Evidence of improved power conversion efficiency in lead-free CsGeI3 based perovskite solar cell heterostructure via scaps simulation
Simulation has been performed on fully lead-free inorganic cesium germanium tri-iodide (CsGeI3) perovskite solar cell heterostructure and achieved a champion power conversion efficiency (PCE) of ∼18.30% with significantly improved device parameters. The influence of thickness of an electron transpor...
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| Published in | Journal of vacuum science and technology. B, Nanotechnology & microelectronics Vol. 39; no. 1 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.01.2021
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| Online Access | Get full text |
| ISSN | 2166-2746 2166-2754 |
| DOI | 10.1116/6.0000718 |
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| Abstract | Simulation has been performed on fully lead-free inorganic cesium germanium tri-iodide (CsGeI3) perovskite solar cell heterostructure and achieved a champion power conversion efficiency (PCE) of ∼18.30% with significantly improved device parameters. The influence of thickness of an electron transport layer, a hole transport layer, an absorber, defect density, doping concentration, electron affinity, temperature, and series resistance issued for the optimization of the lead-free device is studied. It is confirmed via the scaps simulation results that this device is perfectly optimized with the experimental results and demonstrates the maximum possible improved power conversion efficiency in a fully inorganic lead-free CsGeI3 perovskite solar cell device. The final optimized device performance parameters are as follows: %PCE = 18.30%, %FF = 75.46%, Jsc = 23.31 mA/cm2, and Voc = 1.04 V. In the future, this efficiency may offer prominent potential as a substitute in a highly efficient green solar absorber material for photovoltaic applications after confirmation in the laboratory. |
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| AbstractList | Simulation has been performed on fully lead-free inorganic cesium germanium tri-iodide (CsGeI3) perovskite solar cell heterostructure and achieved a champion power conversion efficiency (PCE) of ∼18.30% with significantly improved device parameters. The influence of thickness of an electron transport layer, a hole transport layer, an absorber, defect density, doping concentration, electron affinity, temperature, and series resistance issued for the optimization of the lead-free device is studied. It is confirmed via the scaps simulation results that this device is perfectly optimized with the experimental results and demonstrates the maximum possible improved power conversion efficiency in a fully inorganic lead-free CsGeI3 perovskite solar cell device. The final optimized device performance parameters are as follows: %PCE = 18.30%, %FF = 75.46%, Jsc = 23.31 mA/cm2, and Voc = 1.04 V. In the future, this efficiency may offer prominent potential as a substitute in a highly efficient green solar absorber material for photovoltaic applications after confirmation in the laboratory. |
| Author | Gupta, Ankit Anshul, Avneesh Bherwani, Hemant Raj, Abhishek Kumar, Manish |
| Author_xml | – sequence: 1 givenname: Abhishek surname: Raj fullname: Raj, Abhishek organization: 3Experimental Research Laboratory, Department of Physics, ARSD College, University of Delhi, New Delhi 110021, India – sequence: 2 givenname: Manish surname: Kumar fullname: Kumar, Manish organization: Experimental Research Laboratory, Department of Physics, ARSD College, University of Delhi – sequence: 3 givenname: Hemant surname: Bherwani fullname: Bherwani, Hemant organization: 3Experimental Research Laboratory, Department of Physics, ARSD College, University of Delhi, New Delhi 110021, India – sequence: 4 givenname: Ankit surname: Gupta fullname: Gupta, Ankit organization: 3Experimental Research Laboratory, Department of Physics, ARSD College, University of Delhi, New Delhi 110021, India – sequence: 5 givenname: Avneesh surname: Anshul fullname: Anshul, Avneesh organization: CSIR-National Environmental Engineering Research Institute (NEERI) |
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