Palladium Catalysts with Triglyme‐Functionalized NHC Ligands for Suzuki Coupling Reactions in Aqueous Solvent

To perform green chemistry, hydrophilic catalysts with high activity and stability are required. We designed and synthesized a catalyst [Pd(IPr*TEG)(cin)Cl)] from commercially available materials; this catalyst could be used in a wide range of Suzuki coupling reactions in aqueous solvents. The react...

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Bibliographic Details
Published inChemistrySelect (Weinheim) Vol. 6; no. 34; pp. 9175 - 9178
Main Authors Liu, Qingqing, Zhong, Jing, Tian, Funing, Wang, Qiwei, Wang, Yuanhua, Zhong, Liu, Huang, Qingfei
Format Journal Article
LanguageEnglish
Published 14.09.2021
Subjects
Aqueous solvent
N-heterocyclic carbene
palladium
Suzuki coupling
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ISSN2365-6549
2365-6549
DOI10.1002/slct.202102092

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Summary:To perform green chemistry, hydrophilic catalysts with high activity and stability are required. We designed and synthesized a catalyst [Pd(IPr*TEG)(cin)Cl)] from commercially available materials; this catalyst could be used in a wide range of Suzuki coupling reactions in aqueous solvents. The reaction works smoothly under low catalyst loading with a good to excellent yield. It was noted that the catalyst can be recycled, and it performed well in cyclical reactions. A novel eco‐friendly catalyst [Pd(IPr*TEG)(cin)Cl)] from economical materials that could be used in a wide range of Suzuki coupling reactions in aqueous solvent.
Bibliography:These authors contributed equally to this work.
ISSN:2365-6549
2365-6549
DOI:10.1002/slct.202102092