
Initially defined high entropy alloys (HEAs) usually exhibit a single-phase solid-solution structure. However, two and/or more types of phases in HEAs possibly induce the desired microstructure features, which contribute to improving the wear properties of HEAs. Here, we prepare a series of (AlCoCrF...
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| Published in | Rare metals Vol. 43; no. 1; pp. 324 - 333 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Beijing
Nonferrous Metals Society of China
01.01.2024
Springer Nature B.V |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1001-0521 1867-7185 |
| DOI | 10.1007/s12598-023-02410-0 |
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| Abstract | Initially defined high entropy alloys (HEAs) usually exhibit a single-phase solid-solution structure. However, two and/or more types of phases in HEAs possibly induce the desired microstructure features, which contribute to improving the wear properties of HEAs. Here, we prepare a series of (AlCoCrFeNi)
100−
x
Hf
x
(
x
= 0, 2, 4 and 6; at%) HEAs and concern their phase compositions, microstructures and wear properties. Hf leads to the formation of (Ni, Co)
2
Hf-type Laves phase and tailors the microstructure from a body-centered cubic (BCC) single-phase structure to a hypoeutectic structure. An increased hardness from ~ HV 512.3 to ~ HV 734.1 is due to solid-solution strengthening, grain refinement strengthening and precipitated phase strengthening. And a few oxides (Al
2
O
3
+ Cr
2
O
3
) caused by the wear heating contribute to an 85.5% decrease in wear rate of the HEA system from 6.71 × 10
−5
to 0.97 × 10
−5
m
3
·N
−1
·m
−1
. In addition, Hf addition changes the wear mechanism from abrasive wear, mild oxidative wear and adhesive wear to oxidative wear and adhesive wear. |
|---|---|
| AbstractList | Initially defined high entropy alloys (HEAs) usually exhibit a single-phase solid-solution structure. However, two and/or more types of phases in HEAs possibly induce the desired microstructure features, which contribute to improving the wear properties of HEAs. Here, we prepare a series of (AlCoCrFeNi)
100−
x
Hf
x
(
x
= 0, 2, 4 and 6; at%) HEAs and concern their phase compositions, microstructures and wear properties. Hf leads to the formation of (Ni, Co)
2
Hf-type Laves phase and tailors the microstructure from a body-centered cubic (BCC) single-phase structure to a hypoeutectic structure. An increased hardness from ~ HV 512.3 to ~ HV 734.1 is due to solid-solution strengthening, grain refinement strengthening and precipitated phase strengthening. And a few oxides (Al
2
O
3
+ Cr
2
O
3
) caused by the wear heating contribute to an 85.5% decrease in wear rate of the HEA system from 6.71 × 10
−5
to 0.97 × 10
−5
m
3
·N
−1
·m
−1
. In addition, Hf addition changes the wear mechanism from abrasive wear, mild oxidative wear and adhesive wear to oxidative wear and adhesive wear. Initially defined high entropy alloys (HEAs) usually exhibit a single-phase solid-solution structure. However, two and/or more types of phases in HEAs possibly induce the desired microstructure features, which contribute to improving the wear properties of HEAs. Here, we prepare a series of (AlCoCrFeNi)100−xHfx (x = 0, 2, 4 and 6; at%) HEAs and concern their phase compositions, microstructures and wear properties. Hf leads to the formation of (Ni, Co)2Hf-type Laves phase and tailors the microstructure from a body-centered cubic (BCC) single-phase structure to a hypoeutectic structure. An increased hardness from ~ HV 512.3 to ~ HV 734.1 is due to solid-solution strengthening, grain refinement strengthening and precipitated phase strengthening. And a few oxides (Al2O3 + Cr2O3) caused by the wear heating contribute to an 85.5% decrease in wear rate of the HEA system from 6.71 × 10−5 to 0.97 × 10−5 m3·N−1·m−1. In addition, Hf addition changes the wear mechanism from abrasive wear, mild oxidative wear and adhesive wear to oxidative wear and adhesive wear. |
| Author | Ren, Hao Chiu, Yu-Lung Gao, Xue-Feng Qin, Gang Liu, Tong Wu, Shi-Ping Chen, Rui-Run Guo, Jing-Jie |
| Author_xml | – sequence: 1 givenname: Hao surname: Ren fullname: Ren, Hao organization: National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology – sequence: 2 givenname: Rui-Run orcidid: 0000-0003-3695-997X surname: Chen fullname: Chen, Rui-Run email: ruirunchen@hit.edu.cn organization: National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology – sequence: 3 givenname: Xue-Feng surname: Gao fullname: Gao, Xue-Feng organization: National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology – sequence: 4 givenname: Tong surname: Liu fullname: Liu, Tong organization: National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology – sequence: 5 givenname: Gang surname: Qin fullname: Qin, Gang organization: National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology – sequence: 6 givenname: Yu-Lung surname: Chiu fullname: Chiu, Yu-Lung organization: School of Metallurgy and Materials, University of Birmingham – sequence: 7 givenname: Shi-Ping surname: Wu fullname: Wu, Shi-Ping organization: National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology – sequence: 8 givenname: Jing-Jie surname: Guo fullname: Guo, Jing-Jie organization: National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology |
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| Keywords | Wear mechanism High entropy alloy Hardness Laves phase |
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| SubjectTerms | Abrasive wear Adhesive wear Aluminum oxide Biomaterials Chemistry and Materials Science Energy Grain refinement High entropy alloys Hypoeutectic structures Laves phase Materials Engineering Materials Science Metallic Materials Microstructure Nanoscale Science and Technology Original Article Phase composition Physical Chemistry Solid phases Solid solutions Solution strengthening Wear mechanisms Wear rate |
| Title | A Hf-doped dual-phase high-entropy alloy: phase evolution and wear features |
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