An overview of improving photocatalytic activity of MnO2 via the Z-scheme approach for environmental and energy applications

•Crystallographic, electronic, and photoelectric properties of MnO2 were explained.•Z-scheme e− transfer pathway in mno2-based composites is discussed with mechanism.•Environmental and energy applications of mno2-based composites are discussed.•Overview of prevailing challenges along with future per...

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Published inJournal of the Taiwan Institute of Chemical Engineers Vol. 158; p. 104945
Main Authors Malhotra, Monika, Poonia, Komal, Singh, Pardeep, Khan, Aftab Aslam Parwaz, Thakur, Pankaj, Van Le, Quyet, Helmy, Elsayed T., Ahamad, Tansir, Nguyen, Van-Huy, Thakur, Sourbh, Raizada, Pankaj
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2024
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ISSN1876-1070
DOI10.1016/j.jtice.2023.104945

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Abstract •Crystallographic, electronic, and photoelectric properties of MnO2 were explained.•Z-scheme e− transfer pathway in mno2-based composites is discussed with mechanism.•Environmental and energy applications of mno2-based composites are discussed.•Overview of prevailing challenges along with future perspectives. Rapid industrialization has triggered the proliferation of dyes and antibiotics in the water system in recent decades. Due to advantages like low cost, high catalytic efficiency, and the ability to exist in multiple valences, MnO2 as a photocatalyst has attracted more and more attention. This review covers recent progress on MnO2-based composites for photocatalytic properties obtained via the Z-scheme charge carrier mechanism. Firstly, the electronic, photoelectric, and crystallographic properties of MnO2 are highlighted, and the fabrication of heterojunctions by suitable band alignments following the Z-scheme electron transfer pathway. This article presents recent advances in MnO2-based nanomaterials, focusing on improving photocatalytic activity via the Z-scheme mechanism. Then a detailed discussion on various electron transfer pathways in MnO2-based composites offered a broader view by providing several characterization techniques to testify to the route of the Z-scheme mechanism. This review also provided a systematic summary of their applications in environmental (dye, antibiotics degradation) and energy (water splitting, CO2 reduction) applications. Although many efforts have been made, significant improvements are still required for photocatalysis. This work presents future perspectives for improving the efficacy of photocatalysts, followed by a conclusion. [Display omitted]
AbstractList •Crystallographic, electronic, and photoelectric properties of MnO2 were explained.•Z-scheme e− transfer pathway in mno2-based composites is discussed with mechanism.•Environmental and energy applications of mno2-based composites are discussed.•Overview of prevailing challenges along with future perspectives. Rapid industrialization has triggered the proliferation of dyes and antibiotics in the water system in recent decades. Due to advantages like low cost, high catalytic efficiency, and the ability to exist in multiple valences, MnO2 as a photocatalyst has attracted more and more attention. This review covers recent progress on MnO2-based composites for photocatalytic properties obtained via the Z-scheme charge carrier mechanism. Firstly, the electronic, photoelectric, and crystallographic properties of MnO2 are highlighted, and the fabrication of heterojunctions by suitable band alignments following the Z-scheme electron transfer pathway. This article presents recent advances in MnO2-based nanomaterials, focusing on improving photocatalytic activity via the Z-scheme mechanism. Then a detailed discussion on various electron transfer pathways in MnO2-based composites offered a broader view by providing several characterization techniques to testify to the route of the Z-scheme mechanism. This review also provided a systematic summary of their applications in environmental (dye, antibiotics degradation) and energy (water splitting, CO2 reduction) applications. Although many efforts have been made, significant improvements are still required for photocatalysis. This work presents future perspectives for improving the efficacy of photocatalysts, followed by a conclusion. [Display omitted]
ArticleNumber 104945
Author Van Le, Quyet
Malhotra, Monika
Helmy, Elsayed T.
Ahamad, Tansir
Khan, Aftab Aslam Parwaz
Singh, Pardeep
Nguyen, Van-Huy
Poonia, Komal
Thakur, Pankaj
Raizada, Pankaj
Thakur, Sourbh
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  givenname: Komal
  orcidid: 0000-0002-7081-1314
  surname: Poonia
  fullname: Poonia, Komal
  organization: School of Advanced Chemical Sciences, Shoolini University, Solan, Himachal Pradesh 173212, India
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  givenname: Pardeep
  surname: Singh
  fullname: Singh, Pardeep
  organization: School of Advanced Chemical Sciences, Shoolini University, Solan, Himachal Pradesh 173212, India
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  givenname: Aftab Aslam Parwaz
  orcidid: 0000-0002-3746-5034
  surname: Khan
  fullname: Khan, Aftab Aslam Parwaz
  organization: Center of Excellence for Advanced Materials Research, King Abdulaziz University, P. O. Box 80203, Jeddah 21589, Saudi Arabia
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  givenname: Pankaj
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  givenname: Quyet
  surname: Van Le
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  organization: Department of Materials Science and Engineering, Korea University, 145, Anam13 ro Seongbuk-su, Seoul 02841, South Korea
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  givenname: Elsayed T.
  orcidid: 0000-0003-2808-8959
  surname: Helmy
  fullname: Helmy, Elsayed T.
  organization: Environment Division, National Institute of Oceanography and Fisheries, KayetBey, Elanfoushy, Alexandria, Egypt
– sequence: 8
  givenname: Tansir
  surname: Ahamad
  fullname: Ahamad, Tansir
  organization: Department of Chemistry, College of Science, King Saud University, Saudi Arabia
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  givenname: Van-Huy
  orcidid: 0000-0001-8556-1955
  surname: Nguyen
  fullname: Nguyen, Van-Huy
  email: vhnguyen.ChE@gmail.com
  organization: Faculty of Allied Health Sciences, Chettinad Hospital and Research Institute, Chettinad Academy of Research and Education, Kelambakkam, Tamil Nadu 603103, India
– sequence: 10
  givenname: Sourbh
  orcidid: 0000-0001-9799-6921
  surname: Thakur
  fullname: Thakur, Sourbh
  organization: Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology, Silesian University of Technology, B. Krzywoustego 4, Gliwice 44-100, Poland
– sequence: 11
  givenname: Pankaj
  surname: Raizada
  fullname: Raizada, Pankaj
  email: pankajchem1@gmail.com
  organization: School of Advanced Chemical Sciences, Shoolini University, Solan, Himachal Pradesh 173212, India
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Environmental applications
Z-scheme
Energy applications
Photocatalysis
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Snippet •Crystallographic, electronic, and photoelectric properties of MnO2 were explained.•Z-scheme e− transfer pathway in mno2-based composites is discussed with...
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StartPage 104945
SubjectTerms Energy applications
Environmental applications
Manganese dioxide
Photocatalysis
Z-scheme
Title An overview of improving photocatalytic activity of MnO2 via the Z-scheme approach for environmental and energy applications
URI https://dx.doi.org/10.1016/j.jtice.2023.104945
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