An overview of improving photocatalytic activity of MnO2 via the Z-scheme approach for environmental and energy applications
•Crystallographic, electronic, and photoelectric properties of MnO2 were explained.•Z-scheme e− transfer pathway in mno2-based composites is discussed with mechanism.•Environmental and energy applications of mno2-based composites are discussed.•Overview of prevailing challenges along with future per...
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Published in | Journal of the Taiwan Institute of Chemical Engineers Vol. 158; p. 104945 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.05.2024
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Subjects | |
Online Access | Get full text |
ISSN | 1876-1070 |
DOI | 10.1016/j.jtice.2023.104945 |
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Abstract | •Crystallographic, electronic, and photoelectric properties of MnO2 were explained.•Z-scheme e− transfer pathway in mno2-based composites is discussed with mechanism.•Environmental and energy applications of mno2-based composites are discussed.•Overview of prevailing challenges along with future perspectives.
Rapid industrialization has triggered the proliferation of dyes and antibiotics in the water system in recent decades. Due to advantages like low cost, high catalytic efficiency, and the ability to exist in multiple valences, MnO2 as a photocatalyst has attracted more and more attention.
This review covers recent progress on MnO2-based composites for photocatalytic properties obtained via the Z-scheme charge carrier mechanism. Firstly, the electronic, photoelectric, and crystallographic properties of MnO2 are highlighted, and the fabrication of heterojunctions by suitable band alignments following the Z-scheme electron transfer pathway. This article presents recent advances in MnO2-based nanomaterials, focusing on improving photocatalytic activity via the Z-scheme mechanism. Then a detailed discussion on various electron transfer pathways in MnO2-based composites offered a broader view by providing several characterization techniques to testify to the route of the Z-scheme mechanism.
This review also provided a systematic summary of their applications in environmental (dye, antibiotics degradation) and energy (water splitting, CO2 reduction) applications. Although many efforts have been made, significant improvements are still required for photocatalysis. This work presents future perspectives for improving the efficacy of photocatalysts, followed by a conclusion.
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AbstractList | •Crystallographic, electronic, and photoelectric properties of MnO2 were explained.•Z-scheme e− transfer pathway in mno2-based composites is discussed with mechanism.•Environmental and energy applications of mno2-based composites are discussed.•Overview of prevailing challenges along with future perspectives.
Rapid industrialization has triggered the proliferation of dyes and antibiotics in the water system in recent decades. Due to advantages like low cost, high catalytic efficiency, and the ability to exist in multiple valences, MnO2 as a photocatalyst has attracted more and more attention.
This review covers recent progress on MnO2-based composites for photocatalytic properties obtained via the Z-scheme charge carrier mechanism. Firstly, the electronic, photoelectric, and crystallographic properties of MnO2 are highlighted, and the fabrication of heterojunctions by suitable band alignments following the Z-scheme electron transfer pathway. This article presents recent advances in MnO2-based nanomaterials, focusing on improving photocatalytic activity via the Z-scheme mechanism. Then a detailed discussion on various electron transfer pathways in MnO2-based composites offered a broader view by providing several characterization techniques to testify to the route of the Z-scheme mechanism.
This review also provided a systematic summary of their applications in environmental (dye, antibiotics degradation) and energy (water splitting, CO2 reduction) applications. Although many efforts have been made, significant improvements are still required for photocatalysis. This work presents future perspectives for improving the efficacy of photocatalysts, followed by a conclusion.
[Display omitted] |
ArticleNumber | 104945 |
Author | Van Le, Quyet Malhotra, Monika Helmy, Elsayed T. Ahamad, Tansir Khan, Aftab Aslam Parwaz Singh, Pardeep Nguyen, Van-Huy Poonia, Komal Thakur, Pankaj Raizada, Pankaj Thakur, Sourbh |
Author_xml | – sequence: 1 givenname: Monika surname: Malhotra fullname: Malhotra, Monika organization: School of Advanced Chemical Sciences, Shoolini University, Solan, Himachal Pradesh 173212, India – sequence: 2 givenname: Komal orcidid: 0000-0002-7081-1314 surname: Poonia fullname: Poonia, Komal organization: School of Advanced Chemical Sciences, Shoolini University, Solan, Himachal Pradesh 173212, India – sequence: 3 givenname: Pardeep surname: Singh fullname: Singh, Pardeep organization: School of Advanced Chemical Sciences, Shoolini University, Solan, Himachal Pradesh 173212, India – sequence: 4 givenname: Aftab Aslam Parwaz orcidid: 0000-0002-3746-5034 surname: Khan fullname: Khan, Aftab Aslam Parwaz organization: Center of Excellence for Advanced Materials Research, King Abdulaziz University, P. O. Box 80203, Jeddah 21589, Saudi Arabia – sequence: 5 givenname: Pankaj surname: Thakur fullname: Thakur, Pankaj organization: Special Centre For Nanoscience, Jawaharlal Nehru University New Delhi, Delhi 110067 India – sequence: 6 givenname: Quyet surname: Van Le fullname: Van Le, Quyet organization: Department of Materials Science and Engineering, Korea University, 145, Anam13 ro Seongbuk-su, Seoul 02841, South Korea – sequence: 7 givenname: Elsayed T. orcidid: 0000-0003-2808-8959 surname: Helmy fullname: Helmy, Elsayed T. organization: Environment Division, National Institute of Oceanography and Fisheries, KayetBey, Elanfoushy, Alexandria, Egypt – sequence: 8 givenname: Tansir surname: Ahamad fullname: Ahamad, Tansir organization: Department of Chemistry, College of Science, King Saud University, Saudi Arabia – sequence: 9 givenname: Van-Huy orcidid: 0000-0001-8556-1955 surname: Nguyen fullname: Nguyen, Van-Huy email: vhnguyen.ChE@gmail.com organization: Faculty of Allied Health Sciences, Chettinad Hospital and Research Institute, Chettinad Academy of Research and Education, Kelambakkam, Tamil Nadu 603103, India – sequence: 10 givenname: Sourbh orcidid: 0000-0001-9799-6921 surname: Thakur fullname: Thakur, Sourbh organization: Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology, Silesian University of Technology, B. Krzywoustego 4, Gliwice 44-100, Poland – sequence: 11 givenname: Pankaj surname: Raizada fullname: Raizada, Pankaj email: pankajchem1@gmail.com organization: School of Advanced Chemical Sciences, Shoolini University, Solan, Himachal Pradesh 173212, India |
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Snippet | •Crystallographic, electronic, and photoelectric properties of MnO2 were explained.•Z-scheme e− transfer pathway in mno2-based composites is discussed with... |
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Title | An overview of improving photocatalytic activity of MnO2 via the Z-scheme approach for environmental and energy applications |
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