Impact of charge-compensated Fe and Nb co-substitution on BaTiO3: Bandgap and grain size reduction and enhanced bulk photovoltaic power of Al/BFNT/Ag solar cell
•Al/BaTi1-2xFexNbxO3/Ag is an excellent bulk ferroelectric photovoltaic device configuration.•Increment of aliovalent Fe3+and Nb5+ionic substitutions reduces the bandgap of 0.075BFNT ceramics to ∼2.55 eV and broadens the visible spectrum absorption.•The photocurrent density of Al/0.075BFNT/Ag photov...
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          | Published in | Solar energy Vol. 257; pp. 34 - 44 | 
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| Main Authors | , , | 
| Format | Journal Article | 
| Language | English | 
| Published | 
            Elsevier Ltd
    
        01.06.2023
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| Subjects | |
| Online Access | Get full text | 
| ISSN | 0038-092X 1471-1257  | 
| DOI | 10.1016/j.solener.2023.03.058 | 
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| Abstract | •Al/BaTi1-2xFexNbxO3/Ag is an excellent bulk ferroelectric photovoltaic device configuration.•Increment of aliovalent Fe3+and Nb5+ionic substitutions reduces the bandgap of 0.075BFNT ceramics to ∼2.55 eV and broadens the visible spectrum absorption.•The photocurrent density of Al/0.075BFNT/Ag photovoltaic cell is about ∼ 2.2 times higher than that of pure BT.•A high photovoltaic power of ∼ 12 μW/cm2 was achieved.
The generation of above bandgap photovoltage using bulk ferroelectric materials has become a subject of great interest, however, their photocurrent density is limited by a broad bandgap and poor conductivity. To overcome this limitation, we replaced aliovalent metal ions (Fe3+and Nb5+)at the B-site of robust ferroelectric BaTiO3and fabricated an Al/BaTi1-2xFexNbxO3/Ag photovoltaic device. Both the experimental and the theoretical studies showed that bandgap was lowered to ∼2.55 eV and hence absorption of wide energy range of the solar spectrum was attained. An apt top electrode, reduced bandgap and domain size resulted in greater photocurrent density of 1.46 μA/cm2 and photovoltage of 8.31 V for Al/0.075BFNT/Ag solar cell in unpoled condition. This research suggest that reduced band gap, mixed structural phases and nano-sized domains suffices greatest PV power output while the large polarization and poling are not necessary prerequisites. | 
    
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| AbstractList | •Al/BaTi1-2xFexNbxO3/Ag is an excellent bulk ferroelectric photovoltaic device configuration.•Increment of aliovalent Fe3+and Nb5+ionic substitutions reduces the bandgap of 0.075BFNT ceramics to ∼2.55 eV and broadens the visible spectrum absorption.•The photocurrent density of Al/0.075BFNT/Ag photovoltaic cell is about ∼ 2.2 times higher than that of pure BT.•A high photovoltaic power of ∼ 12 μW/cm2 was achieved.
The generation of above bandgap photovoltage using bulk ferroelectric materials has become a subject of great interest, however, their photocurrent density is limited by a broad bandgap and poor conductivity. To overcome this limitation, we replaced aliovalent metal ions (Fe3+and Nb5+)at the B-site of robust ferroelectric BaTiO3and fabricated an Al/BaTi1-2xFexNbxO3/Ag photovoltaic device. Both the experimental and the theoretical studies showed that bandgap was lowered to ∼2.55 eV and hence absorption of wide energy range of the solar spectrum was attained. An apt top electrode, reduced bandgap and domain size resulted in greater photocurrent density of 1.46 μA/cm2 and photovoltage of 8.31 V for Al/0.075BFNT/Ag solar cell in unpoled condition. This research suggest that reduced band gap, mixed structural phases and nano-sized domains suffices greatest PV power output while the large polarization and poling are not necessary prerequisites. | 
    
| Author | Raja, N. Sundarakannan, B. Venkidu, L.  | 
    
| Author_xml | – sequence: 1 givenname: L. surname: Venkidu fullname: Venkidu, L. organization: Department of Physics, Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli 627012, Tamil Nadu, India – sequence: 2 givenname: N. surname: Raja fullname: Raja, N. organization: Department of Physics, Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli 627012, Tamil Nadu, India – sequence: 3 givenname: B. surname: Sundarakannan fullname: Sundarakannan, B. email: sundarakannan@msuniv.ac.in organization: Department of Physics, Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli 627012, Tamil Nadu, India  | 
    
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| Snippet | •Al/BaTi1-2xFexNbxO3/Ag is an excellent bulk ferroelectric photovoltaic device configuration.•Increment of aliovalent Fe3+and Nb5+ionic substitutions reduces... | 
    
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| SubjectTerms | Bandgap Ferroelectric photovoltaic Open circuit voltage Photocurrent  | 
    
| Title | Impact of charge-compensated Fe and Nb co-substitution on BaTiO3: Bandgap and grain size reduction and enhanced bulk photovoltaic power of Al/BFNT/Ag solar cell | 
    
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