Research on overcharge thermal runaway behavior analysis and early warning algorithm of ternary lithium battery pack

During the charging process, lithium-ion batteries may experience thermal runaway due to the failure of overcharging protection mechanisms, posing a significant fire hazard. This work by analyzing the evolution of surface temperature, space temperature, and voltage of ternary lithium battery pack un...

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Published inJournal of applied electrochemistry Vol. 55; no. 2; pp. 273 - 288
Main Authors He, Xingfeng, Du, Jianhua, Yang, Shizhi, Cao, Xin, Qu, Chang, Ou, Yingjie, Wang, Jiabin, Xiong, Leji, Tu, Ran
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 01.02.2025
Springer Nature B.V
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Online AccessGet full text
ISSN0021-891X
1572-8838
DOI10.1007/s10800-024-02184-y

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Abstract During the charging process, lithium-ion batteries may experience thermal runaway due to the failure of overcharging protection mechanisms, posing a significant fire hazard. This work by analyzing the evolution of surface temperature, space temperature, and voltage of ternary lithium battery pack under different overcharging rates, a three-level early warning algorithm and device for thermal runaway of ternary lithium battery pack were developed. The results revealed that the entire thermal runaway process can be divided into three stages: early, middle, and late, based on the variations in batteries’ physical morphology, voltage, and temperature. Under identical initial conditions, the internal chemical reactions within the battery became more intense with the increasing charging rate, resulting in an earlier occurrence of thermal runaway. Ultimately, through testing and validation, the designed three-level warning algorithm proved capable of accurately assessing overcharging conditions in lithium batteries and issuing warnings in the early stages of thermal runaway. This work provided crucial references for enhancing the monitoring and warning capabilities of the battery management system. Graphical abstract
AbstractList During the charging process, lithium-ion batteries may experience thermal runaway due to the failure of overcharging protection mechanisms, posing a significant fire hazard. This work by analyzing the evolution of surface temperature, space temperature, and voltage of ternary lithium battery pack under different overcharging rates, a three-level early warning algorithm and device for thermal runaway of ternary lithium battery pack were developed. The results revealed that the entire thermal runaway process can be divided into three stages: early, middle, and late, based on the variations in batteries’ physical morphology, voltage, and temperature. Under identical initial conditions, the internal chemical reactions within the battery became more intense with the increasing charging rate, resulting in an earlier occurrence of thermal runaway. Ultimately, through testing and validation, the designed three-level warning algorithm proved capable of accurately assessing overcharging conditions in lithium batteries and issuing warnings in the early stages of thermal runaway. This work provided crucial references for enhancing the monitoring and warning capabilities of the battery management system.
During the charging process, lithium-ion batteries may experience thermal runaway due to the failure of overcharging protection mechanisms, posing a significant fire hazard. This work by analyzing the evolution of surface temperature, space temperature, and voltage of ternary lithium battery pack under different overcharging rates, a three-level early warning algorithm and device for thermal runaway of ternary lithium battery pack were developed. The results revealed that the entire thermal runaway process can be divided into three stages: early, middle, and late, based on the variations in batteries’ physical morphology, voltage, and temperature. Under identical initial conditions, the internal chemical reactions within the battery became more intense with the increasing charging rate, resulting in an earlier occurrence of thermal runaway. Ultimately, through testing and validation, the designed three-level warning algorithm proved capable of accurately assessing overcharging conditions in lithium batteries and issuing warnings in the early stages of thermal runaway. This work provided crucial references for enhancing the monitoring and warning capabilities of the battery management system. Graphical abstract
Author Ou, Yingjie
Qu, Chang
Tu, Ran
Yang, Shizhi
He, Xingfeng
Cao, Xin
Wang, Jiabin
Xiong, Leji
Du, Jianhua
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Keywords Lithium-ion battery
Overcharge
Warning algorithm
Spatial temperature
Thermal runaway
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Snippet During the charging process, lithium-ion batteries may experience thermal runaway due to the failure of overcharging protection mechanisms, posing a...
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SubjectTerms Algorithms
Batteries
Charging
Chemical reactions
Chemistry
Chemistry and Materials Science
Electric potential
Electric vehicles
Electrochemistry
Electrolytes
Energy storage
Experiments
Gases
Heat
Industrial Chemistry/Chemical Engineering
Initial conditions
Lithium
Lithium batteries
Lithium-ion batteries
Physical Chemistry
Research Article
Sensors
Space temperature
Thermal runaway
Voltage
Title Research on overcharge thermal runaway behavior analysis and early warning algorithm of ternary lithium battery pack
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