Supramolecular Chemistry in Metal–Organic Framework Materials
Far from being simply rigid, benign architectures, metal–organic frameworks (MOFs) exhibit diverse interactions with their interior environment. From developing crystal sponges to studying reactions in framework materials, the role of both supramolecular chemistry and framework structure is evident....
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| Published in | Advanced materials (Weinheim) p. e2414509 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
02.02.2025
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0935-9648 1521-4095 1521-4095 |
| DOI | 10.1002/adma.202414509 |
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| Abstract | Far from being simply rigid, benign architectures, metal–organic frameworks (MOFs) exhibit diverse interactions with their interior environment. From developing crystal sponges to studying reactions in framework materials, the role of both supramolecular chemistry and framework structure is evident. We explore the role of supramolecular chemistry in determining framework…guest interactions and attempts to understand the dynamic behavior in MOFs, including attempts to control pore behavior through the incorporation of mechanically‐interlocked molecules. Appreciating and understanding the role of supramolecular interactions and dynamic behavior in metal–organic frameworks emerge as important directions for the field. |
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| AbstractList | Far from being simply rigid, benign architectures, metal-organic frameworks (MOFs) exhibit diverse interactions with their interior environment. From developing crystal sponges to studying reactions in framework materials, the role of both supramolecular chemistry and framework structure is evident. We explore the role of supramolecular chemistry in determining framework…guest interactions and attempts to understand the dynamic behavior in MOFs, including attempts to control pore behavior through the incorporation of mechanically-interlocked molecules. Appreciating and understanding the role of supramolecular interactions and dynamic behavior in metal-organic frameworks emerge as important directions for the field.Far from being simply rigid, benign architectures, metal-organic frameworks (MOFs) exhibit diverse interactions with their interior environment. From developing crystal sponges to studying reactions in framework materials, the role of both supramolecular chemistry and framework structure is evident. We explore the role of supramolecular chemistry in determining framework…guest interactions and attempts to understand the dynamic behavior in MOFs, including attempts to control pore behavior through the incorporation of mechanically-interlocked molecules. Appreciating and understanding the role of supramolecular interactions and dynamic behavior in metal-organic frameworks emerge as important directions for the field. Far from being simply rigid, benign architectures, metal-organic frameworks (MOFs) exhibit diverse interactions with their interior environment. From developing crystal sponges to studying reactions in framework materials, the role of both supramolecular chemistry and framework structure is evident. We explore the role of supramolecular chemistry in determining framework…guest interactions and attempts to understand the dynamic behavior in MOFs, including attempts to control pore behavior through the incorporation of mechanically-interlocked molecules. Appreciating and understanding the role of supramolecular interactions and dynamic behavior in metal-organic frameworks emerge as important directions for the field. |
| Author | Champness, Neil R. Orton, Georgia R. F. Schier, Danielle E. Miguel‐Casañ, Eugenia |
| Author_xml | – sequence: 1 givenname: Eugenia orcidid: 0000-0001-9047-4143 surname: Miguel‐Casañ fullname: Miguel‐Casañ, Eugenia organization: School of Chemistry University of Birmingham Edgbaston Birmingham B15 2TT UK – sequence: 2 givenname: Georgia R. F. orcidid: 0000-0002-7566-0092 surname: Orton fullname: Orton, Georgia R. F. organization: School of Chemistry University of Birmingham Edgbaston Birmingham B15 2TT UK – sequence: 3 givenname: Danielle E. surname: Schier fullname: Schier, Danielle E. organization: School of Chemistry University of Birmingham Edgbaston Birmingham B15 2TT UK – sequence: 4 givenname: Neil R. orcidid: 0000-0003-2970-1487 surname: Champness fullname: Champness, Neil R. organization: School of Chemistry University of Birmingham Edgbaston Birmingham B15 2TT UK |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/39895182$$D View this record in MEDLINE/PubMed |
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| Keywords | metal–organic frameworks reticular chemistry supramolecular chemistry |
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