In-situ investigation of shear force induced solution phase transformation of ABA-type tri-block copolymers
Interplay between self-assembly and phase behaviors for block copolymer under external force is one of the significant research directions in materials science. Rheo-small-angle neutron scattering (Rheo-SANS) is a powerful in situ tool that enables the investigation of this subject. Herein, we prese...
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| Published in | Colloid and interface science communications Vol. 67; p. 100839 |
|---|---|
| Main Authors | , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.07.2025
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| Online Access | Get full text |
| ISSN | 2215-0382 2215-0382 |
| DOI | 10.1016/j.colcom.2025.100839 |
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| Abstract | Interplay between self-assembly and phase behaviors for block copolymer under external force is one of the significant research directions in materials science. Rheo-small-angle neutron scattering (Rheo-SANS) is a powerful in situ tool that enables the investigation of this subject. Herein, we present the installation and commissioning of the Rheo-SANS instrument, in conjunction with an Anton-Paar MCR 302e rheometer, at the small-angle neutron scattering beamline (BL01) of the China Spallation Neutron Source (CSNS). We provide a detailed description of the design, construction and technical specifications of the Rheo-SANS instrument. Taking advantage of this newly built Rheo-SANS facility, we are able to investigate the phase transformation behavior of block copolymer under external shear force, which is otherwise impossible for traditional characterization methods. We demonstrate through Rheo-SANS experiment that for block copolymer with small packing parameter (Pluronic F127), shear force can cause orientation of the Hcp phase in solid-like state. While in liquid-like state, shear force hardly orients the system. On the contrary, for block copolymer with large packing parameter (Pluronic L64), shear force can easily cause orientation of the lamella phase in liquid-like state, while in solid-like state, much large shear force is needed to induce the orientation of the lamella phase.
[Display omitted]
•Block-copolymer with different packing parameter reacting differently under external Shear.•The most densely packed plane reorient along the flow direction under shear.•Using the self-established Rheo-SANS apparatus |
|---|---|
| AbstractList | Interplay between self-assembly and phase behaviors for block copolymer under external force is one of the significant research directions in materials science. Rheo-small-angle neutron scattering (Rheo-SANS) is a powerful in situ tool that enables the investigation of this subject. Herein, we present the installation and commissioning of the Rheo-SANS instrument, in conjunction with an Anton-Paar MCR 302e rheometer, at the small-angle neutron scattering beamline (BL01) of the China Spallation Neutron Source (CSNS). We provide a detailed description of the design, construction and technical specifications of the Rheo-SANS instrument. Taking advantage of this newly built Rheo-SANS facility, we are able to investigate the phase transformation behavior of block copolymer under external shear force, which is otherwise impossible for traditional characterization methods. We demonstrate through Rheo-SANS experiment that for block copolymer with small packing parameter (Pluronic F127), shear force can cause orientation of the Hcp phase in solid-like state. While in liquid-like state, shear force hardly orients the system. On the contrary, for block copolymer with large packing parameter (Pluronic L64), shear force can easily cause orientation of the lamella phase in liquid-like state, while in solid-like state, much large shear force is needed to induce the orientation of the lamella phase.
[Display omitted]
•Block-copolymer with different packing parameter reacting differently under external Shear.•The most densely packed plane reorient along the flow direction under shear.•Using the self-established Rheo-SANS apparatus |
| ArticleNumber | 100839 |
| Author | Sun, Haofeng Cheng, He Jiang, Hanqiu Wang, Jun Ke, Yubin Tong, Xin Yang, Hua Jiang, Naisheng Dou, Mengjia Xie, Zhenhua He, Chunyong Han, Zhijing Hu, Haitao |
| Author_xml | – sequence: 1 givenname: Jun surname: Wang fullname: Wang, Jun organization: School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China – sequence: 2 givenname: Haofeng surname: Sun fullname: Sun, Haofeng organization: School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China – sequence: 3 givenname: Zhijing surname: Han fullname: Han, Zhijing organization: School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China – sequence: 4 givenname: Mengjia surname: Dou fullname: Dou, Mengjia organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China – sequence: 5 givenname: Haitao surname: Hu fullname: Hu, Haitao organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China – sequence: 6 givenname: He surname: Cheng fullname: Cheng, He organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China – sequence: 7 givenname: Chunyong surname: He fullname: He, Chunyong organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China – sequence: 8 givenname: Zhenhua surname: Xie fullname: Xie, Zhenhua organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China – sequence: 9 givenname: Hanqiu surname: Jiang fullname: Jiang, Hanqiu organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China – sequence: 10 givenname: Naisheng surname: Jiang fullname: Jiang, Naisheng email: naishengjiang@ustb.edu.cn organization: School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China – sequence: 11 givenname: Xin surname: Tong fullname: Tong, Xin email: tongxin@ihep.ac.cn organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China – sequence: 12 givenname: Yubin surname: Ke fullname: Ke, Yubin email: keyb@ihep.ac.cn organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China – sequence: 13 givenname: Hua surname: Yang fullname: Yang, Hua organization: Spallation Neutron Source Science Center, Dongguan, Guangdong 523803, China |
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| Cites_doi | 10.1021/la700382y 10.1088/0953-8984/20/40/404207 10.1021/ma00046a049 10.1021/jp9730297 10.1002/syst.202100050 10.1021/ma062654j 10.1016/j.bpj.2008.12.3900 10.1021/la951506b 10.1039/b906256d 10.1016/0021-9797(82)90299-5 10.1021/jp9084525 10.3390/polym15020355 10.1039/c1sm05521f 10.1016/j.carbpol.2023.121281 10.1021/ma0508911 10.1016/0005-2736(75)90171-6 10.1016/j.cej.2018.01.062 10.1016/j.cocis.2011.12.001 10.1021/la802943d 10.1021/ma100476s 10.1038/nmat2446 10.1021/jp109333c 10.3390/molecules28217434 10.1039/C9SM01644A |
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| Keywords | Pluronic block copolymers Phase transformation Small-angle neutron scattering Rheo-SANS |
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| Title | In-situ investigation of shear force induced solution phase transformation of ABA-type tri-block copolymers |
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