A comparison between in situ monazite Lu–Hf and U–Pb geochronology
In complex metamorphic rocks, monazite U–Pb dates can span a wide concordant range, leading to ambiguous geological interpretations (e.g. slow protracted cooling versus multiphase growth). We present in situ monazite Lu–Hf analysis as an independent chronometer to verify U–Pb age interpretations. Mo...
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Published in | Geochronology (Göttingen. Online) Vol. 7; no. 2; pp. 199 - 211 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Göttingen
Copernicus GmbH
05.06.2025
Copernicus Publications |
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ISSN | 2628-3719 2628-3697 2628-3719 |
DOI | 10.5194/gchron-7-199-2025 |
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Abstract | In complex metamorphic rocks, monazite U–Pb dates can span a wide concordant range, leading to ambiguous geological interpretations (e.g. slow protracted cooling versus multiphase growth). We present in situ monazite Lu–Hf analysis as an independent chronometer to verify U–Pb age interpretations. Monazite Lu–Hf dates were attained via laser ablation inductively coupled plasma mass spectrometry equipped with collision/reaction cell technology (LA-ICP-MS/MS). In situ Lu–Hf dates for potential reference monazites with uncertainties <1.6 % agree with published U–Pb dates, validating the approach. We demonstrate the method on complex metamorphic samples from the Arkaroola region of the northern Flinders Ranges, South Australia, which exhibit protracted thermal and monazite growth histories due to high geothermal gradient metamorphism. In situ Lu–Hf dates reproduce the main U–Pb monazite age populations, demonstrating the ability to reliably resolve multiple age populations from polymetamorphic monazite samples. |
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AbstractList | In complex metamorphic rocks, monazite U–Pb dates can span a wide concordant range, leading to ambiguous geological interpretations (e.g. slow protracted cooling versus multiphase growth). We present in situ monazite Lu–Hf analysis as an independent chronometer to verify U–Pb age interpretations. Monazite Lu–Hf dates were attained via laser ablation inductively coupled plasma mass spectrometry equipped with collision/reaction cell technology (LA-ICP-MS/MS). In situ Lu–Hf dates for potential reference monazites with uncertainties <1.6 % agree with published U–Pb dates, validating the approach. We demonstrate the method on complex metamorphic samples from the Arkaroola region of the northern Flinders Ranges, South Australia, which exhibit protracted thermal and monazite growth histories due to high geothermal gradient metamorphism. In situ Lu–Hf dates reproduce the main U–Pb monazite age populations, demonstrating the ability to reliably resolve multiple age populations from polymetamorphic monazite samples. In complex metamorphic rocks, monazite U–Pb dates can span a wide concordant range, leading to ambiguous geological interpretations (e.g. slow protracted cooling versus multiphase growth). We present in situ monazite Lu–Hf analysis as an independent chronometer to verify U–Pb age interpretations. Monazite Lu–Hf dates were attained via laser ablation inductively coupled plasma mass spectrometry equipped with collision/reaction cell technology (LA-ICP-MS/MS). In situ Lu–Hf dates for potential reference monazites with uncertainties <1.6 % agree with published U–Pb dates, validating the approach. We demonstrate the method on complex metamorphic samples from the Arkaroola region of the northern Flinders Ranges, South Australia, which exhibit protracted thermal and monazite growth histories due to high geothermal gradient metamorphism. In situ Lu–Hf dates reproduce the main U–Pb monazite age populations, demonstrating the ability to reliably resolve multiple age populations from polymetamorphic monazite samples. |
Author | Gilbert, Sarah E. Hand, Martin De Vries Van Leeuwen, Alexander T. Mulder, Jacob Glorie, Stijn |
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Cites_doi | 10.1007/s00710-016-0478-7 10.1130/G52442.1 10.1016/0168-1176(93)87009-H 10.5194/gchron-4-353-2022 10.1080/08120099508728198 10.1016/S0012-821X(04)00012-3 10.1016/j.epsl.2022.117922 10.1139/e90-152 10.1007/PL00007673 10.5194/gchron-2024-29 10.5194/gchron-6-397-2024 10.1039/D4JA00258J 10.1016/j.chemgeo.2016.01.009 10.1007/s00410-012-0812-y 10.1016/j.chemgeo.2024.122038 10.1016/S0016-7037(03)00258-8 10.1093/petrology/egl044 10.1007/s00410-010-0599-7 10.1016/j.gsf.2023.101629 10.1016/j.chemgeo.2012.07.001 10.1039/c1ja10172b 10.1016/j.precamres.2012.12.001 10.1016/j.chemgeo.2021.120195 10.1046/j.1440-0952.1999.00711.x 10.1016/j.gsf.2024.101867 10.1144/SP537-2022-205 10.1016/j.gsf.2019.09.004 10.1111/jmg.12590 10.1080/08120090801982595 10.1016/j.gsf.2018.04.001 10.1016/j.precamres.2020.105849 10.1016/j.gr.2023.04.011 10.1016/S0009-2541(02)00155-9 10.1016/j.gr.2012.12.017 10.1016/j.chemgeo.2021.120299 10.1086/499570 10.1007/s00410-024-02143-y 10.1111/j.1751-908X.1997.tb00538.x 10.1016/S0301-9268(99)00068-6 10.1016/j.gsf.2021.101340 10.1111/j.1751-908X.2009.00032.x 10.1039/C6JA00048G 10.1130/G36533.1 |
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SubjectTerms | Ablation Age Geochemistry Geochronology Inductively coupled plasma mass spectrometry Isotopes Laser ablation Lasers Lead Mass spectrometry Mass spectroscopy Measuring instruments Metamorphic rocks Metamorphism Monazite Populations Radiometric dating Ratios Reference materials Scientific imaging Trace elements |
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Title | A comparison between in situ monazite Lu–Hf and U–Pb geochronology |
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