Direct measurement of thermoelectric properties of β-MnO2 in its powder form

Thermoelectric power of nanoscale materials could be greatly enhanced than that of their bulks, but its precise measurement becomes a challenging problem. A setup designed for directly characterizing the thermoelectric properties of powder samples was constructed. As a demonstration, we measured the...

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Published inApplied physics letters Vol. 110; no. 2
Main Authors Shen, Shi-Peng, Chai, Yi-Sheng, Wang, Shou-Guo, Yang, Chuan-Sen, Shang, Da-Shan, Sun, Young
Format Journal Article
LanguageEnglish
Published Melville American Institute of Physics 09.01.2017
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ISSN0003-6951
1077-3118
DOI10.1063/1.4973630

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Summary:Thermoelectric power of nanoscale materials could be greatly enhanced than that of their bulks, but its precise measurement becomes a challenging problem. A setup designed for directly characterizing the thermoelectric properties of powder samples was constructed. As a demonstration, we measured the thermoelectric potential of β-MnO2 sample in different powder forms around room temperature. The β-MnO2 powder ground in the air has a much larger thermopower than that in the as-bought sample or powder ground in the dry Ar atmosphere. It was concluded that the Seebeck coefficient of β-MnO2 powder can be greatly affected in the air due to a possible electrochemical reaction with H2O vapor.
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ISSN:0003-6951
1077-3118
DOI:10.1063/1.4973630