Highly Efficient Electrocatalytic Carboxylation of 1-Phenylethyl Chloride at Cu Foam Cathode

A simple and efficient electrocatalytic carboxylation of benzyl chloride with CO2 is described. The reaction operates under 1 atm CO2 and room temperature in an undivided cell with Cu foam cathode and Mg sacrificial anode without any additional catalyst. For the model compound 1-phenylethyl chloride...

Full description

Saved in:
Bibliographic Details
Published inCatalysts Vol. 8; no. 7; p. 273
Main Authors Wu, La-Xia, Sun, Qi-Long, Yang, Man-Ping, Zhao, Ying-Guo, Guan, Ye-Bin, Wang, Huan, Lu, Jia-Xing
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 06.07.2018
Subjects
Acids
Carbon dioxide
Carboxylation
Catalysts
Cathodes
Charge density
Charge materials
Chemical reactions
Chloride
Chlorides
Electrode materials
Electrodes
Electrolysis
Metal foams
Noble metals
Room temperature
Sacrificial anodes
Silver
Online AccessGet full text
ISSN2073-4344
2073-4344
DOI10.3390/catal8070273

Cover

Abstract A simple and efficient electrocatalytic carboxylation of benzyl chloride with CO2 is described. The reaction operates under 1 atm CO2 and room temperature in an undivided cell with Cu foam cathode and Mg sacrificial anode without any additional catalyst. For the model compound 1-phenylethyl chloride, the influence of cathode material, solvent, charge, current density and temperature were investigated. Under optimized conditions, 99% yield of 2-phenylpropionic acid could be obtained. Moreover, reasonable yields were also achieved with other benzyl chlorides.
AbstractList A simple and efficient electrocatalytic carboxylation of benzyl chloride with CO2 is described. The reaction operates under 1 atm CO2 and room temperature in an undivided cell with Cu foam cathode and Mg sacrificial anode without any additional catalyst. For the model compound 1-phenylethyl chloride, the influence of cathode material, solvent, charge, current density and temperature were investigated. Under optimized conditions, 99% yield of 2-phenylpropionic acid could be obtained. Moreover, reasonable yields were also achieved with other benzyl chlorides.
A simple and efficient electrocatalytic carboxylation of benzyl chloride with CO2 is described. The reaction operates under 1 atm CO2 and room temperature in a single chamber electrolysis cell with Cu foam cathode and Mg sacrificial anode. No additional catalyst is needed, and noble metal is not necessary. The effects of cathode material, solvent current density, charge amount, and temperature were studied using 1-phenylethyl chloride as a model compound. Under optimal conditions, 99% yield of 2-phenylpropionic acid could be obtained. Moreover, reasonable yields were also achieved with other benzyl chlorides.
Author Guan, Ye-Bin
Wang, Huan
Sun, Qi-Long
Yang, Man-Ping
Zhao, Ying-Guo
Lu, Jia-Xing
Wu, La-Xia
Author_xml – sequence: 1
  givenname: La-Xia
  orcidid: 0000-0002-5291-8839
  surname: Wu
  fullname: Wu, La-Xia
– sequence: 2
  givenname: Qi-Long
  surname: Sun
  fullname: Sun, Qi-Long
– sequence: 3
  givenname: Man-Ping
  surname: Yang
  fullname: Yang, Man-Ping
– sequence: 4
  givenname: Ying-Guo
  surname: Zhao
  fullname: Zhao, Ying-Guo
– sequence: 5
  givenname: Ye-Bin
  surname: Guan
  fullname: Guan, Ye-Bin
– sequence: 6
  givenname: Huan
  surname: Wang
  fullname: Wang, Huan
– sequence: 7
  givenname: Jia-Xing
  surname: Lu
  fullname: Lu, Jia-Xing
BookMark eNptkEFLAzEQhYNUsNbe_AEBr65mkizJHmVprVDQg96EJZtN3JR0U7MpuP_etfVQxLnMHL73hvcu0aQLnUHoGsgdYwW51yopL4kgVLAzNKVEsIwzzicn9wWa9_2GjFMAk5BP0fvKfbR-wAtrnXamS3jhjU4xHOyG5DQuVazD1-BVcqHDwWLIXlrTDd6kdvC4bH2IrjFYJVzu8TKo7ShJbWjMFTq3yvdm_rtn6G25eC1X2fr58al8WGeaEUgZN7amRnCjgQsoSG2ZaDTnubREkrrmAJIbUIVlhBUs54zqhmumpKSC1orN0M3RdxfD5970qdqEfezGlxXNR6aQADBS9EjpGPo-Gltplw6hUlTOV0CqnyKr0yJH0e0f0S66rYrD__g3-xF2jQ
CitedBy_id crossref_primary_10_1002_nano_202000001
crossref_primary_10_1021_acssuschemeng_9b04647
crossref_primary_10_1016_j_coelec_2023_101254
crossref_primary_10_1002_aesr_202100001
crossref_primary_10_1016_j_greenca_2024_02_001
crossref_primary_10_1021_acscentsci_0c01532
Cites_doi 10.1016/j.jelechem.2009.02.013
10.1002/smll.201002331
10.1016/j.tet.2008.08.093
10.1002/ejoc.201701436
10.1016/j.electacta.2007.10.021
10.1021/acs.jpcc.8b01928
10.1021/jo047731s
10.1016/j.electacta.2015.01.072
10.1016/j.electacta.2010.09.020
10.1021/acsaem.8b00356
10.1039/C5RA19289G
10.1016/j.electacta.2004.10.047
10.1016/S1872-2067(15)61075-0
10.1002/anie.201308341
10.1039/C5TA09321J
10.1016/j.apcatb.2014.04.023
10.1016/j.jelechem.2008.07.021
10.1016/0022-0728(90)87217-8
10.1016/j.elecom.2011.08.049
10.1016/S0022-0728(02)01418-3
10.1016/S1003-6326(15)64049-3
10.1002/anie.200704782
10.1016/j.electacta.2006.01.039
10.3390/catal7090274
10.3762/bjoc.10.260
10.1002/anie.200900667
10.1016/j.elecom.2014.02.009
10.1016/S0040-4039(00)98538-1
10.1016/j.jelechem.2005.04.007
10.1039/b206746c
10.1016/j.elecom.2010.06.027
10.1002/cssc.201301131
10.1039/C8CC00969D
10.1021/acs.chemrev.7b00435
ContentType Journal Article
Copyright 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
Copyright_xml – notice: 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
DBID AAYXX
CITATION
7SR
8BQ
8FD
8FE
8FG
ABJCF
ABUWG
AFKRA
AZQEC
BENPR
BGLVJ
CCPQU
D1I
DWQXO
HCIFZ
JG9
KB.
PDBOC
PHGZM
PHGZT
PIMPY
PKEHL
PQEST
PQGLB
PQQKQ
PQUKI
PRINS
DOI 10.3390/catal8070273
DatabaseName CrossRef
Engineered Materials Abstracts
METADEX
Technology Research Database
ProQuest SciTech Collection
ProQuest Technology Collection
Materials Science & Engineering Collection
ProQuest Central
ProQuest Central UK/Ireland
ProQuest Central Essentials - QC
ProQuest Central
ProQuest Technology Collection
ProQuest One
ProQuest Materials Science Collection
ProQuest Central
SciTech Premium Collection
Materials Research Database
Materials Science Database
Materials Science Collection
ProQuest Central Premium
ProQuest One Academic (New)
ProQuest Publicly Available Content Database
ProQuest One Academic Middle East (New)
ProQuest One Academic Eastern Edition (DO NOT USE)
ProQuest One Applied & Life Sciences
ProQuest One Academic
ProQuest One Academic UKI Edition
ProQuest Central China
DatabaseTitle CrossRef
Publicly Available Content Database
Materials Research Database
Technology Collection
Technology Research Database
ProQuest One Academic Middle East (New)
ProQuest Central Essentials
Materials Science Collection
ProQuest Central (Alumni Edition)
SciTech Premium Collection
ProQuest One Community College
ProQuest Central China
ProQuest Central
ProQuest One Applied & Life Sciences
Engineered Materials Abstracts
ProQuest Central Korea
Materials Science Database
ProQuest Central (New)
ProQuest Materials Science Collection
ProQuest One Academic Eastern Edition
ProQuest Technology Collection
ProQuest SciTech Collection
METADEX
ProQuest One Academic UKI Edition
Materials Science & Engineering Collection
ProQuest One Academic
ProQuest One Academic (New)
DatabaseTitleList CrossRef
Publicly Available Content Database
Database_xml – sequence: 1
  dbid: 8FG
  name: ProQuest Technology Collection
  url: https://search.proquest.com/technologycollection1
  sourceTypes: Aggregation Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 2073-4344
ExternalDocumentID 10_3390_catal8070273
GroupedDBID 5VS
8FE
8FG
AADQD
AAFWJ
AAYXX
ABDBF
ABJCF
ACUHS
ADBBV
ADMLS
AENEX
AFKRA
AFZYC
ALMA_UNASSIGNED_HOLDINGS
BCNDV
BENPR
BGLVJ
CCPQU
CITATION
D1I
ESX
HCIFZ
IAO
IPNFZ
KB.
KQ8
MODMG
M~E
OK1
PDBOC
PHGZM
PHGZT
PIMPY
PROAC
RIG
7SR
8BQ
8FD
ABUWG
AZQEC
DWQXO
JG9
PKEHL
PQEST
PQGLB
PQQKQ
PQUKI
PRINS
ID FETCH-LOGICAL-c301t-4efb2e74ec147190bf37dc4458f080bb41184e1a9f303935432cd4c3a88272ba3
IEDL.DBID 8FG
ISSN 2073-4344
IngestDate Fri Jul 25 12:15:14 EDT 2025
Thu Apr 24 22:51:12 EDT 2025
Tue Jul 01 01:11:59 EDT 2025
IsDoiOpenAccess true
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 7
Language English
License https://creativecommons.org/licenses/by/4.0
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c301t-4efb2e74ec147190bf37dc4458f080bb41184e1a9f303935432cd4c3a88272ba3
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ORCID 0000-0002-5291-8839
OpenAccessLink https://www.proquest.com/docview/2582798111?pq-origsite=%requestingapplication%
PQID 2582798111
PQPubID 2032420
ParticipantIDs proquest_journals_2582798111
crossref_citationtrail_10_3390_catal8070273
crossref_primary_10_3390_catal8070273
ProviderPackageCode CITATION
AAYXX
PublicationCentury 2000
PublicationDate 2018-07-06
PublicationDateYYYYMMDD 2018-07-06
PublicationDate_xml – month: 07
  year: 2018
  text: 2018-07-06
  day: 06
PublicationDecade 2010
PublicationPlace Basel
PublicationPlace_xml – name: Basel
PublicationTitle Catalysts
PublicationYear 2018
Publisher MDPI AG
Publisher_xml – name: MDPI AG
References Correa (ref_7) 2009; 48
Zhang (ref_34) 2009; 630
Matthessen (ref_9) 2014; 10
An (ref_26) 2011; 13
ref_33
Niu (ref_14) 2009; 27
Yang (ref_4) 2014; 7
Isse (ref_18) 2005; 581
Poizot (ref_27) 2010; 56
Isse (ref_19) 2006; 51
Zhou (ref_30) 2015; 25
Durante (ref_31) 2014; 158–159
Sock (ref_21) 1985; 26
Isse (ref_22) 2003; 541
Ebert (ref_6) 2005; 70
Poizot (ref_28) 2008; 624
Tateno (ref_11) 2015; 161
Bellomunno (ref_23) 2005; 50
Chen (ref_13) 2014; 42
Yang (ref_16) 2016; 37
ref_25
Chen (ref_35) 2011; 7
ref_20
Zhang (ref_29) 2010; 12
Yang (ref_10) 2018; 54
(ref_8) 2008; 47
Artz (ref_3) 2018; 118
Dong (ref_24) 2018; 122
Scialdone (ref_17) 2008; 53
Kim (ref_2) 2014; 53
Tateno (ref_12) 2015; 5
Alkordi (ref_1) 2016; 4
ref_5
Niu (ref_15) 2008; 64
Gennaro (ref_32) 1990; 289
References_xml – volume: 27
  start-page: 1041
  year: 2009
  ident: ref_14
  article-title: Electrocatalytic carboxylation of benzyl chloride at silver cathode in ionic liquid BMIMBF4
  publication-title: Chin. J. Catal.
– volume: 630
  start-page: 35
  year: 2009
  ident: ref_34
  article-title: Asymmetric electrochemical carboxylation of prochiral acetophenone: An efficient route to optically active atrolactic acid via selective fixation of carbon dioxide
  publication-title: J. Electroanal. Chem.
  doi: 10.1016/j.jelechem.2009.02.013
– volume: 7
  start-page: 858
  year: 2011
  ident: ref_35
  article-title: Unique heterogeneous silver-copper dendrites with a trace amount of uniformly distributed elemental cu and their enhanced sers properties
  publication-title: Small
  doi: 10.1002/smll.201002331
– volume: 64
  start-page: 10517
  year: 2008
  ident: ref_15
  article-title: Electrocatalytic carboxylation of aliphatic halides at silver cathode in acetonitrile
  publication-title: Tetrahedron
  doi: 10.1016/j.tet.2008.08.093
– ident: ref_5
  doi: 10.1002/ejoc.201701436
– volume: 53
  start-page: 2514
  year: 2008
  ident: ref_17
  article-title: Electrocarboxylation of benzyl chlorides at silver cathode at the preparative scale level
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2007.10.021
– volume: 122
  start-page: 11392
  year: 2018
  ident: ref_24
  article-title: First-principles insight into electrocatalytic reduction of CO2 to CH4 on a copper nanoparticle
  publication-title: J. Phys. Chem. C
  doi: 10.1021/acs.jpcc.8b01928
– volume: 70
  start-page: 4314
  year: 2005
  ident: ref_6
  article-title: Carboxylation and esterification of functionalized arylcopper reagents
  publication-title: J. Org. Chem.
  doi: 10.1021/jo047731s
– volume: 161
  start-page: 212
  year: 2015
  ident: ref_11
  article-title: Electrochemical fixation of CO2 to organohalides in room-temperature ionic liquids under supercritical CO2
  publication-title: Electrochimica Acta
  doi: 10.1016/j.electacta.2015.01.072
– volume: 56
  start-page: 15
  year: 2010
  ident: ref_27
  article-title: Silver–palladium cathode
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2010.09.020
– ident: ref_25
  doi: 10.1021/acsaem.8b00356
– volume: 5
  start-page: 98721
  year: 2015
  ident: ref_12
  article-title: Development of a novel electrochemical carboxylation system using a microreactor
  publication-title: RSC Adv.
  doi: 10.1039/C5RA19289G
– volume: 50
  start-page: 2331
  year: 2005
  ident: ref_23
  article-title: Building up an electrocatalytic activity scale of cathode materials for organic halide reductions
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2004.10.047
– volume: 37
  start-page: 994
  year: 2016
  ident: ref_16
  article-title: Cathode made of compacted silver nanoparticles for electrocatalytic carboxylation of 1-phenethyl bromide with CO2
  publication-title: Chin. J. Catal.
  doi: 10.1016/S1872-2067(15)61075-0
– volume: 53
  start-page: 771
  year: 2014
  ident: ref_2
  article-title: Carbon dioxide capture and use: Organic synthesis using carbon dioxide from exhaust gas
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.201308341
– volume: 4
  start-page: 7453
  year: 2016
  ident: ref_1
  article-title: CO2 conversion: The potential of porous-organic polymers (pops) for catalytic CO2-epoxide insertion
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C5TA09321J
– volume: 158–159
  start-page: 286
  year: 2014
  ident: ref_31
  article-title: Electrochemical activation of carbon-halogen bonds: Electrocatalysis at silver/copper nanoparticles
  publication-title: Appl. Catal. B: Environ.
  doi: 10.1016/j.apcatb.2014.04.023
– volume: 624
  start-page: 52
  year: 2008
  ident: ref_28
  article-title: The one-electron cleavage and reductive homo-coupling of alkyl bromides at silver-palladium cathodes
  publication-title: J. Electroanal. Chem.
  doi: 10.1016/j.jelechem.2008.07.021
– volume: 289
  start-page: 203
  year: 1990
  ident: ref_32
  article-title: Solubility and electrochemical determination of CO2 in some dipolar aprotic solvents
  publication-title: J. Electroanal. Chem.
  doi: 10.1016/0022-0728(90)87217-8
– volume: 13
  start-page: 1413
  year: 2011
  ident: ref_26
  article-title: Study on Ag–Pd bimetallic nanoparticles for electrocatalytic reduction of benzyl chloride
  publication-title: Electrochem. Commun.
  doi: 10.1016/j.elecom.2011.08.049
– volume: 541
  start-page: 93
  year: 2003
  ident: ref_22
  article-title: Homogeneous electron transfer catalysis in the electrochemical carboxylation of arylethyl chlorides
  publication-title: J. Electroanal. Chem.
  doi: 10.1016/S0022-0728(02)01418-3
– volume: 25
  start-page: 4001
  year: 2015
  ident: ref_30
  article-title: Ag-Ni alloy nanoparticles for electrocatalytic reduction of benzyl chloride
  publication-title: Trans. Nonferrous Met. Soc. China
  doi: 10.1016/S1003-6326(15)64049-3
– volume: 47
  start-page: 3100
  year: 2008
  ident: ref_8
  article-title: Carboxylic acids as substrates in homogeneous catalysis
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200704782
– volume: 51
  start-page: 4956
  year: 2006
  ident: ref_19
  article-title: Electrochemical reduction of benzyl halides at a silver electrode
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2006.01.039
– ident: ref_33
  doi: 10.3390/catal7090274
– volume: 10
  start-page: 2484
  year: 2014
  ident: ref_9
  article-title: Electrocarboxylation: Towards sustainable and efficient synthesis of valuable carboxylic acids
  publication-title: Beilstein J. Org. Chem.
  doi: 10.3762/bjoc.10.260
– volume: 48
  start-page: 6201
  year: 2009
  ident: ref_7
  article-title: Metal-catalyzed carboxylation of organometallic reagents with carbon dioxide
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200900667
– volume: 42
  start-page: 55
  year: 2014
  ident: ref_13
  article-title: Asymmetric electrocarboxylation of 1-phenylethyl chloride catalyzed by electrogenerated chiral [CoI(salen)]− complex
  publication-title: Electrochem. Commun.
  doi: 10.1016/j.elecom.2014.02.009
– volume: 26
  start-page: 1509
  year: 1985
  ident: ref_21
  article-title: Electrosynthesis of carboxylic acids from organic halides and carbon dioxide
  publication-title: Tetrahedron Lett.
  doi: 10.1016/S0040-4039(00)98538-1
– volume: 581
  start-page: 38
  year: 2005
  ident: ref_18
  article-title: Electrocatalytic reduction of arylethyl chlorides at silver cathodes in the presence of carbon dioxide: Synthesis of 2-arylpropanoic acids
  publication-title: J. Electroanal. Chem.
  doi: 10.1016/j.jelechem.2005.04.007
– ident: ref_20
  doi: 10.1039/b206746c
– volume: 12
  start-page: 1233
  year: 2010
  ident: ref_29
  article-title: Fabrication of Ag/Au bimetallic nanoparticles by upd-redox replacement: Application in the electrochemical reduction of benzyl chloride
  publication-title: Electrochem. Commun.
  doi: 10.1016/j.elecom.2010.06.027
– volume: 7
  start-page: 962
  year: 2014
  ident: ref_4
  article-title: Recent advances in carbon dioxide capture, fixation, and activation by using N-heterocyclic carbenes
  publication-title: ChemSusChem.
  doi: 10.1002/cssc.201301131
– volume: 54
  start-page: 4108
  year: 2018
  ident: ref_10
  article-title: Platinum/nitrogen-doped carbon/carbon cloth: A bifunctional catalyst for the electrochemical reduction and carboxylation of CO2 with excellent efficiency
  publication-title: Chem. Commun.
  doi: 10.1039/C8CC00969D
– volume: 118
  start-page: 434
  year: 2018
  ident: ref_3
  article-title: Sustainable conversion of carbon dioxide: An integrated review of catalysis and life cycle assessment
  publication-title: Chem. Rev.
  doi: 10.1021/acs.chemrev.7b00435
SSID ssj0000913815
Score 2.1249585
Snippet A simple and efficient electrocatalytic carboxylation of benzyl chloride with CO2 is described. The reaction operates under 1 atm CO2 and room temperature in...
A simple and efficient electrocatalytic carboxylation of benzyl chloride with CO2 is described. The reaction operates under 1 atm CO2 and room temperature in a...
SourceID proquest
crossref
SourceType Aggregation Database
Enrichment Source
Index Database
StartPage 273
SubjectTerms Acids
Carbon dioxide
Carboxylation
Catalysts
Cathodes
Charge density
Charge materials
Chemical reactions
Chloride
Chlorides
Electrode materials
Electrodes
Electrolysis
Metal foams
Noble metals
Room temperature
Sacrificial anodes
Silver
Title Highly Efficient Electrocatalytic Carboxylation of 1-Phenylethyl Chloride at Cu Foam Cathode
URI https://www.proquest.com/docview/2582798111
Volume 8
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1LT8MwDI5gO8AF8RSDMeUAJxSxJmnTnhBUHRMS04SYtANS1aSpdhjt2DqJ_nucPgY7wLlpKjmx_dn9bCN0rZnu88SxiaJSEc4im3iOa5NYak_0lXCjskjsZeQMJ_x5ak_rhNuqplU2NrE01HGmTI78jtouFZ4Lqnm_-CRmapT5u1qP0NhFbYuCrzWV4oOnTY7F9Lx0LbviuzOI7qt6cBeuORVs2xNtG-LSuwwO0UENC_FDdY5HaEenx2jPb6axnaB3Q8iYFzgoWz6Ap8BBNcCm_FYBr2E_Wsrsq6jIbThLsEXGM50WcDKzYo79mSHbxRpHOfbXeJBFH9jU_2WxPkWTQfDmD0k9GYEoUMiccJ1IqgXXygLn4vVlwkSsOLfdBBCglBzCBq6tyEtYWXvLGVUxVywCPC2ojNgZaqVZqs8RTmLKBHe4pWEDwIKe6UdjwT5KgPbHSQfdNlIKVd023EyvmIcQPhiZhr9l2kE3m9WLql3GH-u6jcDDWmlW4c8RX_z_-BLtA25xS9as00WtfLnWV4ANctkrL0APtR-D0fj1G1dHuyU
linkProvider ProQuest
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV07T8MwED7xGGBBPEV5eoAJWTS2EzsDQii0lKcYQGJACrHjqENpgLaC_Cl-I-ek4THAxhzHli7fnT87390B7FhumyILfGqYNlTwxKdhoHyaahvKppEqKZPELq-Czq04u_PvJuC9zoVxsso6JpaBOs2NuyPfZ75iMlTomodPz9R1jXJ_V-sWGhUszm3xike2wcHpMX7fXcbarZuoQ8ddBahBMA-psJlmVgprPAzMYVNnXKZGCF9lyJ60Fki5hfWSMONl3qrgzKTC8AS5qGQ64TjvJEwLzrmTEKr2yeedjquxqTy_0tdzHjar_HOFbsUk_7nz_Qz85W7Wnoe5MQ0lRxVuFmDC9hdhJqq7vy3BvROA9ArSKktM4M5EWlXDnHKtAl8jUfKi87eiEtORPCMeve7afoFI6BY9EnWduC-1JBmSaETaefJIXL5hntpluP0Xm63AVD_v21UgWcq4FIHwLE6A3DN09W88nMdIjDZp1oC92kqxGZcpd90yejEeV5xN4-82bcDu5-inqjzHL-M2aoPHYycdxF-QWvv78TbMdG4uL-KL06vzdZhFzqRKxW6wAVPDl5HdRF4y1FslGAg8_Df6PgB9pfVJ
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1LT9wwEB7xkKAX1FIQtLT1AU6V1Y3txMkBoTbsCkq7WqEicUAKfmoPy4buLqL5i_1VjPOg5dDeOMexpcnnmbHzzXwA-467nvBJTA3ThgquYpolaUytdpnsGZmqukjs-zA5uRBfL-PLJfjd1cIEWmXnE2tHbUsT7sg_sThlMksDC8e3tIjR8eDo9icNClLhT2snp6FamQV7WLcba4s8zlx1j8e5-eHpMX77A8YG_R_5CW0VB6hBoC-ocF4zJ4UzETrtrKc9l9YIEaceMyutBabjwkUq87yuaRWcGSsMV5inSqYVx3mXYVVi1MeD4OqX_nB0_njjEzpwplHcsO85z3pNdXqKm45J_jQuPg0LdawbvISNNkklnxtUvYIlN92E9bzThnsNV4EeMqlIv25AgXGL9Bs5nXqtCl8juZrp8lfVUO1I6UlER2M3rRAn42pC8nGg_llH1ILkd2RQqhsSqhFL67bg4lmstg0r03LqdoB4y7gUiYgcToCZaRa640Q4j5Hoi6zfhY-dlQrTNjEPWhqTAg8zwabF3zbdhYPH0bdN845_jNvrDF60W3he_AHcm_8__gBriMTi2-nw7C28wIQqrem8yR6sLGZ37h0mLQv9vkUDgevnBuADBdgAMw
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Highly+Efficient+Electrocatalytic+Carboxylation+of+1-Phenylethyl+Chloride+at+Cu+Foam+Cathode&rft.jtitle=Catalysts&rft.au=Wu%2C+La-Xia&rft.au=Sun%2C+Qi-Long&rft.au=Yang%2C+Man-Ping&rft.au=Zhao%2C+Ying-Guo&rft.date=2018-07-06&rft.issn=2073-4344&rft.eissn=2073-4344&rft.volume=8&rft.issue=7&rft.spage=273&rft_id=info:doi/10.3390%2Fcatal8070273&rft.externalDBID=n%2Fa&rft.externalDocID=10_3390_catal8070273
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2073-4344&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2073-4344&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2073-4344&client=summon