Analysis of proton irradiation products in simulated intersteller dusts by mass spectrometry
It is known that various kinds of organic compounds exist in space. In order to study the possibility of the formation of organic compounds in comets or their precursory bodies (intersteller dust grains), ice mixtures of carbon monoxide (or methane), ammonia and water made in a cryostat at 10 K (&qu...
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| Published in | BUNSEKI KAGAKU Vol. 45; no. 6; pp. 569 - 574 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English Japanese |
| Published |
Tokyo
The Japan Society for Analytical Chemistry
1996
Japan Science and Technology Agency |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0525-1931 |
| DOI | 10.2116/bunsekikagaku.45.569 |
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| Abstract | It is known that various kinds of organic compounds exist in space. In order to study the possibility of the formation of organic compounds in comets or their precursory bodies (intersteller dust grains), ice mixtures of carbon monoxide (or methane), ammonia and water made in a cryostat at 10 K ("simulated cometary ices") were irradiated with high energy protons. Irradiated ice products were warmed up to room temperature, while sublimed gases were analyzed with a quadrupole mass spectrometer. Some hydrocarbons and alcohols were detected. "Amino acid precursors" (compounds yielding amino acids after hydrolysis) were detected in non-volatile products remaining on the substrate at room temperature. These results suggest the possible formation of organic compounds in interstellar dust grains by cosmic radiation. |
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| AbstractList | It is known that various kinds of organic compounds exist in space. In order to study the possibility of the formation of organic compounds in comets or their precursory bodies (intersteller dust grains), ice mixtures of carbon monoxide (or methane), ammonia and water made in a cryostat at 10 K ("simulated cometary ices") were irradiated with high energy protons. Irradiated ice products were warmed up to room temperature, while sublimed gases were analyzed with a quadrupole mass spectrometer. Some hydrocarbons and alcohols were detected. "Amino acid precursors" (compounds yielding amino acids after hydrolysis) were detected in non-volatile products remaining on the substrate at room temperature. These results suggest the possible formation of organic compounds in interstellar dust grains by cosmic radiation. |
| Author | KANEKO, Takeo KOBAYASHI, Kensei TSUCHIYA, Masahiko KASAMATSU, Takashi |
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| References_xml | – reference: 7) J. M. Greenberg, C. X. Mendoza-Gomez : "The Chemistry of Life's Origins", Edited by J. M. Greenberg, C. X. Mendoza-Gomez, V. Pirronello, p. 1 (1993), (Kluwer Academic, Dordrecht). – reference: 1) 小林憲正 : 分析化学(Bunseki Kagaku), 投稿中. – reference: 5) J. Kissel, F. R. Krueger : Nature (London), 326,755 (1987). – reference: 3) 山本智 : ぶんせき(Bunseki), 1995,381. – reference: 2) G. Carle, D. Schwartz, J. Huntington (Ed.) : NASA SP, 512, (1992). – reference: 14) K. Hiraoka, N. Ohashi, Y. Kihara, K. Yamamoto, T. Sato, A. Yamashita : Chem. Phys. Lett., 229,408 (1994). – reference: 4) 香内晃 : 日本惑星科学会誌, 3, 94 (1994). – reference: 10) K. Kobayashi, T. Kaneko, T. Kobayashi, Li Hui, M. Tsuchiya, T. Saito, T. Oshima : Anal. Sci., 7 (supplment), 921 (1991). – reference: 15) 齋藤進, 笠松隆志, 青木暢宏, 小原雅典, 金子竹男, 土屋正彦, 小林憲正 : 第54回分析化学討論会講演要旨集, p. 661 (1993). – reference: 9) G. Strazzulla, V. Pirronello, G. Foti : Astron. Astrophys., 123, 93 (1983). – reference: 8) V. Pirronello, G. Strazzulla, G. Foti, W. L. Brown, L. J. Lanzerotti : Astron. Astrophys., 134,204 (1984). – reference: 6) M. H. Moore, B. Donn, R. Khanna, M. F. A, Hearn : Icarus, 54,388 (1983). – reference: 12) 小田稔, 西村純, 桜井邦朋 : "宇宙線物理学", p. 24 (1983), (朝倉書店). – reference: 13) 日本化学会編 : "化学便覧基礎編II", 改訂4版, p. 117 (1993), (丸善). – reference: 11) 桜井邦明, 清水幹夫 : "彗星-その本性と起源-", (1989), (朝倉書店). |
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| SubjectTerms | comets interstellar dust grains MS origins of life proton irradiation |
| Title | Analysis of proton irradiation products in simulated intersteller dusts by mass spectrometry |
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