Stress effects on the kinetics of hydrogen adsorption in a spherical particle: An analytical model
We consider a two-phase elastic solid subject to diffusion-induced phase transformation by interstitial hydrogen. We derive a simple analytical model to quantify the effect of misfit strain on the kinetic of phase transformation and to calculate the amplitude of the well-know hysteresis cycle observ...
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| Published in | International journal of hydrogen energy Vol. 40; no. 47; pp. 17009 - 17016 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
21.12.2015
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0360-3199 1879-3487 |
| DOI | 10.1016/j.ijhydene.2015.07.088 |
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| Abstract | We consider a two-phase elastic solid subject to diffusion-induced phase transformation by interstitial hydrogen. We derive a simple analytical model to quantify the effect of misfit strain on the kinetic of phase transformation and to calculate the amplitude of the well-know hysteresis cycle observed when a sequence of forward and reverse phase transformations takes place.
•We consider adsorption and desorption of interstitial hydrogen by a spherical particle.•The particle is modeled as a two-phase elastic solid partitioned by a sharp interface.•Elastic misfits are taken into account.•A differential equation governing the motion of the phase interface is derived.•A closed-form solution is obtained. |
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| AbstractList | We consider a two-phase elastic solid subject to diffusion-induced phase transformation by interstitial hydrogen. We derive a simple analytical model to quantify the effect of misfit strain on the kinetic of phase transformation and to calculate the amplitude of the well-know hysteresis cycle observed when a sequence of forward and reverse phase transformations takes place.
•We consider adsorption and desorption of interstitial hydrogen by a spherical particle.•The particle is modeled as a two-phase elastic solid partitioned by a sharp interface.•Elastic misfits are taken into account.•A differential equation governing the motion of the phase interface is derived.•A closed-form solution is obtained. |
| Author | Tomassetti, Giuseppe Duda, Fernando P. |
| Author_xml | – sequence: 1 givenname: Fernando P. surname: Duda fullname: Duda, Fernando P. email: duda@mecanica.coppe.ufrj.br organization: Programa de Engenharia Mecânica, COPPE, Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brazil – sequence: 2 givenname: Giuseppe orcidid: 0000-0001-8801-7461 surname: Tomassetti fullname: Tomassetti, Giuseppe email: tomassetti@ing.uniroma2.it organization: Università di Roma “Tor Vergata”, Dipartimento di Ingegneria Civile e Ingegneria Informatica, Via Politecnico 1, 00169, Italy |
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| Cites_doi | 10.1016/j.cplett.2010.01.071 10.1016/j.ijhydene.2008.06.070 10.3934/dcdsb.2014.19.2313 10.1038/nmat4086 10.1016/j.ijhydene.2009.08.088 10.1016/j.ijhydene.2014.01.125 10.1016/j.ijhydene.2006.11.022 10.1016/j.ijhydene.2011.03.167 10.1016/S0925-8388(97)00192-8 10.1023/A:1004535408168 10.1103/PhysRevLett.74.2523 10.1016/0001-6160(85)90077-X 10.1016/j.actamat.2010.05.030 10.1103/PhysRevLett.104.135502 10.1016/0001-6160(89)90185-5 10.1021/jp901552n 10.1063/1.3447868 10.1016/j.ijhydene.2013.11.085 10.1103/PhysRevB.84.052301 10.1016/0020-7683(86)90122-8 10.1557/JMR.1988.0257 10.1016/0022-5096(96)00014-2 10.1016/j.cplett.2010.04.012 10.1039/C4RA08089K 10.1016/0036-9748(89)90355-4 10.1007/s10659-006-9089-6 10.1016/0001-6160(82)90023-2 10.1023/A:1004587425006 10.1007/s00245-006-0862-5 10.1002/cphc.200800498 10.1016/j.ijhydene.2013.04.049 |
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| Snippet | We consider a two-phase elastic solid subject to diffusion-induced phase transformation by interstitial hydrogen. We derive a simple analytical model to... |
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| StartPage | 17009 |
| SubjectTerms | Hydrogen storage Hysteresis Nanoparticles Phase transformation Stress-assisted diffusion |
| Title | Stress effects on the kinetics of hydrogen adsorption in a spherical particle: An analytical model |
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| Volume | 40 |
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