Removal of Ni2+ Ion from Artificial Nickel Wastewater by Using Natural Zeolite

The Ministry of the Environment of Japan has decided that the content of the nickel (H) ion included in the wastewater should be observed according to the effluent standard. Moreover, the new wastewater treatment techniques for Ni2+ ion are required. On the other hand, zeolite is well known as porou...

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Published inRESOURCES PROCESSING Vol. 48; no. 3; pp. 168 - 175
Main Authors KUZUNO, Eiichi, FUJITA, Toyohisa, SHIBAYAMA, Atsushi, MIYAZAKI, Toshio
Format Journal Article
LanguageEnglish
Published The Resources Processing Society of Japan 2001
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ISSN0912-4764
1883-9150
1883-9150
DOI10.4144/rpsj1986.48.168

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Abstract The Ministry of the Environment of Japan has decided that the content of the nickel (H) ion included in the wastewater should be observed according to the effluent standard. Moreover, the new wastewater treatment techniques for Ni2+ ion are required. On the other hand, zeolite is well known as porous and adsorptive ores. However, most of the zeolite used in practice, as adsorbent, is artificial. As a result, the useful fields of natural and fine zeolite are limited. In this study, the removal of Ni2+ ion from artificial Nickel wastewater was investigated by using no-reforming natural fine zeolite, and ammonium sulfate. It was found that the Ni2+ ion of 50 mg/l in artificial wastewater was completely removed as nickel hydroxide at pH8 employing natural zeorlite 0.5 g and ammonium ion (Al3+ ion) 10 mg/l. In addition, the equilibrium time of removal of Ni2+ ion was shorter. Consequently, it is concluded that in order to removed from waste water as nickel hydroxide the role of no-reforming natural fine zeolite and Al3+ ion were carrier and flocculating aid, respectively.
AbstractList The Ministry of the Environment of Japan has decided that the content of the nickel (H) ion included in the wastewater should be observed according to the effluent standard. Moreover, the new wastewater treatment techniques for Ni2+ ion are required. On the other hand, zeolite is well known as porous and adsorptive ores. However, most of the zeolite used in practice, as adsorbent, is artificial. As a result, the useful fields of natural and fine zeolite are limited. In this study, the removal of Ni2+ ion from artificial Nickel wastewater was investigated by using no-reforming natural fine zeolite, and ammonium sulfate. It was found that the Ni2+ ion of 50 mg/l in artificial wastewater was completely removed as nickel hydroxide at pH8 employing natural zeorlite 0.5 g and ammonium ion (Al3+ ion) 10 mg/l. In addition, the equilibrium time of removal of Ni2+ ion was shorter. Consequently, it is concluded that in order to removed from waste water as nickel hydroxide the role of no-reforming natural fine zeolite and Al3+ ion were carrier and flocculating aid, respectively.
Author MIYAZAKI, Toshio
SHIBAYAMA, Atsushi
FUJITA, Toyohisa
KUZUNO, Eiichi
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References 1) 環境省水質保全局水質管理課:平成10年度水質汚濁に係わる要監視項目の調査結果について,平成11年環境庁(現環境省)水質保全局長通知(1999
2) 例えば, Macko, R. and Maso, T.: Electrochemical treatment of spent electroless nickel solution, Plat. Surf. Finish (USA), Vol. 87, No. 3, p. 10-12 (2000
7) 富永博夫:ゼオライトの科学と応用,講談社,p.39(1987
13) 矢沢彬,江口元徳:湿式製錬と廃水処理,P.273-280(1975
6) 原伸宣,高橋浩:ゼオライト―基礎と応用―,講談社,p.58(1975
10) 秋田大学鉱山学部通信教育講座教材作成専門委会,廃水処理,p.30-38(1995
11) 真宮三男,薛玉蘭,葛野栄一;中和殿物中の水酸化アルミニウムと石膏の浮選分離,秋田大学鉱山学部地下資源研究施設報告別冊,No.47,p.1-9(1982
4) 例えば,竹内節:吸着の化学一表面・界面制御のキーテクノロジー―,産業図書,p.101-106(1995
3) 例えば Cohen, E. M.: Nickel recovery for planting plant waste solutions, Pcoc. Mid-Ad. Ind. Hazard Waste Conf. (USA), Vol.32nd, p. 691-697 (2000
8) Ouki,S. K. and Kavannagh, M.: Treatment of metals-contaminated wastewaters by use of natural zeolite,WaterSci.Tech.,Vol.39,No.10/11,p.115-122(1999
12) 例えば,湯川恭啓:機能性凝集剤Gellannicによる排水処理2ニッケルイオン,銅イオン,亜鉛イオン含有排水,用水と廃水,Vbl.42,No.2,P.177-180(2000
9) 水管理技術研究会;凝集沈殿,p.302-308,(株)工学図書(1966
5) 杉岡正敏,中田由貴子:天然ゼオライトの表面改質による高機能化,資源・素材学会'92秋季大会講演要旨集(S-5),p.14-17(1992
References_xml – reference: 10) 秋田大学鉱山学部通信教育講座教材作成専門委会,廃水処理,p.30-38(1995)
– reference: 11) 真宮三男,薛玉蘭,葛野栄一;中和殿物中の水酸化アルミニウムと石膏の浮選分離,秋田大学鉱山学部地下資源研究施設報告別冊,No.47,p.1-9(1982)
– reference: 2) 例えば, Macko, R. and Maso, T.: Electrochemical treatment of spent electroless nickel solution, Plat. Surf. Finish (USA), Vol. 87, No. 3, p. 10-12 (2000)
– reference: 13) 矢沢彬,江口元徳:湿式製錬と廃水処理,P.273-280(1975)
– reference: 3) 例えば Cohen, E. M.: Nickel recovery for planting plant waste solutions, Pcoc. Mid-Ad. Ind. Hazard Waste Conf. (USA), Vol.32nd, p. 691-697 (2000)
– reference: 1) 環境省水質保全局水質管理課:平成10年度水質汚濁に係わる要監視項目の調査結果について,平成11年環境庁(現環境省)水質保全局長通知(1999)
– reference: 6) 原伸宣,高橋浩:ゼオライト―基礎と応用―,講談社,p.58(1975)
– reference: 7) 富永博夫:ゼオライトの科学と応用,講談社,p.39(1987)
– reference: 8) Ouki,S. K. and Kavannagh, M.: Treatment of metals-contaminated wastewaters by use of natural zeolite,WaterSci.Tech.,Vol.39,No.10/11,p.115-122(1999)
– reference: 5) 杉岡正敏,中田由貴子:天然ゼオライトの表面改質による高機能化,資源・素材学会'92秋季大会講演要旨集(S-5),p.14-17(1992)
– reference: 9) 水管理技術研究会;凝集沈殿,p.302-308,(株)工学図書(1966)
– reference: 4) 例えば,竹内節:吸着の化学一表面・界面制御のキーテクノロジー―,産業図書,p.101-106(1995)
– reference: 12) 例えば,湯川恭啓:機能性凝集剤Gellannicによる排水処理2ニッケルイオン,銅イオン,亜鉛イオン含有排水,用水と廃水,Vbl.42,No.2,P.177-180(2000)
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Title Removal of Ni2+ Ion from Artificial Nickel Wastewater by Using Natural Zeolite
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