Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with tert-butyl-hydroperoxide catalyzed by titanium silicalite 1 （TS-1） in ambient-temperature ionic liquid [emim]BF4. Good yield and higher selectivity of products were foun...

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Published inChinese journal of chemical engineering Vol. 16; no. 3; pp. 373 - 375
Main Author 王建英 赵华 张向京 刘润静 胡永琪
Format Journal Article
LanguageEnglish
Published 01.06.2008
Subjects
催化氧化
环己烷
离子液体
钛硅分子筛
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ISSN1004-9541
2210-321X
DOI10.1016/S1004-9541(08)60091-9

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Abstract An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with tert-butyl-hydroperoxide catalyzed by titanium silicalite 1 （TS-1） in ambient-temperature ionic liquid [emim]BF4. Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent. The research results showed 13.2% conversion of cyclohexane, 97.6% cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90℃.
AbstractList An efficient and environmentally friendly procedure was described for easy product isolation for the oxidation of cyclohexane with tert-butyl-hydroperoxide catalyzed by titanium silicalite 1 （TS-1） in ambient-temperature ionic liquid [emim]BF4. Good yield and higher selectivity of products were found in the ionic liquid compared with in molecular solvent. The research results showed 13.2% conversion of cyclohexane, 97.6% cyclohexanol and cyclohexanone selectivity were obtained in ionic liquid under mild conditions of 90℃.
Author 王建英 赵华 张向京 刘润静 胡永琪
AuthorAffiliation College of Chemical Engineering, Beijing Unversity of Chemical Technology, Beijing 100029, China College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
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ionic liquid, cyclohexane, TS-1, tert-butyl-hydroperoxide
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SubjectTerms 催化氧化
环己烷
离子液体
钛硅分子筛
Title Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide
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