Fuel desulfurization using ionic liquids –An updated review
•Fuel desulfurization and modern technologies involved have been analyzed.•The applications of ILs and IL-based composites are summarized.•The mechanisms of IL-based composites have been revealed in this review.•The challenges, opportunities, and future applications IL-based composites with potentia...
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| Published in | Journal of ionic liquids Vol. 5; no. 2; p. 100162 |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.12.2025
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| Subjects | |
| Online Access | Get full text |
| ISSN | 2772-4220 2772-4220 |
| DOI | 10.1016/j.jil.2025.100162 |
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| Abstract | •Fuel desulfurization and modern technologies involved have been analyzed.•The applications of ILs and IL-based composites are summarized.•The mechanisms of IL-based composites have been revealed in this review.•The challenges, opportunities, and future applications IL-based composites with potential for commercialization have been highlighted.
Environmental and human safety has become an important subject of research interest in petroleum chemistry and environmental catalysis. The presence of sulfur-containing compounds in fuel oil is an overwhelming problem in the petrochemical industries due to regulations for environmental protection. The emitted toxic gases from the combustion of fossil fuels result in air contamination that can damage the human respiratory system, cause acid rain, and negatively affect refinery equipment. Therefore, fuel desulfurization becomes necessary to remove sulfur and its derivatives from fuel oil. Recently, ionic liquids (ILs) have been identified as good candidates for many industrial applications. They are widely known for their potential as designer solvents due to fascinating properties such as low volatility, high tunability, and high thermal stability. However, their general environmental impact varies significantly depending on their specific chemical compositions with some ILs exhibiting toxicity or poor biodegradability. The present study comprehensively reviews the recent achievements and applications of ILs in fuel oil desulfurization, addressing the mechanisms of the conversion process. The practicality and reusability of ILs for fuel oil desulfurization have been reported, and finally, the conclusion and future research prospects in this exciting area have been suggested. This review is anticipated to provide insights into fuel refinement and purification technologies through the sustainable application of ILs for clean fuel generation. |
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| AbstractList | •Fuel desulfurization and modern technologies involved have been analyzed.•The applications of ILs and IL-based composites are summarized.•The mechanisms of IL-based composites have been revealed in this review.•The challenges, opportunities, and future applications IL-based composites with potential for commercialization have been highlighted.
Environmental and human safety has become an important subject of research interest in petroleum chemistry and environmental catalysis. The presence of sulfur-containing compounds in fuel oil is an overwhelming problem in the petrochemical industries due to regulations for environmental protection. The emitted toxic gases from the combustion of fossil fuels result in air contamination that can damage the human respiratory system, cause acid rain, and negatively affect refinery equipment. Therefore, fuel desulfurization becomes necessary to remove sulfur and its derivatives from fuel oil. Recently, ionic liquids (ILs) have been identified as good candidates for many industrial applications. They are widely known for their potential as designer solvents due to fascinating properties such as low volatility, high tunability, and high thermal stability. However, their general environmental impact varies significantly depending on their specific chemical compositions with some ILs exhibiting toxicity or poor biodegradability. The present study comprehensively reviews the recent achievements and applications of ILs in fuel oil desulfurization, addressing the mechanisms of the conversion process. The practicality and reusability of ILs for fuel oil desulfurization have been reported, and finally, the conclusion and future research prospects in this exciting area have been suggested. This review is anticipated to provide insights into fuel refinement and purification technologies through the sustainable application of ILs for clean fuel generation. |
| ArticleNumber | 100162 |
| Author | Juma, Ali Khatib Aliero, Abdulrahman Sani Ekeoma, Bernard Chukwuemeka Hamza, Sa’adatu Auwal Imam, Madina Haruna, Abdurrashid Abdulsalam, Safiya Merican, Zulkifli Merican Aljunid Abdullahi, Mustapha |
| Author_xml | – sequence: 1 givenname: Abdurrashid orcidid: 0000-0002-0410-1015 surname: Haruna fullname: Haruna, Abdurrashid email: abdurrashidharuna@abu.edu.ng organization: Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria – sequence: 2 givenname: Zulkifli Merican Aljunid surname: Merican fullname: Merican, Zulkifli Merican Aljunid email: zulkifli.aljunid@utp.edu.my organization: Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, Malaysia – sequence: 3 givenname: Ali Khatib surname: Juma fullname: Juma, Ali Khatib organization: Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, Malaysia – sequence: 4 givenname: Abdulrahman Sani surname: Aliero fullname: Aliero, Abdulrahman Sani organization: Department of Biosciences, Faculty of Science, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia – sequence: 5 givenname: Bernard Chukwuemeka surname: Ekeoma fullname: Ekeoma, Bernard Chukwuemeka organization: Department of Chemical and Biological Engineering, The University of Alabama, Tuscaloosa, AL, 35487, United States – sequence: 6 givenname: Mustapha surname: Abdullahi fullname: Abdullahi, Mustapha organization: Department of Pure and Applied Chemistry, Kaduna State University, Tafawa-Balewa Way, Kaduna State, Nigeria – sequence: 7 givenname: Madina surname: Imam fullname: Imam, Madina organization: Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria – sequence: 8 givenname: Safiya surname: Abdulsalam fullname: Abdulsalam, Safiya organization: Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria – sequence: 9 givenname: Sa’adatu Auwal surname: Hamza fullname: Hamza, Sa’adatu Auwal organization: Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria |
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| Keywords | TTIP DBTO2 LLE COFs CO2 H2O2 Clean-fuel production ADS BDS BT DFT EDS HDS DBT ODS POMs UV DBTO Organic sulfur Fuel desulfurization MOFs DCM ILs Petroleum chemistry TH SLMs 4 6-DMBT SDGs |
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| SubjectTerms | Clean-fuel production Fuel desulfurization Organic sulfur Petroleum chemistry |
| Title | Fuel desulfurization using ionic liquids –An updated review |
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