Phase Diagram of the MgF2–SrF2 System and Interactions of Magnesium and Strontium Fluorides with Other Fluorides

The phase diagram of the SrF 2 –MgF 2 system has been studied by differential thermal analysis (DTA) and X-ray powder diffraction (XRD). The stability area of the compound SrMgF 4 is very small, and its extent is about 20°С between 870 and 890°С. The formation of compounds by magnesium fluoride and...

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Published in	Russian journal of inorganic chemistry Vol. 68; no. 12; pp. 1789 - 1798
Main Authors	Fedorov, P. P., Pynenkov, A. A., Uslamina, M. A., Ushakov, S. N., Voronov, V. V., Alexandrov, A. A., Chernova, E. V., Nishchev, K. N.
Format	Journal Article
Language	English
Published	Moscow Pleiades Publishing 01.12.2023 Springer Nature B.V
Subjects	Cations Chemistry Chemistry and Materials Science Differential thermal analysis Electronegativity Inorganic Chemistry Lewis acid Magnesium fluorides Metal fluorides Phase diagrams Physicochemical Analysis of Inorganic Systems Stability analysis Strontium Strontium compounds Strontium fluorides X ray powder diffraction strontium fluoride Lewis acids and bases cumulative moment of cations phase diagram magnesium fluoride electronegativity SrMgF amphotericity thermal analysis
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ISSN	0036-0236 1531-8613
DOI	10.1134/S0036023623602325

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Abstract	The phase diagram of the SrF 2 –MgF 2 system has been studied by differential thermal analysis (DTA) and X-ray powder diffraction (XRD). The stability area of the compound SrMgF 4 is very small, and its extent is about 20°С between 870 and 890°С. The formation of compounds by magnesium fluoride and strontium fluoride with other metal fluorides is considered in the M versus X coordinates, where M is the cumulative moment of the cation and X is the cation electronegativity. Two areas of compound formation were identified for each of the fluorides. Magnesium and strontium fluorides are amphoteric compounds in terms of the Lewis acid and base theory.
AbstractList	The phase diagram of the SrF 2 –MgF 2 system has been studied by differential thermal analysis (DTA) and X-ray powder diffraction (XRD). The stability area of the compound SrMgF 4 is very small, and its extent is about 20°С between 870 and 890°С. The formation of compounds by magnesium fluoride and strontium fluoride with other metal fluorides is considered in the M versus X coordinates, where M is the cumulative moment of the cation and X is the cation electronegativity. Two areas of compound formation were identified for each of the fluorides. Magnesium and strontium fluorides are amphoteric compounds in terms of the Lewis acid and base theory. The phase diagram of the SrF2–MgF2 system has been studied by differential thermal analysis (DTA) and X-ray powder diffraction (XRD). The stability area of the compound SrMgF4 is very small, and its extent is about 20°С between 870 and 890°С. The formation of compounds by magnesium fluoride and strontium fluoride with other metal fluorides is considered in the M versus X coordinates, where M is the cumulative moment of the cation and X is the cation electronegativity. Two areas of compound formation were identified for each of the fluorides. Magnesium and strontium fluorides are amphoteric compounds in terms of the Lewis acid and base theory.
Author	Chernova, E. V. Pynenkov, A. A. Ushakov, S. N. Fedorov, P. P. Voronov, V. V. Alexandrov, A. A. Uslamina, M. A. Nishchev, K. N.
Author_xml	– sequence: 1 givenname: P. P. surname: Fedorov fullname: Fedorov, P. P. email: ppfedorov@yandex.ru organization: Prokhorov General Physics Institute, Russian Academy of Sciences – sequence: 2 givenname: A. A. surname: Pynenkov fullname: Pynenkov, A. A. organization: Ogarev Mordovian State University – sequence: 3 givenname: M. A. surname: Uslamina fullname: Uslamina, M. A. organization: Ogarev Mordovian State University – sequence: 4 givenname: S. N. surname: Ushakov fullname: Ushakov, S. N. organization: Prokhorov General Physics Institute, Russian Academy of Sciences, Ogarev Mordovian State University – sequence: 5 givenname: V. V. surname: Voronov fullname: Voronov, V. V. organization: Prokhorov General Physics Institute, Russian Academy of Sciences – sequence: 6 givenname: A. A. surname: Alexandrov fullname: Alexandrov, A. A. organization: Prokhorov General Physics Institute, Russian Academy of Sciences – sequence: 7 givenname: E. V. surname: Chernova fullname: Chernova, E. V. organization: Prokhorov General Physics Institute, Russian Academy of Sciences – sequence: 8 givenname: K. N. surname: Nishchev fullname: Nishchev, K. N. organization: Ogarev Mordovian State University
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Copyright	Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 12, pp. 1789–1798. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 12, pp. 1769–1778.
Copyright_xml	– notice: Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 12, pp. 1789–1798. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 12, pp. 1769–1778.
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Keywords	strontium fluoride Lewis acids and bases cumulative moment of cations phase diagram magnesium fluoride electronegativity SrMgF amphotericity thermal analysis
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Snippet	The phase diagram of the SrF 2 –MgF 2 system has been studied by differential thermal analysis (DTA) and X-ray powder diffraction (XRD). The stability area of... The phase diagram of the SrF2–MgF2 system has been studied by differential thermal analysis (DTA) and X-ray powder diffraction (XRD). The stability area of the...
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SubjectTerms	Cations Chemistry Chemistry and Materials Science Differential thermal analysis Electronegativity Inorganic Chemistry Lewis acid Magnesium fluorides Metal fluorides Phase diagrams Physicochemical Analysis of Inorganic Systems Stability analysis Strontium Strontium compounds Strontium fluorides X ray powder diffraction
Title	Phase Diagram of the MgF2–SrF2 System and Interactions of Magnesium and Strontium Fluorides with Other Fluorides
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