Theoretical Analysis of Rydberg and Autoionizing State Spectra of Antimony

We calculate the Rydberg and autoionization Rydberg spectra of antimony （Sb） from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. Our calculation can be used to classify and assign the atomic states described in recently reported three...

Full description

Saved in:
Bibliographic Details
Published inChinese physics letters Vol. 34; no. 7; pp. 61 - 65
Main Author 吕双飞 李若虹 贾凤东 李晓康 Jens Lassen 钟志萍
Format Journal Article
LanguageEnglish
Published 01.06.2017
Subjects
Rydberg系列
光谱
多通道理论
多通道量子亏损理论
第一原理
自电离态
里德伯态
锑
Online AccessGet full text
ISSN0256-307X
1741-3540
DOI10.1088/0256-307X/34/7/073101

Cover

More Information
Summary:We calculate the Rydberg and autoionization Rydberg spectra of antimony （Sb） from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. Our calculation can be used to classify and assign the atomic states described in recently reported three Rydberg series and four autoionizing states. The perturbation effects on line intensity, variation and line profile are discussed. Assignments of the perturber states and autoionizing states are presented.
Bibliography:Shuang-Fei Lv1, Ruohong Li2, Feng-Dong Jia1, Xiao-Kang Li1 Jens Lassen2, Zhi-Ping Zhong1（ 1School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049 2TRIUMF, Wesbrook Mall 4004, Vancouver, Canada）
11-1959/O4
We calculate the Rydberg and autoionization Rydberg spectra of antimony （Sb） from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. Our calculation can be used to classify and assign the atomic states described in recently reported three Rydberg series and four autoionizing states. The perturbation effects on line intensity, variation and line profile are discussed. Assignments of the perturber states and autoionizing states are presented.
ISSN:0256-307X
1741-3540
DOI:10.1088/0256-307X/34/7/073101