Evaluation of various properties of ribbons of Mg-9%Al-3%Ca-based anode material for magnesium batteries produced by single-roll rapid solidification
There is an urgent need to develop next-generation rechargeable batteries for a carbon-neutral society. In this context, our research team is focusing on magnesium, which is abundant in the earth's crust and inexpensive. Ribbons of Mg-9%Al-3%Ca, a magnesium alloy, were prepared as anode materia...
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| Published in | Journal of Japan Institute of Light Metals Vol. 74; no. 10; pp. 455 - 462 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | Japanese |
| Published |
Tokyo
The Japan Institute of Light Metals
15.10.2024
Japan Science and Technology Agency |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0451-5994 0368-5306 1880-8018 1880-8018 2186-618X |
| DOI | 10.2464/jilm.74.455 |
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| Abstract | There is an urgent need to develop next-generation rechargeable batteries for a carbon-neutral society. In this context, our research team is focusing on magnesium, which is abundant in the earth's crust and inexpensive. Ribbons of Mg-9%Al-3%Ca, a magnesium alloy, were prepared as anode material for rechargeable batteries by a single-roll rapid solidification method. The fabricated ribbons were subjected to various manufacturing conditions, and various properties such as surface properties, microstructure, mechanical properties, and electrochemical activity of the fabricated ribbons were evaluated. As a result, it was found that a peripheral speed of 25 m/s and an injection pressure of 0.05 MPa or less were desirable to fabricate ribbons with good surface and mechanical properties. It was also confirmed that electrochemical activity contributes significantly to the orientation of magnesium and that production conditions with a peripheral velocity of 30 m/s or higher resulted in low electrochemical activity. |
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| AbstractList | There is an urgent need to develop next-generation rechargeable batteries for a carbon-neutral society. In this context, our research team is focusing on magnesium, which is abundant in the earth's crust and inexpensive. Ribbons of Mg-9%Al-3%Ca, a magnesium alloy, were prepared as anode material for rechargeable batteries by a single-roll rapid solidification method. The fabricated ribbons were subjected to various manufacturing conditions, and various properties such as surface properties, microstructure, mechanical properties, and electrochemical activity of the fabricated ribbons were evaluated. As a result, it was found that a peripheral speed of 25 m/s and an injection pressure of 0.05 MPa or less were desirable to fabricate ribbons with good surface and mechanical properties. It was also confirmed that electrochemical activity contributes significantly to the orientation of magnesium and that production conditions with a peripheral velocity of 30 m/s or higher resulted in low electrochemical activity. |
| ArticleNumber | 741001 |
| Author | TABATA, Hironobu KIRIMOTO, Yuichi KURIHARA, Hideki HAGA, Toshio TSUKEDA, Tadayoshi AIDA, Tetsuo SUZUKI, Mayumi |
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| References_xml | – reference: 24) Y. Kirimoto, K. Fuke, T. Tsukeda, T. Aida, Y. Nemoto, M. Ikeda, H. Tabata, H. Kurihara and M. Suzuki: J. Japan Inst. Light Metals, 73 (2023), 537-544. – reference: 12) X. Chen, S. Wei, F. Tong, M. P. Taylor and P. Cao: Electrochim. Acta, 398 (2021), 139336. – reference: 16) Y. Orikasa: Bulletin of the Ceram. Soc. of Japan, 56 (2021), 343-346. – reference: 21) K. Fuke, T. Tsukeda, T. Aida, M. Ikeda, H. Tabata, H. Kurihara and M. Suzuki: Proc. The 142th Conf. Japan Inst. Light Metals, (2022), 118-119. – reference: 1) T. Tsukeda, T. Nakagawa, M. Moriwaki, K. Kikura, R. Sakurae, T. Aida, H. Tabata, H. Kurihara and M. Suzuki: Mater. Trans., 63 (2022), 408-414. – reference: 6) K. Yamazaki: J. Japan Inst. Light Metals, 72 (2022), 92-98. – reference: 33) M. Matsumoto: Bull. Res. Inst. Miner. Dressin. Metall, Tohoku Univ., 47 (1991), 141-144. – reference: 26) Y. Kirimoto, T. Tsukeda, T. Aida, Y. Nemoto, M. Ikeda, H. Tabata, H. Kurihara and M. Suzuki: Proc. The 144th Conf. Japan Inst. Light Metals, (2023), 209-210. – reference: 25) Y. Kirimoto, T. Tsukeda, T. Aida, Y. Nemoto, M. Ikeda, H. Tabata, H. Kurihara and M. Suzuki: Proc. The 143th Conf. Japan Inst. Light Metals, (2022), 99-100. – reference: 2) T. Tsukeda, M. Moriwaki, T. Nakagawa, T. Aida, H. Tabata, H. Kurihara and M. Suzuki: Journal of JSEM., 22 (2022), 15-19. – reference: 10) H. Kurihara, M. Inamoto and H. Ogasa: Chem. Lett., 50 (2021), 1213. – reference: 11) H. K. Tian, R. Jalem, M. Matsui, T. Mandai, H. Somekawa and Y. Tateyama: J. Mater. Chem., A, 9 (2021), 15207. – reference: 3) T. Tsukeda, Y. Kirimoto, T. Aida, M. Ikeda, H. Tabata, H. Kurihara, M. Suzuki and Y. Nemoto: ALUTOPIA, 53 (2023), 12-20. – reference: 19) S. Yagi and T. Ichitsubo: Bulletin of the Ceram. Soc. of Japan, 56 (2021), 355-358. – reference: 22) M. Ikeda, H. Tabata, K. Fuke, T. Tsukeda, T. Aida, H. Kurihara and M. Suzuki: Proc. The 143th Conf. Japan Inst. Light Metals, (2022), 95-96. – reference: 23) K. Fuke, T. Tsukeda, T. Aida, M. Ikeda, H. Tabata, H. Kurihara and M. Suzuki: Proc. The 144th Conf. Japan Inst. Light Metals, (2023), 199-200. – reference: 17) H. Watanabe and H. Imai: Bulletin of the Ceram. Soc. of Japan, 56 (2021), 347-350. – reference: 13) K. Kanamura: Bulletin of the Ceram. Soc. of Japan, 56 (2021), 326-330. – reference: 18) H. Kobayashi: Bulletin of the Ceram. Soc. of Japan, 56 (2021), 351-354. – reference: 30) H. Sakamoto, N. Okumura, Y. Inoue and T. Yamada: J. Japan Inst. Metals, 60 (1996), 870-877. – reference: 32) K. Fuke, Y. Kirimoto, T. Tsukeda, T. Aida, H. Tabata, H. Kurihara and M. Suzuki: Proc. The 145 Conf. Japan Inst. Light Metals, (2023), 85-86. – reference: 7) D. Aurbach, H. Gizbar, A. Schechter, O. Chusid, H. E. Gottlieb, Y. Gofer and I. Goldberg: J. Electrochem. Soc., 149 (2002), A115. – reference: 31) M. Inoue, M. Iwai, K. Matuzawa, S. Kamado and Y. Kojima: J. Japan Inst. Light Metals, 48 (1998), 257-262. – reference: 28) T. Haga and M. Motomura: J. Japan Inst. Light Metals, 40 (1990), 265-270. – reference: 9) T. Mandai and H. Somekawa: Chem. Commun., 56 (2020), 12122. – reference: 4) S. Fukui, T. Tsukeda, T. Aida, H. Tabata, H. Kurihara and M. Suzuki: J. Japan Inst. Light Metals, 74 (2024), 14-17. – reference: 5) T. Tsukeda: J. Japan Inst. Light Metals, 74 (2024), 227-232. – reference: 27) Y. Kirimoto, T. Tsukeda, T. Aida, Y. Nemoto, M. Ikeda, H. Tabata, H. Kurihara and M. Suzuki: Proc. The 145th Conf. Japan Inst. Light Metals, (2023), 83-84. – reference: 15) Y. Idemoto and N. Ishida: Bulletin of the Ceram. Soc. of Japan, 56 (2021), 337-342. – reference: 8) Y. Gofer, O. Chusid, H. Gizbar, Y. Viestfrid, H. E. Gottlieb and D. Aurbach: Electrochem. Solid-State Lett., 9 (2006), A257. – reference: 20) M. Nakayama, K. Nakano and R. Kobayashi: Bulletin of the Ceram. Soc. of Japan, 56 (2021), 362-365. – reference: 29) K. Takeshita and H. Naya: J. Japan Inst. Metals. 60 (1996), 163-168. – reference: 14) K. Shimokawa, N. Okamoto and T. Ichitsubo: Bulletin of the Ceram. Soc. of Japan, 56 (2021), 331-336. – ident: 2 – ident: 18 – ident: 12 doi: 10.1016/j.electacta.2021.139336 – ident: 24 doi: 10.2464/jilm.73.537 – ident: 1 doi: 10.2320/matertrans.MT-MA2022008 – ident: 6 doi: 10.2464/jilm.72.92 – ident: 33 – ident: 7 doi: 10.1149/1.1429925 – ident: 16 – ident: 14 – ident: 8 doi: 10.1149/1.2186003 – ident: 5 doi: 10.2464/jilm.74.227 – ident: 20 – ident: 26 – ident: 22 – ident: 17 – ident: 3 – ident: 30 doi: 10.2320/jinstmet1952.60.9_870 – ident: 9 doi: 10.1039/D0CC05373B – ident: 31 doi: 10.2464/jilm.48.257 – ident: 29 doi: 10.2320/jinstmet1952.60.2_163 – ident: 19 – ident: 13 – ident: 15 – ident: 32 – ident: 4 doi: 10.2464/jilm.74.14 – ident: 28 doi: 10.2464/jilm.40.265 – ident: 10 doi: 10.1246/cl.210072 – ident: 21 – ident: 27 – ident: 11 doi: 10.1039/D1TA02419A – ident: 25 – ident: 23 |
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| Snippet | There is an urgent need to develop next-generation rechargeable batteries for a carbon-neutral society. In this context, our research team is focusing on... |
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| SubjectTerms | Aluminum Anodes Calcium Electrode materials Magnesium base alloys magnesium rechargeable battery manufacturing process Mechanical properties Rapid solidification Rechargeable batteries Ribbons single roll rapidly solidification method Surface properties |
| Title | Evaluation of various properties of ribbons of Mg-9%Al-3%Ca-based anode material for magnesium batteries produced by single-roll rapid solidification |
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