Natural citric acid (lemon juice) assisted synthesis of ZnO nanostructures: Evaluation of phase composition, morphology, optical and thermal properties

• Published in: Ceramics international Vol. 47; no. 16; pp. 23110 - 23115
• Main Authors: Vandamar Poonguzhali, R., Ranjith Kumar, E., Sumithra, M.G., Arunadevi, N., Rahale, C. Sharmila, Munshi, Alaa M, Mersal, Gaber A.M., El-Metwaly, Nashwa M.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.08.2021
• Subjects: Lemon-assisted synthesis; Nanostructures; Phase analysis; TEM; Thermal properties; Thermal properties; Nanostructures; Lemon-assisted synthesis; Phase analysis; TEM
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2021.05.024

In recent years, because of their excellent electrocatalytic action and applications in different fields, metal oxide nanostructures have received massive consideration from scientists. Zinc oxide nanostructures are useful materials for a range of sensing applications and possess admirable electrocatalytic properties and stability. The current research presents the natural citric acid assisted synthesis of ZnO nanostructures and their structural, optical, morphological and thermal properties. X-ray diffraction was studied for the phase assessment of as prepared (Z1) and annealed ZnO (Z2) nanostructures and the crystallite sizes of the Z1 and Z2 samples were also located in the range between 35 nm and 38 nm. FESEM and TEM experiments were carried out to explore the surface features of Z1 and Z2 samples. The polycrystalline existence of the samples is demonstrated by the hexagonal, cubic and spherical shaped ZnO nanostructures. The energy band gap of Z1 and Z2 samples was determined (3.16 eV for Z1 and 3.12 eV for Z2) from the UV spectrum. The impact of annealing treatment on the thermal stability of ZnO nanostructures was studied and the main peak was observed for the Z1 sample at ~249 °C and for the Z2 sample at ~289 °C.