Measurement and Correlation of Solid-Liquid Equilibria of Phenyl Salicylate with C4 Alcohols
In an equilibrium vessel, the solid-liquid equilibria （SLE） for three binary mixtures of phenyl salicylate with 1-butanol, 2-butanol, and 2-methyl-1-propanol, respectively, have been measured from 283.15 K to the melting temperature of the solute using a method in which an excess amount of solute wa...
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| Published in | Chinese journal of chemical engineering Vol. 17; no. 1; pp. 140 - 144 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
01.02.2009
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1004-9541 2210-321X |
| DOI | 10.1016/S1004-9541(09)60045-8 |
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| Abstract | In an equilibrium vessel, the solid-liquid equilibria （SLE） for three binary mixtures of phenyl salicylate with 1-butanol, 2-butanol, and 2-methyl-1-propanol, respectively, have been measured from 283.15 K to the melting temperature of the solute using a method in which an excess amount of solute was equilibrated with the alcohol solution. The liquid concentrations of the investigated phenyl salicylate in the saturated solution were analyzed by UV spectrometry. Activity coefficients for phenyl salicylate have been calculated by means of the Wilson, NRTL, and UNIQUAC equations and with them were correlated solubility data that were compared with the experimental ones. The best correlation of the solubility data has been obtained by the Wilson equation by which the average root-mean-square deviation of temperature for the three systems is 1.03 K. |
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| AbstractList | In an equilibrium vessel, the solid-liquid equilibria （SLE） for three binary mixtures of phenyl salicylate with 1-butanol, 2-butanol, and 2-methyl-1-propanol, respectively, have been measured from 283.15 K to the melting temperature of the solute using a method in which an excess amount of solute was equilibrated with the alcohol solution. The liquid concentrations of the investigated phenyl salicylate in the saturated solution were analyzed by UV spectrometry. Activity coefficients for phenyl salicylate have been calculated by means of the Wilson, NRTL, and UNIQUAC equations and with them were correlated solubility data that were compared with the experimental ones. The best correlation of the solubility data has been obtained by the Wilson equation by which the average root-mean-square deviation of temperature for the three systems is 1.03 K. In an equilibrium vessel, the solid-liquid equilibria (SLE) for three binary mixtures of phenyl salicylate with 1-butanol, 2-butanol, and 2-methyl-1-propanol, respectively, have been measured from 283.15 K to the melting temperature of the solute using a method in which an excess amount of solute was equilibrated with the alcoholsolution. The liquid concentrations of the investigated phenyl salicylate in the saturated solution were analyzed byUV spectrometry. Activity coefficients for phenyl salicylate have been calculated by means of the Wilson, NRTL, and UNIQUAC equations and with them were correlated solubility data that were compared with the experimentalones. The best correlation of the solubility data has been obtained by the Wilson equation by which the averageroot-mean-square deviation of temperature for the three systems is 1.03 K. |
| Author | 魏东炜 裴艳红 张超 闫峰 |
| AuthorAffiliation | Tianjin Research and Development Center for Petrochemical Technology, Tianjin University, Tianjin 300072, China |
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| Cites_doi | 10.1016/j.catcom.2006.01.019 10.1351/pac200678071455 10.1002/aic.690140124 10.1006/jcht.2002.0976 10.1002/aic.690210115 10.1063/1.476348 10.1021/ja01056a002 10.1016/j.molcata.2004.03.057 |
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| Title | Measurement and Correlation of Solid-Liquid Equilibria of Phenyl Salicylate with C4 Alcohols |
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