Rapid detection and recognition of phosphors using laser-induced breakdown spectroscopy and principal component analysis method—back propagation neural network algorithm
Rapid detection and quality monitoring of phosphor materials have always been a difficult problem in phosphor materials market. In this work, an independently proposed method based on principal component analysis method—error back propagation neural network algorithm—laser induced breakdown spectros...
        Saved in:
      
    
          | Published in | Laser physics Vol. 34; no. 5; pp. 55701 - 55709 | 
|---|---|
| Main Authors | , , , , , , | 
| Format | Journal Article | 
| Language | English | 
| Published | 
            IOP Publishing
    
        01.05.2024
     | 
| Subjects | |
| Online Access | Get full text | 
| ISSN | 1054-660X 1555-6611  | 
| DOI | 10.1088/1555-6611/ad3429 | 
Cover
| Abstract | Rapid detection and quality monitoring of phosphor materials have always been a difficult problem in phosphor materials market. In this work, an independently proposed method based on principal component analysis method—error back propagation neural network algorithm—laser induced breakdown spectroscopy (PCA-BPNN-LIBS) was used for the detection and recognition of phosphors. Firstly, spectroscopic study was carried out on phosphor material samples, and the composition of phosphor elements was analyzed according to the full emission spectrum. Spectral data with different element characteristics detected by LIBS were used as training data sets for further identification. Then PCA method and BPNN algorithm were applied to identify 4 types phosphor samples (P11, P20, P43, P46). A very clear distinction graph was obtained, and the classification accuracy of 99.93% was verified. Allresults show that the proposed PCA-BPNN-LIBS method is an effective method for rapid analysis and recognition of phosphors. | 
    
|---|---|
| AbstractList | Rapid detection and quality monitoring of phosphor materials have always been a difficult problem in phosphor materials market. In this work, an independently proposed method based on principal component analysis method—error back propagation neural network algorithm—laser induced breakdown spectroscopy (PCA-BPNN-LIBS) was used for the detection and recognition of phosphors. Firstly, spectroscopic study was carried out on phosphor material samples, and the composition of phosphor elements was analyzed according to the full emission spectrum. Spectral data with different element characteristics detected by LIBS were used as training data sets for further identification. Then PCA method and BPNN algorithm were applied to identify 4 types phosphor samples (P11, P20, P43, P46). A very clear distinction graph was obtained, and the classification accuracy of 99.93% was verified. Allresults show that the proposed PCA-BPNN-LIBS method is an effective method for rapid analysis and recognition of phosphors. | 
    
| Author | Yao, Hongbing Sun, Zhongmou Shen, Lingbin Tian, Dongpeng Ge, Yifan Liu, Yuzhu Tian, Liping  | 
    
| Author_xml | – sequence: 1 givenname: Lingbin surname: Shen fullname: Shen, Lingbin organization: College of Science, Hohai University , Nanjing 213022, People’s Republic of China – sequence: 2 givenname: Liping surname: Tian fullname: Tian, Liping organization: Jiangsu International Joint Laboratory on Meteorological Photonics and Optoelectronic Detection, Nanjing University of Information Science and Technology , Nanjing 210044, People’s Republic of China – sequence: 3 givenname: Hongbing surname: Yao fullname: Yao, Hongbing organization: College of Science, Hohai University , Nanjing 213022, People’s Republic of China – sequence: 4 givenname: Dongpeng surname: Tian fullname: Tian, Dongpeng organization: Jiangsu International Joint Laboratory on Meteorological Photonics and Optoelectronic Detection, Nanjing University of Information Science and Technology , Nanjing 210044, People’s Republic of China – sequence: 5 givenname: Yifan surname: Ge fullname: Ge, Yifan organization: Jiangsu International Joint Laboratory on Meteorological Photonics and Optoelectronic Detection, Nanjing University of Information Science and Technology , Nanjing 210044, People’s Republic of China – sequence: 6 givenname: Zhongmou surname: Sun fullname: Sun, Zhongmou organization: Jiangsu International Joint Laboratory on Meteorological Photonics and Optoelectronic Detection, Nanjing University of Information Science and Technology , Nanjing 210044, People’s Republic of China – sequence: 7 givenname: Yuzhu surname: Liu fullname: Liu, Yuzhu organization: Jiangsu International Joint Laboratory on Meteorological Photonics and Optoelectronic Detection, Nanjing University of Information Science and Technology , Nanjing 210044, People’s Republic of China  | 
    
| BookMark | eNp1UMtKAzEUDaJgW927zMqVY5OZJDOzlOILCoIouAuZJNOmnSYhmVK68yP8C__KLzFtxZXCDffmcs5JzhmCY-usBuACo2uMqmqMKaUZYxiPhSpIXh-Bwe_qOM2IkjSjt1MwjHGBECEE4QH4fBbeKKh0r2VvnIXCKhi0dDNr9nfXQj93MZ0Q4ToaO4OdiDpkxqq11Ao2QYulchsLo08awUXp_Hav44Ox0njRQelWPv3X9mkvum00Ea50P3fq6_2jEXKZoM6Lmdg_afU6JI7V_caFJRTdzAXTz1dn4KQVXdTnP30EXu9uXyYP2fTp_nFyM81kzkif5UxVDS0laauqqEktRc1IUSnMmCpZrllZkIYxWYi6TLFUucgxTRzS4IIWqUYAHXRlMhODbnkyshJhyzHiu7D5Llm-S5Yfwk6UywPFOM8Xbh2Sy8g7zwvCKUeUlghzr9oEvPoD-K_uN7TilGs | 
    
| CODEN | LAPHEJ | 
    
| Cites_doi | 10.1016/j.sab.2022.106576 10.1007/s00256-019-03171-7 10.1186/s13007-022-00883-1 10.1364/OE.27.00A790 10.1080/00032719.2022.2067862 10.1088/2058-6272/ac5afa 10.1039/C8RA08158A 10.1364/OE.443732 10.1016/j.chemolab.2022.104691 10.1016/j.optlaseng.2020.106010 10.1016/j.compag.2022.106986 10.1080/10739149.2022.2087185 10.1088/1612-202X/aaea6e 10.1080/00032719.2022.2052307 10.1021/acssuschemeng.7b04796 10.1039/D1JA00250C 10.1364/OE.400324 10.1016/j.sab.2022.106567 10.1080/10739149.2022.2080705 10.1080/00032719.2021.1972118 10.1088/2058-6272/ac639b  | 
    
| ContentType | Journal Article | 
    
| Copyright | 2024 Astro Ltd. All rights, including for text and data mining, AI training, and similar technologies, are reserved. | 
    
| Copyright_xml | – notice: 2024 Astro Ltd. All rights, including for text and data mining, AI training, and similar technologies, are reserved. | 
    
| DBID | AAYXX CITATION  | 
    
| DOI | 10.1088/1555-6611/ad3429 | 
    
| DatabaseName | CrossRef | 
    
| DatabaseTitle | CrossRef | 
    
| DatabaseTitleList | CrossRef | 
    
| DeliveryMethod | fulltext_linktorsrc | 
    
| Discipline | Physics | 
    
| EISSN | 1555-6611 | 
    
| ExternalDocumentID | 10_1088_1555_6611_ad3429 lpad3429  | 
    
| GroupedDBID | 0R~ 0VY 1N0 29L 4.4 408 40D 5GY 6NX AAGCD AAJIO AATNI ABHWH ABIJN ABJNI ABVAM ACGFS ACHIP ACREN ADEQX ADWVK AEINN AENEX AFBBN AFYNE AHBYD AKPSB ALMA_UNASSIGNED_HOLDINGS AMTXH AOAED ATQHT BA0 CEBXE CJUJL CRLBU CS3 EBS F5P IIPPG IJHAN IOP IZVLO KOT N5L P9T PJBAE QOS R9I RIN ROL RPA RSV S27 S3B SDH SOJ SY9 T13 WK8 AAYXX CITATION  | 
    
| ID | FETCH-LOGICAL-c264t-26d8b57c4f883949ca96438d166d762e6734b66c3a9710582a2156d84b1353353 | 
    
| IEDL.DBID | IOP | 
    
| ISSN | 1054-660X | 
    
| IngestDate | Wed Oct 01 05:43:22 EDT 2025 Tue Jul 29 22:11:10 EDT 2025 Tue Aug 20 22:16:35 EDT 2024  | 
    
| IsPeerReviewed | true | 
    
| IsScholarly | true | 
    
| Issue | 5 | 
    
| Language | English | 
    
| License | This article is available under the terms of the IOP-Standard License. | 
    
| LinkModel | DirectLink | 
    
| MergedId | FETCHMERGED-LOGICAL-c264t-26d8b57c4f883949ca96438d166d762e6734b66c3a9710582a2156d84b1353353 | 
    
| Notes | 2023LPL0276 | 
    
| PageCount | 9 | 
    
| ParticipantIDs | crossref_primary_10_1088_1555_6611_ad3429 iop_journals_10_1088_1555_6611_ad3429  | 
    
| ProviderPackageCode | CITATION AAYXX  | 
    
| PublicationCentury | 2000 | 
    
| PublicationDate | 2024-05-01 | 
    
| PublicationDateYYYYMMDD | 2024-05-01 | 
    
| PublicationDate_xml | – month: 05 year: 2024 text: 2024-05-01 day: 01  | 
    
| PublicationDecade | 2020 | 
    
| PublicationTitle | Laser physics | 
    
| PublicationTitleAbbrev | LP | 
    
| PublicationTitleAlternate | Laser Phys | 
    
| PublicationYear | 2024 | 
    
| Publisher | IOP Publishing | 
    
| Publisher_xml | – name: IOP Publishing | 
    
| References | Li (lpad3429bib7) 2022; 18 Atta (lpad3429bib1) 2018; 15 Ren (lpad3429bib14) 2022; 197 Musyoka (lpad3429bib19) 2022; 55 Cherni (lpad3429bib17) 2023; 51 Ward (lpad3429bib21) 2019; 48 Rao (lpad3429bib9) 2022; 198 Feng (lpad3429bib15) 2022; 231 Cao (lpad3429bib18) 2023; 51 Forte (lpad3429bib3) 2019; 9 Gąsior (lpad3429bib13) 2023; 199 Akhtar (lpad3429bib8) 2022; 55 Amjad (lpad3429bib2) 2020; 128 Ahmed (lpad3429bib5) 2022; 55 Zhang (lpad3429bib6) 2022; 24 Zhang (lpad3429bib11) 2020; 28 Zhang (lpad3429bib16) 2022; 24 National Institute of Standards and Technology (lpad3429bib20) Liu (lpad3429bib22) 2021; 36 Yin (lpad3429bib4) 2018; 6 Qu (lpad3429bib12) 2019; 27 Zhou (lpad3429bib10) 2021; 29  | 
    
| References_xml | – volume: 199 year: 2023 ident: lpad3429bib13 article-title: Analysis of hydrogen isotopes retention in thermonuclear reactors with LIBS supported by machine learning publication-title: Spectrochim. Acta B doi: 10.1016/j.sab.2022.106576 – volume: 48 start-page: 1393 year: 2019 ident: lpad3429bib21 article-title: Image intensifier distortion influences a surgeon’s ability to aim guidewires during orthopaedical procedures publication-title: Skeletal Radiol. doi: 10.1007/s00256-019-03171-7 – volume: 18 start-page: 52 year: 2022 ident: lpad3429bib7 article-title: Research on anthracnose grade of Camellia oleifera based on the combined LIBS and THz technology publication-title: Plant Methods doi: 10.1186/s13007-022-00883-1 – volume: 27 start-page: 790 year: 2019 ident: lpad3429bib12 article-title: Real-time in situ detection of the local air pollution with laser-induced breakdown spectroscopy publication-title: Opt. Express doi: 10.1364/OE.27.00A790 – volume: 55 start-page: 2669 year: 2022 ident: lpad3429bib19 article-title: Direct analysis of blood for diagnostic metals for malaria by peak-free laser-induced breakdown spectroscopy (LIBS) with artificial neural networks (ANN) and partial least squares (PLS) publication-title: Anal. Lett. doi: 10.1080/00032719.2022.2067862 – volume: 24 start-page: 31 year: 2022 ident: lpad3429bib16 article-title: Fast identification of mural pigments at Mogao Grottoes using a LIBS-based spectral matching algorithm publication-title: Plasma Sci. Technol. doi: 10.1088/2058-6272/ac5afa – volume: 9 start-page: 1378 year: 2019 ident: lpad3429bib3 article-title: Integrated process for the recovery of yttrium and europium from CRT phosphor waste publication-title: RSC Adv. doi: 10.1039/C8RA08158A – volume: 29 start-page: 39811 year: 2021 ident: lpad3429bib10 article-title: Real-time monitoring of carbon concentration using laser-induced breakdown spectroscopy and machine learning publication-title: Opt. Express doi: 10.1364/OE.443732 – volume: 231 year: 2022 ident: lpad3429bib15 article-title: Discrimination of the pollution grade of metal elements in atmospherically deposited particulate matter via laser-induced breakdown spectroscopy combined with mach ine learning method publication-title: Chemometr. Intell. Lab. doi: 10.1016/j.chemolab.2022.104691 – volume: 128 year: 2020 ident: lpad3429bib2 article-title: Novel two-dimensional phosphor thermography by decay-time method using a low frame-rate CMOS camera publication-title: Opt. Laser Eng. doi: 10.1016/j.optlaseng.2020.106010 – volume: 197 year: 2022 ident: lpad3429bib14 article-title: LIBS in agriculture: a review focusing on revealing nutritional and toxic elements in soil, water, and crops publication-title: Comput. Electron. Agric. doi: 10.1016/j.compag.2022.106986 – volume: 51 start-page: 59 year: 2023 ident: lpad3429bib18 article-title: Rapid classification of coal by laser-induced breakdown spectroscopy (LIBS) with K-nearest neighbor (KNN) chemometrics publication-title: Instrum. Sci. Technol. doi: 10.1080/10739149.2022.2087185 – ident: lpad3429bib20 – volume: 15 year: 2018 ident: lpad3429bib1 article-title: Determination of zinc and iron in wheat using laser-induced breakdown spectroscopy publication-title: Laser Phys. Lett. doi: 10.1088/1612-202X/aaea6e – volume: 55 start-page: 2239 year: 2022 ident: lpad3429bib5 article-title: Analysis of an iron-copper alloy by calibration-free laser-induced breakdown spectroscopy (CF-LIBS) and inductively coupled plasma-mass spectrometry (ICP-MS) publication-title: Anal. Lett. doi: 10.1080/00032719.2022.2052307 – volume: 6 start-page: 4321 year: 2018 ident: lpad3429bib4 article-title: Reclamation and harmless treatment of waste cathode ray tube phosphors: novel and sustainable design publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.7b04796 – volume: 36 start-page: 2480 year: 2021 ident: lpad3429bib22 article-title: Determination of lead in aqueous solutions using resonant surface-enhanced LIBS publication-title: J. Anal. Atom. Spectrom. doi: 10.1039/D1JA00250C – volume: 28 start-page: 22844 year: 2020 ident: lpad3429bib11 article-title: Online detection of halogen atoms in atmospheric VOCs by the LIBS-SPAMS technique publication-title: Opt. Express doi: 10.1364/OE.400324 – volume: 198 year: 2022 ident: lpad3429bib9 article-title: A combination of spectrum selection and machine learning regression for minor element determination in gravel stones with LIBS publication-title: Spectrochim. Acta B doi: 10.1016/j.sab.2022.106567 – volume: 51 start-page: 16 year: 2023 ident: lpad3429bib17 article-title: Noninvasive diagnosis of type 2 diabetes mellitus by hair analysis using laser-induced breakdown spectroscopy (LIBS) publication-title: Instrum. Sci. Technol. doi: 10.1080/10739149.2022.2080705 – volume: 55 start-page: 904 year: 2022 ident: lpad3429bib8 article-title: Elemental analysis of cement and its components by laser-induced breakdown spectroscopy (LIBS) and laser ablation time of flight mass spectrometry (LA-TOF-MS) publication-title: Anal. Lett. doi: 10.1080/00032719.2021.1972118 – volume: 24 start-page: 22 year: 2022 ident: lpad3429bib6 article-title: Rapid identification of volatile organic compounds and their isomers in the atmosphere publication-title: Plasma Sci. Technol. doi: 10.1088/2058-6272/ac639b  | 
    
| SSID | ssj0044401 | 
    
| Score | 2.3603256 | 
    
| Snippet | Rapid detection and quality monitoring of phosphor materials have always been a difficult problem in phosphor materials market. In this work, an independently... | 
    
| SourceID | crossref iop  | 
    
| SourceType | Index Database Enrichment Source Publisher  | 
    
| StartPage | 55701 | 
    
| SubjectTerms | BPNN LIBS PCA phosphor rapid detection and identification  | 
    
| Title | Rapid detection and recognition of phosphors using laser-induced breakdown spectroscopy and principal component analysis method—back propagation neural network algorithm | 
    
| URI | https://iopscience.iop.org/article/10.1088/1555-6611/ad3429 | 
    
| Volume | 34 | 
    
| hasFullText | 1 | 
    
| inHoldings | 1 | 
    
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVIOP databaseName: IOP Science Platform customDbUrl: eissn: 1555-6611 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0044401 issn: 1054-660X databaseCode: IOP dateStart: 20130101 isFulltext: true titleUrlDefault: https://iopscience.iop.org/ providerName: IOP Publishing – providerCode: PRVLSH databaseName: SpringerLink Journals customDbUrl: mediaType: online eissn: 1555-6611 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0044401 issn: 1054-660X databaseCode: AFBBN dateStart: 20060101 isFulltext: true providerName: Library Specific Holdings  | 
    
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3LatwwFBWThEA3fSYkfaRatIsuPDN-yQpdlZIwBJKU0oFZBIRenoRJbTPjLJpVPqJ_0b_ql_RI8oQkhBAKNtjmWhKSrHuudXREyIeElarkUkfcTRwC_xeRZNpNOCpVFEpzmbq1w4dHbDTODib5pEc-X6-FqZtu6O_jMggFhyrsCHF8AA-YR3Ar8UCaFMPpCllLOYCxW713_G05DGfI20dbwCSwHk66Ocr7Urjlk1aQ7w0Xs_-MnCwLF5gls_5Fq_r68o5u43-W_jl52kFP-iWYviA9W70k654CqhevyJ_vsjkz1NjWs7MqKitDr_lFuK9L2pzWC5zzBXV8-SkF9LbzCGE9OoihiK7lzCCsp379ptPJrJtfPp0m_NNH9o7DXldwdXge9FBo2MX679VvJfUMpojjp77DUKe2iXeqwFWn8nxaz8_a058bZLy_9-PrKOq2cog0EFcbJcxwlRc6KzkQWbarpdMB4yZmzGA4tqxIM8WYTuUuIE_OEwkogncy5fblwLFJVisUbotQRHix1dap-gBeDBXnlg91Io01cVrGyTb5tGxM0QTFDuFn2jkXrvKFq3wRKn-bfEQ7ie6zXTxg9_6W3Xkj0kzkwguYxaIx5etHpvSGPEkAiwJl8i1ZbecX9h1gTat2fPf9BzKb83E | 
    
| linkProvider | IOP Publishing | 
    
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3dTtRAGJ0IRsMNCmoEVOYCLrzo7vZvOlwaZYMKSAwkezfOXxey0Da75QKueAjfgrfySTwz0zVCjDExaZO2mZ-233S-83XOnCFkK2GlKrnUEXcDh8D_RSSZdgOOShWF0lymbu7wwSHbO8k-jfJRt86pnwtTN13X38NhEAoOr7AjxPE-PGAewa3EfWlSdKf9xpQL5KHXKXEz-L4czbviDPX7iAu4BDkGo26c8k-l3PFLC6j7NzczfEK-zW8wsEsmvctW9fT1Pe3G_3iCp2S5g6D0XUi-Qh7YapU88lRQPXtGbr_K5sxQY1vP0qqorAz9xTPCeV3S5rSeYZ_OqOPNjykguJ1GCO_RUAxFlC0nBuE99fM4nV5m3Vz5cprwbx_VOy57XcHl4XrQRaFhNesfN9-V1BMkRTw_9g2HOtVN5KkCZ53K83E9PWtPL56Tk-Hu8fu9qFvSIdJAXm2UMMNVXuis5EBm2Y6WTg-Mm5gxg27ZsiLNFGM6lTuAPjlPJCAJ8mTKrc-B7QVZrHBzLwlFpBdbbZ26D2DGQHFu-UAn0lgTp2WcrJG3c4OKJih3CD_izrlwBhDOACIYYI1sw1ai-3xnf0m3eSfdeSPSTOTCC5nFAmZc_8eSNsnjow9Dsf_x8PMGWUqAlAKL8hVZbKeX9jWQTqve-Nb8E4ST-NI | 
    
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Rapid+detection+and+recognition+of+phosphors+using+laser-induced+breakdown+spectroscopy+and+principal+component+analysis+method%E2%80%94back+propagation+neural+network+algorithm&rft.jtitle=Laser+physics&rft.au=Shen%2C+Lingbin&rft.au=Tian%2C+Liping&rft.au=Yao%2C+Hongbing&rft.au=Tian%2C+Dongpeng&rft.date=2024-05-01&rft.issn=1054-660X&rft.eissn=1555-6611&rft.volume=34&rft.issue=5&rft.spage=55701&rft_id=info:doi/10.1088%2F1555-6611%2Fad3429&rft.externalDBID=n%2Fa&rft.externalDocID=10_1088_1555_6611_ad3429 | 
    
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1054-660X&client=summon | 
    
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1054-660X&client=summon | 
    
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1054-660X&client=summon |