CeO2 and CeO2-based nanomaterials for photocatalytic, antioxidant and antimicrobial activities
Cerium oxide (CeO2), one of the most significant rare-earth oxides, has attracted considerable interest over the past decades. This is primarily due to the ease in Ce3+/Ce4+ redox ability as well as other factors that affect the efficacy of CeO2 and CeO2-based materials. CeO2 and CeO2-based material...
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Published in | Journal of rare earths Vol. 41; no. 2; pp. 167 - 181 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.02.2023
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Subjects | |
Online Access | Get full text |
ISSN | 1002-0721 2509-4963 |
DOI | 10.1016/j.jre.2022.09.003 |
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Abstract | Cerium oxide (CeO2), one of the most significant rare-earth oxides, has attracted considerable interest over the past decades. This is primarily due to the ease in Ce3+/Ce4+ redox ability as well as other factors that affect the efficacy of CeO2 and CeO2-based materials. CeO2 and CeO2-based materials have shown enhanced responses in catalytic and photocatalytic activities for environmental and biological applications. In addition, the formation of Ce3+ and oxygen vacancies in CeO2 has aided in enhancing CeO2 activities. In order to produce oxygen-deficient CeO2 and CeO2-based materials, a variety of synthesis methods were used and are highlighted in this review. Therefore, this review compiles and discusses the mechanisms that involve oxygen vacancies, defects, and Ce3+ formation for environmental applications, such as photocatalytic dye degradation, photocatalytic CO2 reduction, and non-colored pollutants removal. The biological applications of CeO2, such as antioxidant enzyme mimetic, antioxidant reactive oxygen species/reactive nitrogen species, and antimicrobial activities, are also discussed. Additionally, future prospects are also suggested for future development and detailed investigations.
Enhanced response of the CeO2 and CeO2-based materials for photocatalytic, antioxidant, and antimicrobial activities owing to the redox ability, formation of Ce3+, and oxygen vacancies. [Display omitted]
•Syntheses of CeO2, doped-CeO2, and CeO2 composites.•Synergistic formation of Ce3+ and oxygen vacancies in CeO2.•CeO2-based nanomaterials for photocatalytic applications.•CeO2-based nanomaterials for environmental applications.•CeO2-based nanomaterials for biological applications. |
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AbstractList | Cerium oxide (CeO2), one of the most significant rare-earth oxides, has attracted considerable interest over the past decades. This is primarily due to the ease in Ce3+/Ce4+ redox ability as well as other factors that affect the efficacy of CeO2 and CeO2-based materials. CeO2 and CeO2-based materials have shown enhanced responses in catalytic and photocatalytic activities for environmental and biological applications. In addition, the formation of Ce3+ and oxygen vacancies in CeO2 has aided in enhancing CeO2 activities. In order to produce oxygen-deficient CeO2 and CeO2-based materials, a variety of synthesis methods were used and are highlighted in this review. Therefore, this review compiles and discusses the mechanisms that involve oxygen vacancies, defects, and Ce3+ formation for environmental applications, such as photocatalytic dye degradation, photocatalytic CO2 reduction, and non-colored pollutants removal. The biological applications of CeO2, such as antioxidant enzyme mimetic, antioxidant reactive oxygen species/reactive nitrogen species, and antimicrobial activities, are also discussed. Additionally, future prospects are also suggested for future development and detailed investigations.
Enhanced response of the CeO2 and CeO2-based materials for photocatalytic, antioxidant, and antimicrobial activities owing to the redox ability, formation of Ce3+, and oxygen vacancies. [Display omitted]
•Syntheses of CeO2, doped-CeO2, and CeO2 composites.•Synergistic formation of Ce3+ and oxygen vacancies in CeO2.•CeO2-based nanomaterials for photocatalytic applications.•CeO2-based nanomaterials for environmental applications.•CeO2-based nanomaterials for biological applications. |
Author | Matussin, Shaidatul Najihah Khan, Mohammad Mansoob Harunsani, Mohammad Hilni |
Author_xml | – sequence: 1 givenname: Shaidatul Najihah surname: Matussin fullname: Matussin, Shaidatul Najihah – sequence: 2 givenname: Mohammad Hilni orcidid: 0000-0003-3073-6281 surname: Harunsani fullname: Harunsani, Mohammad Hilni – sequence: 3 givenname: Mohammad Mansoob orcidid: 0000-0002-8633-7493 surname: Khan fullname: Khan, Mohammad Mansoob email: mansoob.khan@ubd.edu.bn, mmansoobkhan@yahoo.com |
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Snippet | Cerium oxide (CeO2), one of the most significant rare-earth oxides, has attracted considerable interest over the past decades. This is primarily due to the... |
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SubjectTerms | Biological applications Ce3+/Ce4 Environmental applications Oxygen deficient CeO2 Oxygen vacancies Rare earths |
Title | CeO2 and CeO2-based nanomaterials for photocatalytic, antioxidant and antimicrobial activities |
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