Synthesis of 1,2,4,5-tetra-substituted benzenes via copper-catalyzed dimerization of γ,δ-unsaturated ketones
An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of gamma,delta-unsaturated ketones has been described. This one-pot procedure employs the gamma,delta-unsaturated ketones as the sole substrate with multiple C-C bond formation. This pr...
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| Published in | Chemical communications (Cambridge, England) Vol. 60; no. 60; pp. 7753 - 7756 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
CAMBRIDGE
Royal Soc Chemistry
23.07.2024
Royal Society of Chemistry |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1359-7345 1364-548X 1364-548X |
| DOI | 10.1039/d4cc02458c |
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| Abstract | An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of gamma,delta-unsaturated ketones has been described. This one-pot procedure employs the gamma,delta-unsaturated ketones as the sole substrate with multiple C-C bond formation. This protocol features broad substrate scope and provides a facile and robust method to construct polysubstituted benzene derivatives under mild conditions. |
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| AbstractList | An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes
via
copper catalyzed dimerization of γ,δ-unsaturated ketones has been described. This one-pot procedure employs the γ,δ-unsaturated ketones as the sole substrate with multiple C–C bond formation. This protocol features broad substrate scope and provides a facile and robust method to construct polysubstituted benzene derivatives under mild conditions. An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes copper catalyzed dimerization of γ,δ-unsaturated ketones has been described. This one-pot procedure employs the γ,δ-unsaturated ketones as the sole substrate with multiple C-C bond formation. This protocol features broad substrate scope and provides a facile and robust method to construct polysubstituted benzene derivatives under mild conditions. An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of γ,δ-unsaturated ketones has been described. This one-pot procedure employs the γ,δ-unsaturated ketones as the sole substrate with multiple C-C bond formation. This protocol features broad substrate scope and provides a facile and robust method to construct polysubstituted benzene derivatives under mild conditions.An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of γ,δ-unsaturated ketones has been described. This one-pot procedure employs the γ,δ-unsaturated ketones as the sole substrate with multiple C-C bond formation. This protocol features broad substrate scope and provides a facile and robust method to construct polysubstituted benzene derivatives under mild conditions. An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of gamma,delta-unsaturated ketones has been described. This one-pot procedure employs the gamma,delta-unsaturated ketones as the sole substrate with multiple C-C bond formation. This protocol features broad substrate scope and provides a facile and robust method to construct polysubstituted benzene derivatives under mild conditions. An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of γ,δ-unsaturated ketones has been described. This one-pot procedure employs the γ,δ-unsaturated ketones as the sole substrate with multiple C–C bond formation. This protocol features broad substrate scope and provides a facile and robust method to construct polysubstituted benzene derivatives under mild conditions. |
| Author | Ma, Kai-Xian Hong, Chuan-Ming Li, Qing-Hua Liu, Tang-Lin Yan, Jiang-Min |
| Author_xml | – sequence: 1 givenname: Kai-Xian surname: Ma fullname: Ma, Kai-Xian organization: Southwest Univ, Sch Chem & Chem Engn, Chongqing Key Lab Soft Matter Mat Mfg, Chongqing 400715, Peoples R China – sequence: 2 givenname: Chuan-Ming surname: Hong fullname: Hong, Chuan-Ming organization: Southwest Univ, Sch Chem & Chem Engn, Chongqing Key Lab Soft Matter Mat Mfg, Chongqing 400715, Peoples R China – sequence: 3 givenname: Jiang-Min surname: Yan fullname: Yan, Jiang-Min organization: Southwest Univ, Sch Chem & Chem Engn, Chongqing Key Lab Soft Matter Mat Mfg, Chongqing 400715, Peoples R China – sequence: 4 givenname: Qing-Hua surname: Li fullname: Li, Qing-Hua email: liqinghua@swu.edu.cn organization: Southwest Univ, Sch Chem & Chem Engn, Chongqing Key Lab Soft Matter Mat Mfg, Chongqing 400715, Peoples R China – sequence: 5 givenname: Tang-Lin orcidid: 0000-0002-7318-4520 surname: Liu fullname: Liu, Tang-Lin email: liuschop@swu.edu.cn organization: Southwest Univ, Sch Chem & Chem Engn, Chongqing Key Lab Soft Matter Mat Mfg, Chongqing 400715, Peoples R China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38973629$$D View this record in MEDLINE/PubMed |
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| Snippet | An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of gamma,delta-unsaturated ketones has been... An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of γ,δ-unsaturated ketones has been... An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes copper catalyzed dimerization of γ,δ-unsaturated ketones has been described.... An efficient cyclization for the synthesis of 1,2,4,5-tetra-substituted benzenes via copper catalyzed dimerization of γ,δ-unsaturated ketones has been... |
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| SubjectTerms | Benzene Chemical synthesis Chemistry Chemistry, Multidisciplinary Copper Covalent bonds Dimerization Ketones Physical Sciences Science & Technology Substitutes Substrates |
| Title | Synthesis of 1,2,4,5-tetra-substituted benzenes via copper-catalyzed dimerization of γ,δ-unsaturated ketones |
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