Solid / Liquid Interfacial Structures, Surface Forces, and Rheology of Colloidal Dispersions Comprised of Silica Particles Suspended in Liquid Epoxy Resins

In the present study, we have investigated the liquid resin composite consisted of an epoxy resin, an epoxy resin curing agent, a filler of silica particles, and a particle surface modifier of silane coupling agent at different temperatures, using atomic force microscopy and rheometry. Particular fo...

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Published inFuntai Kogakkaishi Vol. 49; no. 8; pp. 599 - 607
Main Authors Oota, Ken, Shinto, Hiroyuki, Fujisaki, Kazuya, Fukasawa, Tomonori, Matsuoka, Yuki
Format Journal Article
LanguageEnglish
Published The Society of Powder Technology, Japan 01.01.2012
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ISSN0386-6157
1883-7239
DOI10.4164/sptj.49.599

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Abstract In the present study, we have investigated the liquid resin composite consisted of an epoxy resin, an epoxy resin curing agent, a filler of silica particles, and a particle surface modifier of silane coupling agent at different temperatures, using atomic force microscopy and rheometry. Particular focus is on the mechanism how interaction forces between the silica surfaces and rheological properties of the liquid resin composite are affected by the silane coupling agent and the temperature. The relationship between the interparticle force and the particulate suspension rheology was discussed at a molecular level.
AbstractList In the present study, we have investigated the liquid resin composite consisted of an epoxy resin, an epoxy resin curing agent, a filler of silica particles, and a particle surface modifier of silane coupling agent at different temperatures, using atomic force microscopy and rheometry. Particular focus is on the mechanism how interaction forces between the silica surfaces and rheological properties of the liquid resin composite are affected by the silane coupling agent and the temperature. The relationship between the interparticle force and the particulate suspension rheology was discussed at a molecular level.
Author Fukasawa, Tomonori
Shinto, Hiroyuki
Fujisaki, Kazuya
Oota, Ken
Matsuoka, Yuki
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  organization: Production Engineering Research Laboratory, Sumitomo Bakelite Co., Ltd
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10.1016/j.surfrep.2005.08.003
10.1016/S0927-7757(98)00273-8
10.1201/9781420028706
10.1017/CBO9780511977978
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References 1) Honma, Y. : In “Sosetsu Epokishi Jushi (in Japanese)”, The Japan Society of Epoxy Resin Technology vol. 3, p. 161-166, (2003
17) Bergna, H. E. and W. O. Roberts, ed. : “Colloidal Silica : Fundamentals and Applications”, Chapter 3, CRC Press (2005
3) Nagata, K. : In “Sosetsu Epokishi Jushi (in Japanese)”, The Japan Society of Epoxy Resin Technology vol. 2, p. 13-21, (2003
11) Vakarelski, I. U. and K. Higashitani : “Single-nanoparticle-terminated tips for scanning probe microscopy”, Langmuir, 22, 2931-2934 (2006
7) Kanda, Y., T. Nishimura and K. Higashitani : “Interaction forces between silica surfaces in wet cyclohexane”, J. Soc. Powder Technol., Japan, 38, 316-322 (2001
13) Mewis, J. and N. J. Wagner : “Colloidal Suspension Rheology”, Chapter 8, Cambridge University Press (2011
4) Butt, H.-J., B. Cappella and M. Kappl : “Force measurements with the atomic force microscope : Technique, interpretation and applications”, Surface Sci. Rep., 59, 1-152 (2005
12) Mewis, J. and N. J. Wagner : “Colloidal Suspension Rheology”, Chapter 6, Cambridge University Press (2011
6) Kanda, Y., T. Nakamura and K. Higashitani : “AFM studies of interaction forces between surfaces in alcohol-water solutions”, Colloids Surfaces A, 139, 55-62 (1998
15) Evans, D. F. and H. Wennerström : “The Colloidal Domain : where Physics, Chemistry, and Biology Meet”, 2nd edn., p. 264-269, Wiley-VCH (1999
14) Israelachvili, J. N. : “Intermolecular and Surface Forces”, 3rd edn., p. 456-460, Academic Press (2010
2) Nakamura, Y. : In “Sosetsu Epokishi Jushi (in Japanese)”, The Japan Society of Epoxy Resin Technology vol. 2, p. 22-27, (2003
5) Vakarelski, I. U., Y. Kanda, H. Shinto and K. Higashitani : “Adhesion of particles to surfaces in aqueous and non-aqueous media”, Encyclopedia of Surface and Colloid Science : 2nd edn., 1:1, 1-17, CRC Press (2007
8) Wang, S., J. Liu, L. Zhang, Z. Xu and J. Masliyah : “Colloidal interactions between asphaltene surfaces in toluene”, Energy Fuels, 23, 862-869 (2008
9) Bower, M. J. D., T. L. Bank, R. F. Giese and C. J. van Oss : “Nanoscale forces of interaction between glass in aqueous and non-aqueous media : A theoretical and empirical study”, Colloids Surfaces A, 362, 90-96 (2010
10) Yakubo, T., T. Nakabeppu, T. Fukasawa and H. Shinto : “Interaction forces between hydrophilic or hydrophobized silica surfaces in non-aqueous media studied by AFM”, J. Soc. Powder Technol., Japan, 48, 296-302 (2011
16) Iler, R. K. : “The Chemistry of Silica : Solubility, Polymerization, Colloid and Surface Properties and Biochemistry of Silica”, p. 624-648, Wiley-Interscience (1979
19) Shinto, H. : In “Discharge, Collision and Drying of Small Droplet in Inkjet Technology”, p. 85-102, Technical Information Institute (2009
18) Woutersen, A. T. J. M. and C. G. de Kruif : “The rheology of adhesive hard-sphere dispersions”, J. Chem. Phys., 94, 5739-5750 (1991
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References_xml – reference: 8) Wang, S., J. Liu, L. Zhang, Z. Xu and J. Masliyah : “Colloidal interactions between asphaltene surfaces in toluene”, Energy Fuels, 23, 862-869 (2008)
– reference: 13) Mewis, J. and N. J. Wagner : “Colloidal Suspension Rheology”, Chapter 8, Cambridge University Press (2011)
– reference: 17) Bergna, H. E. and W. O. Roberts, ed. : “Colloidal Silica : Fundamentals and Applications”, Chapter 3, CRC Press (2005)
– reference: 5) Vakarelski, I. U., Y. Kanda, H. Shinto and K. Higashitani : “Adhesion of particles to surfaces in aqueous and non-aqueous media”, Encyclopedia of Surface and Colloid Science : 2nd edn., 1:1, 1-17, CRC Press (2007)
– reference: 11) Vakarelski, I. U. and K. Higashitani : “Single-nanoparticle-terminated tips for scanning probe microscopy”, Langmuir, 22, 2931-2934 (2006)
– reference: 6) Kanda, Y., T. Nakamura and K. Higashitani : “AFM studies of interaction forces between surfaces in alcohol-water solutions”, Colloids Surfaces A, 139, 55-62 (1998)
– reference: 7) Kanda, Y., T. Nishimura and K. Higashitani : “Interaction forces between silica surfaces in wet cyclohexane”, J. Soc. Powder Technol., Japan, 38, 316-322 (2001)
– reference: 9) Bower, M. J. D., T. L. Bank, R. F. Giese and C. J. van Oss : “Nanoscale forces of interaction between glass in aqueous and non-aqueous media : A theoretical and empirical study”, Colloids Surfaces A, 362, 90-96 (2010)
– reference: 16) Iler, R. K. : “The Chemistry of Silica : Solubility, Polymerization, Colloid and Surface Properties and Biochemistry of Silica”, p. 624-648, Wiley-Interscience (1979)
– reference: 1) Honma, Y. : In “Sosetsu Epokishi Jushi (in Japanese)”, The Japan Society of Epoxy Resin Technology vol. 3, p. 161-166, (2003)
– reference: 19) Shinto, H. : In “Discharge, Collision and Drying of Small Droplet in Inkjet Technology”, p. 85-102, Technical Information Institute (2009)
– reference: 12) Mewis, J. and N. J. Wagner : “Colloidal Suspension Rheology”, Chapter 6, Cambridge University Press (2011)
– reference: 10) Yakubo, T., T. Nakabeppu, T. Fukasawa and H. Shinto : “Interaction forces between hydrophilic or hydrophobized silica surfaces in non-aqueous media studied by AFM”, J. Soc. Powder Technol., Japan, 48, 296-302 (2011)
– reference: 15) Evans, D. F. and H. Wennerström : “The Colloidal Domain : where Physics, Chemistry, and Biology Meet”, 2nd edn., p. 264-269, Wiley-VCH (1999)
– reference: 4) Butt, H.-J., B. Cappella and M. Kappl : “Force measurements with the atomic force microscope : Technique, interpretation and applications”, Surface Sci. Rep., 59, 1-152 (2005)
– reference: 18) Woutersen, A. T. J. M. and C. G. de Kruif : “The rheology of adhesive hard-sphere dispersions”, J. Chem. Phys., 94, 5739-5750 (1991)
– reference: 2) Nakamura, Y. : In “Sosetsu Epokishi Jushi (in Japanese)”, The Japan Society of Epoxy Resin Technology vol. 2, p. 22-27, (2003)
– reference: 3) Nagata, K. : In “Sosetsu Epokishi Jushi (in Japanese)”, The Japan Society of Epoxy Resin Technology vol. 2, p. 13-21, (2003)
– reference: 14) Israelachvili, J. N. : “Intermolecular and Surface Forces”, 3rd edn., p. 456-460, Academic Press (2010)
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SubjectTerms Coupling agents
Epoxy resins
Liquid epoxy resin
Liquids
Particulate composites
Polymers
Rheology
Silane coupling agent
Silanes
Silica particle
Silicon dioxide
Surface force
Title Solid / Liquid Interfacial Structures, Surface Forces, and Rheology of Colloidal Dispersions Comprised of Silica Particles Suspended in Liquid Epoxy Resins
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