Syntheses and Properties of Conjugated Polymers Containing Thieno[2,3‐b]indole with Different Electron‐deficient Units
New conjugated polymers using electron‐rich unit, thieno[2,3‐b]indole (2‐TI), and various electron‐deficient units were synthesized for the utilization in the photovoltaics. The synthesized polymers (PTIBTI, PTITPD, and PTIID) with various types of electron‐deficient units showed different electroni...
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| Published in | Bulletin of the Korean Chemical Society Vol. 40; no. 12; pp. 1208 - 1214 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley‐VCH Verlag GmbH & Co. KGaA
01.12.2019
대한화학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1229-5949 0253-2964 1229-5949 |
| DOI | 10.1002/bkcs.11902 |
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| Abstract | New conjugated polymers using electron‐rich unit, thieno[2,3‐b]indole (2‐TI), and various electron‐deficient units were synthesized for the utilization in the photovoltaics. The synthesized polymers (PTIBTI, PTITPD, and PTIID) with various types of electron‐deficient units showed different electronic structure and properties. The PTITPD provides the higher VOC through suitable energy level offset of LUMO (donor)‐LUMO (PC71BM) and improved JSC resulting from better crystallinity, charge carrier mobility and morphology, leading to the higher PCE value of OPV out of the series. This result illustrates that the combination of various electron‐deficient units affects the electronic structure, such as the HOMO/LUMO energy levels and bandgap in addition to the morphology and the carrier mobility, implying that variation of the electron‐deficient unit should be explored for the utilization of a given electron‐rich unit to produce the better performance of the device.
Different electronic structure and properties of synthesized polymers with various types of electron‐deficient units. |
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| AbstractList | New conjugated polymers using electron‐rich unit, thieno[2,3‐b]indole (2‐TI), and various electron‐deficient units were synthesized for the utilization in the photovoltaics. The synthesized polymers (
PTIBTI
,
PTITPD,
and
PTIID
) with various types of electron‐deficient units showed different electronic structure and properties. The
PTITPD
provides the higher
V
OC
through suitable energy level offset of LUMO (donor)‐LUMO (PC
71
BM) and improved
J
SC
resulting from better crystallinity, charge carrier mobility and morphology, leading to the higher PCE value of OPV out of the series. This result illustrates that the combination of various electron‐deficient units affects the electronic structure, such as the HOMO/LUMO energy levels and bandgap in addition to the morphology and the carrier mobility, implying that variation of the electron‐deficient unit should be explored for the utilization of a given electron‐rich unit to produce the better performance of the device. New conjugated polymers using electron-rich unit, thieno[2,3-b]indole (2-TI), and various electron-deficient units were synthesized for the utilization in the photovoltaics. The synthesized polymers (PTIBTI, PTITPD, and PTIID) with various types of electron-deficient units showed different electronic structure and properties. The PTITPD provides the higher VOC through suitable energy level offset of LUMO (donor)-LUMO (PC71BM) and improved JSC resulting from better crystallinity, charge carrier mobility and morphology, leading to the higher PCE value of OPV out of the series. This result illustrates that the combination of various electron-deficient units affects the electronic structure, such as the HOMO/LUMO energy levels and bandgap in addition to the morphology and the carrier mobility, implying that variation of the electron-deficient unit should be explored for the utilization of a given electron-rich unit to produce the better performance of the device. KCI Citation Count: 0 New conjugated polymers using electron‐rich unit, thieno[2,3‐b]indole (2‐TI), and various electron‐deficient units were synthesized for the utilization in the photovoltaics. The synthesized polymers (PTIBTI, PTITPD, and PTIID) with various types of electron‐deficient units showed different electronic structure and properties. The PTITPD provides the higher VOC through suitable energy level offset of LUMO (donor)‐LUMO (PC71BM) and improved JSC resulting from better crystallinity, charge carrier mobility and morphology, leading to the higher PCE value of OPV out of the series. This result illustrates that the combination of various electron‐deficient units affects the electronic structure, such as the HOMO/LUMO energy levels and bandgap in addition to the morphology and the carrier mobility, implying that variation of the electron‐deficient unit should be explored for the utilization of a given electron‐rich unit to produce the better performance of the device. Different electronic structure and properties of synthesized polymers with various types of electron‐deficient units. |
| Author | Lee, Sung Hun Chae, Sangmin Kim, Juae Suh, Hongsuk Kim, Hyo Jung Gu, Dasom Hong, Seungyeon |
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| Snippet | New conjugated polymers using electron‐rich unit, thieno[2,3‐b]indole (2‐TI), and various electron‐deficient units were synthesized for the utilization in the... New conjugated polymers using electron-rich unit, thieno[2,3-b]indole (2-TI), and various electron-deficient units were synthesized for the utilization in the... |
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| SubjectTerms | Electron‐deficient unit Organic solar cells (OSCs) Photovoltaic cells Polymer Thieno[2,3‐b]indole (2‐TI) 화학 |
| Title | Syntheses and Properties of Conjugated Polymers Containing Thieno[2,3‐b]indole with Different Electron‐deficient Units |
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