Asymmetric addition of pyridine to 1,4-bis(ethynyl)bicyclo[2.2.2]octane: dissymmetrical rotator ligands illustrated in dpppPt(ii) and [Re6Se8]2+ complexes and an amphidynamic hydrogen bonded framework solid
A polar function like pyridine increases the polarity difference between mono- and disubstituted 1,4-bis(trimethylsilylethynyl)bicyclo[2.2.2]octane cores allowing for their ready separation by chromatography, affording two dissymmetrical ligands illustrated in metal-rotor hybrids like a corner-shape...
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| Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 40; no. 32; pp. 8075 - 8078 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
01.01.2011
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1477-9226 1477-9234 |
| DOI | 10.1039/c1dt10913h |
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| Abstract | A polar function like pyridine increases the polarity difference between mono- and disubstituted 1,4-bis(trimethylsilylethynyl)bicyclo[2.2.2]octane cores allowing for their ready separation by chromatography, affording two dissymmetrical ligands illustrated in metal-rotor hybrids like a corner-shaped mononuclear complex, an octahedral hexanuclear metal complex, and a framework solid with a rather slow rotator. |
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| AbstractList | A polar function like pyridine increases the polarity difference between mono- and disubstituted 1,4-bis(trimethylsilylethynyl)bicyclo[2.2.2]octane cores allowing for their ready separation by chromatography, affording two dissymmetrical ligands illustrated in metal-rotor hybrids like a corner-shaped mononuclear complex, an octahedral hexanuclear metal complex, and a framework solid with a rather slow rotator. A polar function like pyridine increases the polarity difference between mono- and disubstituted 1,4- bis(trimethylsilylethynyl)bicyclo[2.2.2]octane cores allowingfor their ready separation by chromatography, affording two dissymmetrical ligands illustrated in metal–rotor hybrids like a corner-shaped mononuclear complex, an octahedral hexanuclear metal complex, and a framework solid with a rather slow rotator. |
| Author | Barrès, A.-L. Rondeau, D. Mézière, C. Batail, P. Lemouchi, C. Zorina, L. Wzietek, P. |
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| Snippet | A polar function like pyridine increases the polarity difference between mono- and disubstituted 1,4-bis(trimethylsilylethynyl)bicyclo[2.2.2]octane cores... A polar function like pyridine increases the polarity difference between mono- and disubstituted 1,4- bis(trimethylsilylethynyl)bicyclo[2.2.2]octane cores... |
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| Title | Asymmetric addition of pyridine to 1,4-bis(ethynyl)bicyclo[2.2.2]octane: dissymmetrical rotator ligands illustrated in dpppPt(ii) and [Re6Se8]2+ complexes and an amphidynamic hydrogen bonded framework solid |
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