A comparative review on adsorption and photocatalytic degradation of classified dyes with metal/non-metal-based modification of graphitic carbon nitride nanocomposites: Synthesis, mechanism, and affecting parameters

Dyes have different categories, and each is used in one of the industries according to its appearance and physical characteristics. Dyes have severe toxicity and carcinogenic effects, which in water effluents contaminates the aquatic system and threatens other parts of the ecosystem and humans. Dye...

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Published inJournal of cleaner production Vol. 382; p. 134967
Main Authors Ahmadi, Abbas, Hajilou, Mersad, Zavari, Saman, Yaghmaei, Soheila
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.01.2023
Subjects
Online AccessGet full text
ISSN0959-6526
1879-1786
DOI10.1016/j.jclepro.2022.134967

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Abstract Dyes have different categories, and each is used in one of the industries according to its appearance and physical characteristics. Dyes have severe toxicity and carcinogenic effects, which in water effluents contaminates the aquatic system and threatens other parts of the ecosystem and humans. Dye removal using absorption and photocatalytic properties has been the subject of various fundamental researches. Graphitic carbon nitride (g-C3N4) as a photocatalyst is a good choice because of its many excellent features, like adjustable optical band gap and excellent chemical and thermal stability. Although this catalyst has great potential to eliminate contamination, its use is limited because of the low separation of excited carriers. Therefore, modifying the existing graphitic carbon nitride photocatalyst is necessary to improve its properties and overcome the drawbacks. Considering the number of published experimental papers, connecting with other semiconductors and doping metal/non-metal materials is one of the most popular solutions that has shown remarkable results so far. In this study, after an overview and classification of dyes, the review paper investigates the synthesis, interface, and modification of graphitic carbon nitride nanomaterials, affecting parameters and mechanism of both photocatalytic degradation and adsorption removal of categorized dyes. Experimental work on fabricating the pure, binary, and tertiary graphitic carbon nitride nanocomposite was discussed. Photocatalytic process parameters like light source, pH, temperature, dissolved oxygen, initial concentration, catalyst content, stability and recycling of these materials have been analyzed. This paper could be helpful for researchers focusing on the synthesis of carbon graphite nitride, its composites, and their photocatalytic activity. It could also be a resource for understanding the type of dyes and their environmental effects. [Display omitted] •Dyes were categorized and classified into different group based on their chemical structures and applications.•The role of adsorption mechanism and its synergic effect on photocatalytic process were studied.•Different synthesis methods of g-C3N4 and its metal/nonmetal and plasmonic modification were investigated.•Stability and reusability of g-C3N4-based nanomaterials towards degradation of dyes are described.•Operating conditions effects, pH, temperature, dye concentration, and catalyst content were reviewed.
AbstractList Dyes have different categories, and each is used in one of the industries according to its appearance and physical characteristics. Dyes have severe toxicity and carcinogenic effects, which in water effluents contaminates the aquatic system and threatens other parts of the ecosystem and humans. Dye removal using absorption and photocatalytic properties has been the subject of various fundamental researches. Graphitic carbon nitride (g-C3N4) as a photocatalyst is a good choice because of its many excellent features, like adjustable optical band gap and excellent chemical and thermal stability. Although this catalyst has great potential to eliminate contamination, its use is limited because of the low separation of excited carriers. Therefore, modifying the existing graphitic carbon nitride photocatalyst is necessary to improve its properties and overcome the drawbacks. Considering the number of published experimental papers, connecting with other semiconductors and doping metal/non-metal materials is one of the most popular solutions that has shown remarkable results so far. In this study, after an overview and classification of dyes, the review paper investigates the synthesis, interface, and modification of graphitic carbon nitride nanomaterials, affecting parameters and mechanism of both photocatalytic degradation and adsorption removal of categorized dyes. Experimental work on fabricating the pure, binary, and tertiary graphitic carbon nitride nanocomposite was discussed. Photocatalytic process parameters like light source, pH, temperature, dissolved oxygen, initial concentration, catalyst content, stability and recycling of these materials have been analyzed. This paper could be helpful for researchers focusing on the synthesis of carbon graphite nitride, its composites, and their photocatalytic activity. It could also be a resource for understanding the type of dyes and their environmental effects. [Display omitted] •Dyes were categorized and classified into different group based on their chemical structures and applications.•The role of adsorption mechanism and its synergic effect on photocatalytic process were studied.•Different synthesis methods of g-C3N4 and its metal/nonmetal and plasmonic modification were investigated.•Stability and reusability of g-C3N4-based nanomaterials towards degradation of dyes are described.•Operating conditions effects, pH, temperature, dye concentration, and catalyst content were reviewed.
ArticleNumber 134967
Author Zavari, Saman
Yaghmaei, Soheila
Ahmadi, Abbas
Hajilou, Mersad
Author_xml – sequence: 1
  givenname: Abbas
  surname: Ahmadi
  fullname: Ahmadi, Abbas
  organization: Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran
– sequence: 2
  givenname: Mersad
  surname: Hajilou
  fullname: Hajilou, Mersad
  organization: Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran
– sequence: 3
  givenname: Saman
  surname: Zavari
  fullname: Zavari, Saman
  organization: School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
– sequence: 4
  givenname: Soheila
  surname: Yaghmaei
  fullname: Yaghmaei, Soheila
  email: yaghmaei@sharif.edu
  organization: Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran
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AGRNS
AIGII
AIIUN
AKBMS
AKRWK
AKYEP
ANKPU
APXCP
ASPBG
AVWKF
AZFZN
BNPGV
CITATION
D-I
EJD
FEDTE
FGOYB
G-2
HMC
HVGLF
HZ~
R2-
RIG
SEN
SEW
SSH
WUQ
ZY4
ID FETCH-LOGICAL-c239t-e20063a9943faa1e7fe38e4a17ce4e5bac43e56e0a824ec15874997af9f37703
IEDL.DBID AIKHN
ISSN 0959-6526
IngestDate Thu Apr 24 22:56:28 EDT 2025
Tue Jul 01 04:42:22 EDT 2025
Fri Feb 23 02:39:40 EST 2024
IsPeerReviewed true
IsScholarly true
Keywords g-C3N4
Dye classification
Photocatalytic degradation
Nanocomposite synthesis
Heterojunction photocatalyst
Mechanism
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c239t-e20063a9943faa1e7fe38e4a17ce4e5bac43e56e0a824ec15874997af9f37703
ParticipantIDs crossref_citationtrail_10_1016_j_jclepro_2022_134967
crossref_primary_10_1016_j_jclepro_2022_134967
elsevier_sciencedirect_doi_10_1016_j_jclepro_2022_134967
ProviderPackageCode CITATION
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PublicationCentury 2000
PublicationDate 2023-01-01
2023-01-00
PublicationDateYYYYMMDD 2023-01-01
PublicationDate_xml – month: 01
  year: 2023
  text: 2023-01-01
  day: 01
PublicationDecade 2020
PublicationTitle Journal of cleaner production
PublicationYear 2023
Publisher Elsevier Ltd
Publisher_xml – name: Elsevier Ltd
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Snippet Dyes have different categories, and each is used in one of the industries according to its appearance and physical characteristics. Dyes have severe toxicity...
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StartPage 134967
SubjectTerms Dye classification
g-C3N4
Heterojunction photocatalyst
Mechanism
Nanocomposite synthesis
Photocatalytic degradation
Title A comparative review on adsorption and photocatalytic degradation of classified dyes with metal/non-metal-based modification of graphitic carbon nitride nanocomposites: Synthesis, mechanism, and affecting parameters
URI https://dx.doi.org/10.1016/j.jclepro.2022.134967
Volume 382
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