Design of PtZn nanoalloy catalysts for propane dehydrogenation through interface tailoring via atomic layer deposition
Supported Pt nanoparticles are widely used for the catalytic dehydrogenation of propane to propene. Monometallic Pt catalysts are subject to fast deactivation. A successful strategy for stabilization is alloying Pt with a second metal. In this study, we present a novel approach for the precise forma...
Saved in:
| Published in | Catalysis science & technology Vol. 11; no. 2; pp. 484 - 493 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
01.01.2021
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 2044-4753 2044-4761 |
| DOI | 10.1039/D0CY01528H |
Cover
| Abstract | Supported Pt nanoparticles are widely used for the catalytic dehydrogenation of propane to propene. Monometallic Pt catalysts are subject to fast deactivation. A successful strategy for stabilization is alloying Pt with a second metal. In this study, we present a novel approach for the precise formation of bimetallic nanoparticles
via
tailoring of the interface between metal nanoparticles and the support. An ultra-thin functional layer of ZnO is deposited
via
atomic layer deposition on SiO
2
. The supported Pt nanoparticles undergo a phase transformation and form Pt
1
Zn
1
alloy nanoparticles under reductive thermal treatment. The resulting Pt
1
Zn
1
catalyst showed a high and stable selectivity to propene over 12 hours of time on stream. The activity of the Pt
1
Zn
1
catalyst was 1.5 times higher than that of a catalyst of the same composition prepared by incipient wetness impregnation. The nanoalloy formation causes electronic and geometric modification of Pt which reduces side reactions and leads to a stable and active propane dehydrogenation catalyst. |
|---|---|
| AbstractList | Supported Pt nanoparticles are widely used for the catalytic dehydrogenation of propane to propene. Monometallic Pt catalysts are subject to fast deactivation. A successful strategy for stabilization is alloying Pt with a second metal. In this study, we present a novel approach for the precise formation of bimetallic nanoparticles
via
tailoring of the interface between metal nanoparticles and the support. An ultra-thin functional layer of ZnO is deposited
via
atomic layer deposition on SiO
2
. The supported Pt nanoparticles undergo a phase transformation and form Pt
1
Zn
1
alloy nanoparticles under reductive thermal treatment. The resulting Pt
1
Zn
1
catalyst showed a high and stable selectivity to propene over 12 hours of time on stream. The activity of the Pt
1
Zn
1
catalyst was 1.5 times higher than that of a catalyst of the same composition prepared by incipient wetness impregnation. The nanoalloy formation causes electronic and geometric modification of Pt which reduces side reactions and leads to a stable and active propane dehydrogenation catalyst. Supported Pt nanoparticles are widely used for the catalytic dehydrogenation of propane to propene. Monometallic Pt catalysts are subject to fast deactivation. A successful strategy for stabilization is alloying Pt with a second metal. In this study, we present a novel approach for the precise formation of bimetallic nanoparticles via tailoring of the interface between metal nanoparticles and the support. An ultra-thin functional layer of ZnO is deposited via atomic layer deposition on SiO2. The supported Pt nanoparticles undergo a phase transformation and form Pt1Zn1 alloy nanoparticles under reductive thermal treatment. The resulting Pt1Zn1 catalyst showed a high and stable selectivity to propene over 12 hours of time on stream. The activity of the Pt1Zn1 catalyst was 1.5 times higher than that of a catalyst of the same composition prepared by incipient wetness impregnation. The nanoalloy formation causes electronic and geometric modification of Pt which reduces side reactions and leads to a stable and active propane dehydrogenation catalyst. |
| Author | Knemeyer, Kristian Naumann d'Alnoncourt, Raoul Ingale, Piyush Preikschas, Phil Ye, Mengyang Thomas, Arne Geske, Michael Rosowski, Frank |
| Author_xml | – sequence: 1 givenname: Piyush orcidid: 0000-0002-3535-4234 surname: Ingale fullname: Ingale, Piyush organization: BasCat – UniCat BASF JointLab, Technische Universität Berlin, Berlin 10623, Germany – sequence: 2 givenname: Kristian orcidid: 0000-0001-7980-9280 surname: Knemeyer fullname: Knemeyer, Kristian organization: BasCat – UniCat BASF JointLab, Technische Universität Berlin, Berlin 10623, Germany – sequence: 3 givenname: Phil surname: Preikschas fullname: Preikschas, Phil organization: BasCat – UniCat BASF JointLab, Technische Universität Berlin, Berlin 10623, Germany – sequence: 4 givenname: Mengyang surname: Ye fullname: Ye, Mengyang organization: Functional Materials, Department of Chemistry, Technische Universität Berlin, Berlin 10623, Germany – sequence: 5 givenname: Michael surname: Geske fullname: Geske, Michael organization: BasCat – UniCat BASF JointLab, Technische Universität Berlin, Berlin 10623, Germany – sequence: 6 givenname: Raoul orcidid: 0000-0002-9946-4619 surname: Naumann d'Alnoncourt fullname: Naumann d'Alnoncourt, Raoul organization: BasCat – UniCat BASF JointLab, Technische Universität Berlin, Berlin 10623, Germany – sequence: 7 givenname: Arne orcidid: 0000-0002-2130-4930 surname: Thomas fullname: Thomas, Arne organization: Functional Materials, Department of Chemistry, Technische Universität Berlin, Berlin 10623, Germany – sequence: 8 givenname: Frank surname: Rosowski fullname: Rosowski, Frank organization: BasCat – UniCat BASF JointLab, Technische Universität Berlin, Berlin 10623, Germany, BASF SE |
| BookMark | eNptkE1LAzEQhoMoWGsv_oKAN2E1X_t1lFatUNCDHvSyZLOTNmWbrEla2H_v1oqCOJeZw_vMzPueoWPrLCB0Qck1Jby8mZHpG6EpK-ZHaMSIEInIM3r8M6f8FE1CWJOhRElJwUZoN4NglhY7jZ_ju8VWWifb1vVYySjbPsSAtfO4866TFnADq77xbglWRuMsjivvtssVNjaC11IBjtK0zhu7xDsjsYxuYxRuZQ9-gDsXzJ47RydatgEm332MXu_vXqbzZPH08Di9XSSKZSwmeZmmGZMiV5owKKDMaiVTlmsqeJaLrOBlnpZZUzeM1blUiuqac1JQJWoAIHyMLg97h_8_thBitXZbb4eTFROFyARPRTGoyEGlvAvBg66UiV_-oh_cVJRU-4Cr34AH5OoP0nmzkb7_T_wJk4h-_w |
| CitedBy_id | crossref_primary_10_1021_acscatal_4c02517 crossref_primary_10_1021_acsanm_3c03572 crossref_primary_10_3390_catal14120950 crossref_primary_10_3390_nano12091458 crossref_primary_10_1021_acscatal_3c05419 crossref_primary_10_1016_S1872_2067_23_64548_6 crossref_primary_10_1039_D2NR02208G crossref_primary_10_3390_catal11091070 crossref_primary_10_1002_anie_202409556 crossref_primary_10_1016_j_fuel_2023_129421 crossref_primary_10_1039_D3QM00760J crossref_primary_10_1002_cctc_202201405 crossref_primary_10_1002_anie_202319887 crossref_primary_10_1016_j_apcata_2024_119800 crossref_primary_10_1021_acs_energyfuels_4c00469 crossref_primary_10_1002_ange_202409556 crossref_primary_10_1039_D2CP04173A crossref_primary_10_1016_j_fuel_2022_124833 crossref_primary_10_1002_cite_202200085 crossref_primary_10_1021_acs_iecr_3c02161 crossref_primary_10_1021_acscatal_1c01808 crossref_primary_10_1038_s41467_024_52518_9 crossref_primary_10_1021_acscatal_4c02067 crossref_primary_10_1039_D1CS01036K crossref_primary_10_1016_j_mcat_2024_114029 crossref_primary_10_1021_acs_energyfuels_3c02887 crossref_primary_10_2174_1573413718666220616090013 crossref_primary_10_1007_s10563_023_09399_7 crossref_primary_10_1016_j_xcrp_2023_101311 crossref_primary_10_1021_acscatal_2c01631 crossref_primary_10_1021_acsomega_3c02675 crossref_primary_10_1007_s40843_022_2251_8 crossref_primary_10_1039_D1CY00606A crossref_primary_10_1007_s12274_024_6574_9 crossref_primary_10_1002_ange_202319887 crossref_primary_10_1021_acs_jpcc_4c05898 crossref_primary_10_1002_cctc_202301261 crossref_primary_10_1039_D3CP01659E crossref_primary_10_1016_j_fuel_2022_125858 crossref_primary_10_1016_j_jcat_2024_115647 crossref_primary_10_1021_acs_chemmater_3c00668 crossref_primary_10_1016_j_apcatb_2021_120634 crossref_primary_10_1021_acscatal_4c01740 crossref_primary_10_21926_cr_2302018 crossref_primary_10_1016_j_cattod_2025_115283 crossref_primary_10_1016_j_fuel_2024_131730 crossref_primary_10_1021_acs_chemrev_3c00081 crossref_primary_10_1039_D2CY02184F |
| Cites_doi | 10.1021/acscatal.6b03603 10.1002/anie.201404460 10.1007/s11814-009-0233-4 10.1116/1.4936390 10.1116/1.5140603 10.1021/acscatal.5b02878 10.1021/cs200441e 10.1021/jacs.8b05378 10.1021/acscatal.5b02917 10.1016/j.surfrep.2016.03.003 10.1021/cr900056b 10.1039/c3cp50646k 10.1039/C4NR02143F 10.1021/j100784a023 10.1007/s11051-018-4442-9 10.1016/S0926-860X(01)00816-X 10.1021/cs401116p 10.1039/D0CY00304B 10.1021/cs501862h 10.1039/C5CP05043J 10.1002/cctc.201801708 10.1021/cs501279v 10.3390/ma7042833 10.1126/sciadv.aar5418 10.1016/j.jcat.2016.10.017 10.1039/C9SC05599A 10.1016/j.tsf.2007.11.044 10.3390/nano10050981 10.1021/acscatal.9b00549 10.1016/S1381-1169(00)00402-7 10.1021/acs.iecr.8b01313 10.1080/15567249.2019.1607631 10.1002/anie.201800557 10.1016/j.jcat.2016.06.006 10.1063/1.5133390 10.1039/9781847553232-00379 10.1007/s11666-009-9364-8 10.1007/s11244-012-9912-1 10.1007/s11244-011-9708-8 10.1016/j.cattod.2020.04.050 10.1021/am100940g 10.1002/cctc.201901869 10.1063/1.469475 10.1080/2055074X.2016.1263177 10.1021/jacs.8b08162 10.1039/C9CY00237E 10.1016/j.apcata.2011.03.009 10.1016/j.cherd.2011.11.004 10.1007/s11244-012-9917-9 10.1021/acs.iecr.9b01413 10.1126/science.1212906 10.1038/srep08470 10.3390/nano8060365 10.1021/cr5002436 10.1021/acscatal.8b02794 |
| ContentType | Journal Article |
| Copyright | Copyright Royal Society of Chemistry 2021 |
| Copyright_xml | – notice: Copyright Royal Society of Chemistry 2021 |
| DBID | AAYXX CITATION 7SR 8BQ 8FD JG9 |
| DOI | 10.1039/D0CY01528H |
| DatabaseName | CrossRef Engineered Materials Abstracts METADEX Technology Research Database Materials Research Database |
| DatabaseTitle | CrossRef Materials Research Database Engineered Materials Abstracts Technology Research Database METADEX |
| DatabaseTitleList | CrossRef Materials Research Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 2044-4761 |
| EndPage | 493 |
| ExternalDocumentID | 10_1039_D0CY01528H |
| GroupedDBID | 0-7 0R~ 705 AAEMU AAIWI AAJAE AANOJ AARTK AAWGC AAXHV AAYXX ABASK ABDVN ABEMK ABJNI ABPDG ABRYZ ABXOH ACAYK ACGFS ACIWK ACLDK ADMRA ADSRN AEFDR AENEX AENGV AESAV AETIL AFLYV AFOGI AFRZK AFVBQ AGEGJ AGRSR AHGCF AKBGW AKMSF ALMA_UNASSIGNED_HOLDINGS ANUXI APEMP ASKNT AUDPV BLAPV BSQNT C6K CITATION EBS ECGLT EE0 EF- GGIMP H13 HZ~ H~N J3I O-G O9- OK1 R7G RAOCF RCNCU RNS RPMJG RRC RSCEA RVUXY SKA SKF SKH SKJ SKM SKR SKZ SLC SLF SLH 7SR 8BQ 8FD JG9 |
| ID | FETCH-LOGICAL-c262t-795562a47cf02e8e96bca527f14367468397596dbd22b7acc1fb33081c4beee03 |
| ISSN | 2044-4753 |
| IngestDate | Mon Jun 30 04:10:01 EDT 2025 Tue Jul 01 02:28:36 EDT 2025 Thu Apr 24 23:05:42 EDT 2025 |
| IsDoiOpenAccess | false |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 2 |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c262t-795562a47cf02e8e96bca527f14367468397596dbd22b7acc1fb33081c4beee03 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 |
| ORCID | 0000-0002-2130-4930 0000-0001-7980-9280 0000-0002-3535-4234 0000-0002-9946-4619 |
| OpenAccessLink | https://pubs.rsc.org/en/content/articlepdf/2021/cy/d0cy01528h |
| PQID | 2484643548 |
| PQPubID | 2047527 |
| PageCount | 10 |
| ParticipantIDs | proquest_journals_2484643548 crossref_citationtrail_10_1039_D0CY01528H crossref_primary_10_1039_D0CY01528H |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 20210101 |
| PublicationDateYYYYMMDD | 2021-01-01 |
| PublicationDate_xml | – month: 01 year: 2021 text: 20210101 day: 01 |
| PublicationDecade | 2020 |
| PublicationPlace | Cambridge |
| PublicationPlace_xml | – name: Cambridge |
| PublicationTitle | Catalysis science & technology |
| PublicationYear | 2021 |
| Publisher | Royal Society of Chemistry |
| Publisher_xml | – name: Royal Society of Chemistry |
| References | Strempel (D0CY01528H-(cit39)/*[position()=1]) 2018; 8 Ma (D0CY01528H-(cit18)/*[position()=1]) 2017; 3 Vora (D0CY01528H-(cit2)/*[position()=1]) 2012; 55 Sinfelt (D0CY01528H-(cit42)/*[position()=1]) 1964; 68 Cortright (D0CY01528H-(cit43)/*[position()=1]) 2000; 163 Bhasin (D0CY01528H-(cit4)/*[position()=1]) 2001; 221 Camacho-Bunquin (D0CY01528H-(cit52)/*[position()=1]) 2018; 20 Lu (D0CY01528H-(cit56)/*[position()=1]) 2016; 71 Cesar (D0CY01528H-(cit19)/*[position()=1]) 2019 Jiang (D0CY01528H-(cit21)/*[position()=1]) 2015; 5 Iida (D0CY01528H-(cit41)/*[position()=1]) 2018; 57 Richey (D0CY01528H-(cit54)/*[position()=1]) 2020; 152 Almutairi (D0CY01528H-(cit46)/*[position()=1]) 2012; 2 Gong (D0CY01528H-(cit27)/*[position()=1]) 2016; 18 Cybulskis (D0CY01528H-(cit15)/*[position()=1]) 2017; 7 Sattler (D0CY01528H-(cit6)/*[position()=1]) 2014; 114 Belskaya (D0CY01528H-(cit24)/*[position()=1]) 2016; 341 Bricker (D0CY01528H-(cit1)/*[position()=1]) 2012; 55 Rahimi (D0CY01528H-(cit22)/*[position()=1]) 2011; 398 George (D0CY01528H-(cit29)/*[position()=1]) 2010; 110 Resasco (D0CY01528H-(cit5)/*[position()=1]) 2007; vol. 11 Wang (D0CY01528H-(cit7)/*[position()=1]) 2018; 57 Libera (D0CY01528H-(cit57)/*[position()=1]) 2008; 516 Kim (D0CY01528H-(cit3)/*[position()=1]) 2019; 14 Chen (D0CY01528H-(cit14)/*[position()=1]) 2019; 9 Weimer (D0CY01528H-(cit53)/*[position()=1]) 2019; 21 Ingale (D0CY01528H-(cit37)/*[position()=1]) 2020; 10 Doll (D0CY01528H-(cit59)/*[position()=1]) 2010; 19 Sahebdelfar (D0CY01528H-(cit11)/*[position()=1]) 2012; 90 Wegener (D0CY01528H-(cit48)/*[position()=1]) 2020; 12 Cai (D0CY01528H-(cit50)/*[position()=1]) 2018; 4 Schweitzer (D0CY01528H-(cit47)/*[position()=1]) 2014; 4 Ingale (D0CY01528H-(cit32)/*[position()=1]) Lu (D0CY01528H-(cit31)/*[position()=1]) 2012; 335 Wu (D0CY01528H-(cit20)/*[position()=1]) 2018; 140 Sattler (D0CY01528H-(cit12)/*[position()=1]) 2014; 53 Strempel (D0CY01528H-(cit38)/*[position()=1]) 2017 Almutairi (D0CY01528H-(cit44)/*[position()=1]) 2012; 2 Han (D0CY01528H-(cit17)/*[position()=1]) 2014; 6 Oneill (D0CY01528H-(cit30)/*[position()=1]) 2015; 5 Kolodziejczak-Radzimska (D0CY01528H-(cit23)/*[position()=1]) 2014; 7 Rodriguez (D0CY01528H-(cit40)/*[position()=1]) 1995; 102 Qiu (D0CY01528H-(cit49)/*[position()=1]) 2019; 58 Chen (D0CY01528H-(cit26)/*[position()=1]) 2019; 11 Jur (D0CY01528H-(cit35)/*[position()=1]) 2011; 3 Rochlitz (D0CY01528H-(cit51)/*[position()=1]) 2020; 11 Pham (D0CY01528H-(cit10)/*[position()=1]) 2016; 6 Nawaz (D0CY01528H-(cit25)/*[position()=1]) 2009; 26 Li (D0CY01528H-(cit8)/*[position()=1]) 2011; 54 Cao (D0CY01528H-(cit33)/*[position()=1]) 2014; 5 Sønsteby (D0CY01528H-(cit58)/*[position()=1]) 2020; 38 Camacho-Bunquin (D0CY01528H-(cit28)/*[position()=1]) 2017; 345 Liu (D0CY01528H-(cit16)/*[position()=1]) 2016; 6 Strempel (D0CY01528H-(cit34)/*[position()=1]) 2016; 34 Gong (D0CY01528H-(cit45)/*[position()=1]) 2016; 18 Lu (D0CY01528H-(cit36)/*[position()=1]) 2016; 71 Searles (D0CY01528H-(cit13)/*[position()=1]) 2018; 140 Sattler (D0CY01528H-(cit9)/*[position()=1]) 2013; 15 Cao (D0CY01528H-(cit55)/*[position()=1]) 2020; 10 |
| References_xml | – volume: 7 start-page: 4173 year: 2017 ident: D0CY01528H-(cit15)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/acscatal.6b03603 – volume: 53 start-page: 9251 year: 2014 ident: D0CY01528H-(cit12)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201404460 – volume: 26 start-page: 1528 year: 2009 ident: D0CY01528H-(cit25)/*[position()=1] publication-title: Korean J. Chem. Eng. doi: 10.1007/s11814-009-0233-4 – volume: 34 start-page: 01A135 year: 2016 ident: D0CY01528H-(cit34)/*[position()=1] publication-title: J. Vac. Sci. Technol., A doi: 10.1116/1.4936390 – volume: 38 start-page: 020804 year: 2020 ident: D0CY01528H-(cit58)/*[position()=1] publication-title: J. Vac. Sci. Technol., A doi: 10.1116/1.5140603 – volume: 6 start-page: 2158 year: 2016 ident: D0CY01528H-(cit16)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/acscatal.5b02878 – volume: 2 start-page: 71 year: 2012 ident: D0CY01528H-(cit46)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/cs200441e – volume: 140 start-page: 11674 year: 2018 ident: D0CY01528H-(cit13)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.8b05378 – volume: 6 start-page: 2257 year: 2016 ident: D0CY01528H-(cit10)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/acscatal.5b02917 – volume: 71 start-page: 410 year: 2016 ident: D0CY01528H-(cit36)/*[position()=1] publication-title: Surf. Sci. Rep. doi: 10.1016/j.surfrep.2016.03.003 – volume: 110 start-page: 111 year: 2010 ident: D0CY01528H-(cit29)/*[position()=1] publication-title: Chem. Rev. doi: 10.1021/cr900056b – volume: 15 start-page: 12095 year: 2013 ident: D0CY01528H-(cit9)/*[position()=1] publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/c3cp50646k – volume: 6 start-page: 10000 year: 2014 ident: D0CY01528H-(cit17)/*[position()=1] publication-title: Nanoscale doi: 10.1039/C4NR02143F – volume: 68 start-page: 344 year: 1964 ident: D0CY01528H-(cit42)/*[position()=1] publication-title: J. Phys. Chem. doi: 10.1021/j100784a023 – volume: 21 start-page: 9 year: 2019 ident: D0CY01528H-(cit53)/*[position()=1] publication-title: J. Nanopart. Res. doi: 10.1007/s11051-018-4442-9 – volume: 221 start-page: 397 year: 2001 ident: D0CY01528H-(cit4)/*[position()=1] publication-title: Appl. Catal., A doi: 10.1016/S0926-860X(01)00816-X – volume: 4 start-page: 1091 year: 2014 ident: D0CY01528H-(cit47)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/cs401116p – volume: 10 start-page: 2695 year: 2020 ident: D0CY01528H-(cit55)/*[position()=1] publication-title: Cite this Catal. Sci. Technol. doi: 10.1039/D0CY00304B – volume: 5 start-page: 1804 year: 2015 ident: D0CY01528H-(cit30)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/cs501862h – volume: 18 start-page: 601 year: 2016 ident: D0CY01528H-(cit27)/*[position()=1] publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/C5CP05043J – volume: 11 start-page: 868 year: 2019 ident: D0CY01528H-(cit26)/*[position()=1] publication-title: ChemCatChem doi: 10.1002/cctc.201801708 – volume: 5 start-page: 438 year: 2015 ident: D0CY01528H-(cit21)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/cs501279v – volume: 7 start-page: 2833 year: 2014 ident: D0CY01528H-(cit23)/*[position()=1] publication-title: Materials doi: 10.3390/ma7042833 – volume: 4 start-page: eaar5418 year: 2018 ident: D0CY01528H-(cit50)/*[position()=1] publication-title: Sci. Adv. doi: 10.1126/sciadv.aar5418 – volume: 345 start-page: 170 year: 2017 ident: D0CY01528H-(cit28)/*[position()=1] publication-title: J. Catal. doi: 10.1016/j.jcat.2016.10.017 – volume: 11 start-page: 1549 year: 2020 ident: D0CY01528H-(cit51)/*[position()=1] publication-title: Chem. Sci. doi: 10.1039/C9SC05599A – volume: 516 start-page: 6158 year: 2008 ident: D0CY01528H-(cit57)/*[position()=1] publication-title: Thin Solid Films doi: 10.1016/j.tsf.2007.11.044 – volume: 10 start-page: 981 year: 2020 ident: D0CY01528H-(cit37)/*[position()=1] publication-title: Nanomaterials doi: 10.3390/nano10050981 – start-page: 5231 year: 2019 ident: D0CY01528H-(cit19)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/acscatal.9b00549 – volume: 163 start-page: 91 year: 2000 ident: D0CY01528H-(cit43)/*[position()=1] publication-title: J. Mol. Catal. A: Chem. doi: 10.1016/S1381-1169(00)00402-7 – volume: 57 start-page: 8647 year: 2018 ident: D0CY01528H-(cit7)/*[position()=1] publication-title: Ind. Eng. Chem. Res. doi: 10.1021/acs.iecr.8b01313 – volume: 14 start-page: 49 year: 2019 ident: D0CY01528H-(cit3)/*[position()=1] publication-title: Energy Sources, Part B doi: 10.1080/15567249.2019.1607631 – volume: 57 start-page: 6454 year: 2018 ident: D0CY01528H-(cit41)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201800557 – volume: 2 start-page: 71 year: 2012 ident: D0CY01528H-(cit44)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/cs200441e – volume: 341 start-page: 13 year: 2016 ident: D0CY01528H-(cit24)/*[position()=1] publication-title: J. Catal. doi: 10.1016/j.jcat.2016.06.006 – volume: 152 start-page: 40902 year: 2020 ident: D0CY01528H-(cit54)/*[position()=1] publication-title: J. Chem. Phys. doi: 10.1063/1.5133390 – volume: vol. 11 volume-title: Catalysis year: 2007 ident: D0CY01528H-(cit5)/*[position()=1] doi: 10.1039/9781847553232-00379 – volume: 19 start-page: 510 year: 2010 ident: D0CY01528H-(cit59)/*[position()=1] publication-title: J. Therm. Spray Technol. doi: 10.1007/s11666-009-9364-8 – start-page: 88 year: 2017 ident: D0CY01528H-(cit38)/*[position()=1] publication-title: Rev. Sci. Instrum. – volume: 55 start-page: 1309 year: 2012 ident: D0CY01528H-(cit1)/*[position()=1] publication-title: Top. Catal. doi: 10.1007/s11244-012-9912-1 – volume: 54 start-page: 888 year: 2011 ident: D0CY01528H-(cit8)/*[position()=1] publication-title: Top. Catal. doi: 10.1007/s11244-011-9708-8 – ident: D0CY01528H-(cit32)/*[position()=1] publication-title: Catal. Today doi: 10.1016/j.cattod.2020.04.050 – volume: 3 start-page: 299 year: 2011 ident: D0CY01528H-(cit35)/*[position()=1] publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/am100940g – volume: 12 start-page: 1325 year: 2020 ident: D0CY01528H-(cit48)/*[position()=1] publication-title: ChemCatChem doi: 10.1002/cctc.201901869 – volume: 102 start-page: 4279 year: 1995 ident: D0CY01528H-(cit40)/*[position()=1] publication-title: J. Chem. Phys. doi: 10.1063/1.469475 – volume: 18 start-page: 601 year: 2016 ident: D0CY01528H-(cit45)/*[position()=1] publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/C5CP05043J – volume: 3 start-page: 43 issue: 1–2 year: 2017 ident: D0CY01528H-(cit18)/*[position()=1] publication-title: Catal., Struct. React. doi: 10.1080/2055074X.2016.1263177 – volume: 140 start-page: 14870 year: 2018 ident: D0CY01528H-(cit20)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.8b08162 – volume: 9 start-page: 1979 year: 2019 ident: D0CY01528H-(cit14)/*[position()=1] publication-title: Catal. Sci. Technol. doi: 10.1039/C9CY00237E – volume: 398 start-page: 1 year: 2011 ident: D0CY01528H-(cit22)/*[position()=1] publication-title: Appl. Catal., A doi: 10.1016/j.apcata.2011.03.009 – volume: 90 start-page: 1090 year: 2012 ident: D0CY01528H-(cit11)/*[position()=1] publication-title: Chem. Eng. Res. Des. doi: 10.1016/j.cherd.2011.11.004 – volume: 55 start-page: 1297 year: 2012 ident: D0CY01528H-(cit2)/*[position()=1] publication-title: Top. Catal. doi: 10.1007/s11244-012-9917-9 – volume: 58 start-page: 10804 year: 2019 ident: D0CY01528H-(cit49)/*[position()=1] publication-title: Ind. Eng. Chem. Res. doi: 10.1021/acs.iecr.9b01413 – volume: 335 start-page: 1205 year: 2012 ident: D0CY01528H-(cit31)/*[position()=1] publication-title: Science doi: 10.1126/science.1212906 – volume: 5 start-page: 8470 year: 2014 ident: D0CY01528H-(cit33)/*[position()=1] publication-title: Sci. Rep. doi: 10.1038/srep08470 – volume: 71 start-page: 410 year: 2016 ident: D0CY01528H-(cit56)/*[position()=1] publication-title: Surf. Sci. Rep. doi: 10.1016/j.surfrep.2016.03.003 – volume: 8 start-page: 365 issue: 6 year: 2018 ident: D0CY01528H-(cit39)/*[position()=1] publication-title: Nanomaterials doi: 10.3390/nano8060365 – volume: 114 start-page: 10613 year: 2014 ident: D0CY01528H-(cit6)/*[position()=1] publication-title: Chem. Rev. doi: 10.1021/cr5002436 – volume: 20 start-page: 10058 year: 2018 ident: D0CY01528H-(cit52)/*[position()=1] publication-title: ACS Catal. doi: 10.1021/acscatal.8b02794 |
| SSID | ssj0000491082 |
| Score | 2.4829104 |
| Snippet | Supported Pt nanoparticles are widely used for the catalytic dehydrogenation of propane to propene. Monometallic Pt catalysts are subject to fast deactivation.... |
| SourceID | proquest crossref |
| SourceType | Aggregation Database Enrichment Source Index Database |
| StartPage | 484 |
| SubjectTerms | Atomic layer epitaxy Bimetals Catalysts Dehydrogenation Heat treatment Nanoalloys Nanoparticles Phase transitions Platinum Propane Selectivity Silicon dioxide Zinc oxide |
| Title | Design of PtZn nanoalloy catalysts for propane dehydrogenation through interface tailoring via atomic layer deposition |
| URI | https://www.proquest.com/docview/2484643548 |
| Volume | 11 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3Nb9MwFLdKd4DLxKcYDGQJLqjKSBzHbo5TN9QBQhw6aXCJbNcZFSOd2nRS-If4N3n-iJOtOwwuUWSljtL383s_P78PhN5ykYGVFyJiMecRncsSltR8HMlYARlJWKalDZD9wqan9ONZdjYY_OlFLW1qeaB-35pX8j9ShTGQq8mS_QfJhklhAO5BvnAFCcP1TjI-suEXNoyt_l6NKlEtzTl6M7JOmWZd22ILJgYL1rxJkPrRzFdLmM5Jve3RY0pGrEoBK9yEk7qIvCuTrFWblOXRhWhsG_E2vqvPZyfuRYv1qM0PMlCqt_z1J9W5D1z-umg26-CD_lTpX7rxgR1e3wRtvdKLn7D5dilnxvPTOXitH1dX543wltc7LkjSc1xY_UZiSiPKXa3gA90fc_XZg4JOekAkPW3ryqC2hpu6VotbNiFOTUnVo3jyDagPGU87y9ee9t8wiCFM0R7Qp3nR_fYe2iEcSNoQ7Rwez04-B3cebLSS2LYmC5_VFsNN8_fdBNfpz3XrbynN7CHa9XsRfOiA9QgNdPUY3Z-0LQCfoCsHMLwssQEYDgDDAWAYAIY9wPANgGEPMBwAhgPAMAAMO4BhCzDcAewpOv1wPJtMI9-oI1KEkTrieQY0WlCuypjosc6ZVCIjvAQyzjhlQMJ5lrO5nBMiuVAqKWWaAhlVVGqt4_QZGlbLSj9HWMWJ5kLwTGWEKtAdklFe5rkuE1nGTO6hd-3_Vyhfxd40U7kotoW1h96EZy9d7ZZbn9pvxVD4tb0uCEALuDps51_caZKX6EEH8X00rFcb_QrYai1fe6T8BdtHm00 |
| linkProvider | Royal Society of Chemistry |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Design+of+PtZn+nanoalloy+catalysts+for+propane+dehydrogenation+through+interface+tailoring+via+atomic+layer+deposition&rft.jtitle=Catalysis+science+%26+technology&rft.au=Ingale%2C+Piyush&rft.au=Knemeyer%2C+Kristian&rft.au=Preikschas%2C+Phil&rft.au=Ye%2C+Mengyang&rft.date=2021-01-01&rft.issn=2044-4753&rft.eissn=2044-4761&rft.volume=11&rft.issue=2&rft.spage=484&rft.epage=493&rft_id=info:doi/10.1039%2FD0CY01528H&rft.externalDBID=n%2Fa&rft.externalDocID=10_1039_D0CY01528H |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2044-4753&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2044-4753&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2044-4753&client=summon |