2'‐(1,3‐Dithiolan‐2‐ylidene)‐4'‐(1,3‐dithiol‐2‐ylidene)spiro[1,3‐dithiole‐2,5'‐(4'H‐5',6'‐dihydro‐1',3'‐dithiapentalene)], the Self‐Condensation Product of an Extended Tetrathiafulvalene Derivative
SiO2-gel treatment of the extended tetrathiafulvalene derivative 2,3-bis(1,4-dithiafulven-6-yl)-6,7-dihydrotetrathiafulvalene, bearing two 1,4-dithiafulven-6-yl groups in vicinal positions, afforded the title compound, C14H10S8, as a cyclization product. While one dithiafulvenyl group...
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Published in | Acta crystallographica. Section C, Crystal structure communications Vol. 54; no. 12; pp. 2005 - 2007 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
5 Abbey Square, Chester, Cheshire CH1 2HU, England
International Union of Crystallography
15.12.1998
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Subjects | |
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ISSN | 0108-2701 1600-5759 |
DOI | 10.1107/S0108270198009809 |
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Abstract | SiO2-gel treatment of the extended tetrathiafulvalene derivative 2,3-bis(1,4-dithiafulven-6-yl)-6,7-dihydrotetrathiafulvalene, bearing two 1,4-dithiafulven-6-yl groups in vicinal positions, afforded the title compound, C14H10S8, as a cyclization product. While one dithiafulvenyl group is still conjugated with the tetrathiafulvalene moiety, the other one gives rise to a strongly folded 1,3-dithiole group linked to the molecule through a spiro-C atom. Two short nonbonding intramolecular 1,5-S···S contacts are also identified in the title compound. |
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AbstractList | SiO2-gel treatment of the extended tetrathiafulvalene derivative 2,3-bis(1,4-dithiafulven-6-yl)-6,7-dihydrotetrathiafulvalene, bearing two 1,4-dithiafulven-6-yl groups in vicinal positions, afforded the title compound, C14H10S8, as a cyclization product. While one dithiafulvenyl group is still conjugated with the tetrathiafulvalene moiety, the other one gives rise to a strongly folded 1,3-dithiole group linked to the molecule through a spiro-C atom. Two short nonbonding intramolecular 1,5-S···S contacts are also identified in the title compound. |
Author | Mézière, C. Fourmigué, M. Sallé, M. |
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Keywords | Cyclisation product Extended Tetrathiafulvalene Organic conducting materials Crystal structure |
Language | English |
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PublicationTitle | Acta crystallographica. Section C, Crystal structure communications |
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Snippet | SiO2-gel treatment of the extended tetrathiafulvalene derivative 2,3-bis(1,4-dithiafulven-6-yl)-6,7-dihydrotetrathiafulvalene, bearing two... |
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Title | 2'‐(1,3‐Dithiolan‐2‐ylidene)‐4'‐(1,3‐dithiol‐2‐ylidene)spiro[1,3‐dithiole‐2,5'‐(4'H‐5',6'‐dihydro‐1',3'‐dithiapentalene)], the Self‐Condensation Product of an Extended Tetrathiafulvalene Derivative |
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