P‐Type Boron‐Doped Monolayer Graphene with Tunable Bandgap for Enhanced Photocatalytic H 2 Evolution under Visible‐Light Irradiation
Graphene‐based materials are considered as one of the promising photocatalysts for hydrogen production from solar‐driven water splitting yet subject to zero bandgap limitation. Here, we report an efficient one‐step pyrolysis for preparing p‐type boron‐doped monolayer graphene. Through varying the do...
Saved in:
| Published in | ChemCatChem Vol. 11; no. 20; pp. 5145 - 5153 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
18.10.2019
|
| Online Access | Get full text |
| ISSN | 1867-3880 1867-3899 |
| DOI | 10.1002/cctc.201901258 |
Cover
| Abstract | Graphene‐based materials are considered as one of the promising photocatalysts for hydrogen production from solar‐driven water splitting yet subject to zero bandgap limitation. Here, we report an efficient one‐step pyrolysis for preparing p‐type boron‐doped monolayer graphene. Through varying the dopant content, the bandgap of the boron‐doped graphene can be tuned. Moreover, a p‐type conductivity behavior of the boron‐doped monolayer graphene is demonstrated by the four‐probe measurement and Hall effect measurement. The boron‐doped graphene can service as an efficient semiconductor photocatalyst for hydrogen production from water splitting under visible‐light irradiation. The optimized boron‐doped graphene can deliver a high H 2 production rate of 219.3 μmol h −1 g −1 without any cocatalyst. The photocatalyst can be recycled at least four times without obvious activity decay and maintain high H 2 production rate of 215.3 μmol h −1 g −1 after 60 h reaction, indicative of excellent stability. This work may open up a new avenue for fabrication of new photocatalysts based on p‐type boron‐doped monolayer graphene. |
|---|---|
| AbstractList | Graphene‐based materials are considered as one of the promising photocatalysts for hydrogen production from solar‐driven water splitting yet subject to zero bandgap limitation. Here, we report an efficient one‐step pyrolysis for preparing p‐type boron‐doped monolayer graphene. Through varying the dopant content, the bandgap of the boron‐doped graphene can be tuned. Moreover, a p‐type conductivity behavior of the boron‐doped monolayer graphene is demonstrated by the four‐probe measurement and Hall effect measurement. The boron‐doped graphene can service as an efficient semiconductor photocatalyst for hydrogen production from water splitting under visible‐light irradiation. The optimized boron‐doped graphene can deliver a high H 2 production rate of 219.3 μmol h −1 g −1 without any cocatalyst. The photocatalyst can be recycled at least four times without obvious activity decay and maintain high H 2 production rate of 215.3 μmol h −1 g −1 after 60 h reaction, indicative of excellent stability. This work may open up a new avenue for fabrication of new photocatalysts based on p‐type boron‐doped monolayer graphene. |
| Author | Wu, Yujun Younas, Waqar Cao, Chuanbao Zhu, Youqi Han, Zhanli Ma, Xilan |
| Author_xml | – sequence: 1 givenname: Yujun surname: Wu fullname: Wu, Yujun organization: Research Center of Materials Science and Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications Beijing Institute of Technology Beijing 100081 P.R. China – sequence: 2 givenname: Zhanli surname: Han fullname: Han, Zhanli organization: Research Center of Materials Science and Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications Beijing Institute of Technology Beijing 100081 P.R. China – sequence: 3 givenname: Waqar surname: Younas fullname: Younas, Waqar organization: Research Center of Materials Science and Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications Beijing Institute of Technology Beijing 100081 P.R. China – sequence: 4 givenname: Youqi surname: Zhu fullname: Zhu, Youqi organization: Research Center of Materials Science and Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications Beijing Institute of Technology Beijing 100081 P.R. China – sequence: 5 givenname: Xilan surname: Ma fullname: Ma, Xilan organization: Research Center of Materials Science and Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications Beijing Institute of Technology Beijing 100081 P.R. China – sequence: 6 givenname: Chuanbao orcidid: 0000-0003-2830-4383 surname: Cao fullname: Cao, Chuanbao organization: Research Center of Materials Science and Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications Beijing Institute of Technology Beijing 100081 P.R. China |
| BookMark | eNp1kL1OwzAUhS1UJNrCyuwXaPFPfpwRSmkrFcFQWKMb22mMgh05LigbMxPPyJOQAuqAxHTvlc537tEZoYF1ViN0TsmUEsIupAxyygjNCGWxOEJDKpJ0wkWWDQ67ICdo1LZPhCQZT-Mher__fPvYdI3GV8472x_XrtEK3zrraui0xwsPTaWtxq8mVHizs1DUvRqs2kKDS-fx3FZgZQ_dVy44CQHqLhiJl5jh-Yurd8E4i3dW9W6PpjU93_9Zm20V8Mp7UAb2ilN0XELd6rPfOUYPN_PNbDlZ3y1Ws8v1RNIkC5O0YBoUUyVJVRTzKBYqi6gQpUwVp0WkOBRUc8aBFYUmEOtI6AzKXsjTFBI-RtMfX-ld23pd5o03z-C7nJJ832S-bzI_NNkD0R9AmvAdOXgw9X_YF9cWf7o |
| CitedBy_id | crossref_primary_10_1016_j_commatsci_2024_112861 crossref_primary_10_1038_s41598_020_74286_4 crossref_primary_10_1039_D0TA08704A crossref_primary_10_1016_j_electacta_2024_144034 crossref_primary_10_1007_s11244_021_01539_5 crossref_primary_10_1039_D2DT04124C crossref_primary_10_1039_D4TC01429D crossref_primary_10_3390_ijms22136832 crossref_primary_10_1016_j_apsusc_2021_149709 crossref_primary_10_1016_j_apsusc_2021_150380 crossref_primary_10_1021_acs_jpcc_3c04749 crossref_primary_10_1016_j_jiec_2024_08_029 crossref_primary_10_1039_D3QI00700F crossref_primary_10_1016_j_mtcomm_2022_104495 crossref_primary_10_1016_j_micromeso_2021_111514 crossref_primary_10_1016_j_jphotochemrev_2024_100679 crossref_primary_10_1016_j_enconman_2021_115133 crossref_primary_10_1039_D1ME00179E crossref_primary_10_1038_s41598_020_67977_5 crossref_primary_10_1002_cptc_202200267 crossref_primary_10_1002_smtd_202201596 crossref_primary_10_1039_D0TA11939C |
| Cites_doi | 10.1002/jctb.5779 10.1021/acscatal.8b03233 10.1016/j.cattod.2018.05.041 10.1021/nl803025e 10.1016/j.jphotochem.2018.06.002 10.1016/j.nanoen.2016.08.041 10.1016/j.apsusc.2018.02.074 10.1039/b504818d 10.1039/C4TA04182H 10.1039/C9TC03539G 10.1126/science.aaa3145 10.1038/nmat2317 10.1039/C8EE01046C 10.1021/cm0630800 10.1016/j.carbon.2014.11.002 10.1021/cs4000975 10.1021/acsami.5b02641 10.1002/anie.201310635 10.1016/j.apsusc.2015.08.177 10.1007/s12274-017-1703-3 10.1021/cm071588c 10.1021/acs.langmuir.6b03317 10.1002/adma.201301207 10.1002/smll.201203021 10.1016/j.nantod.2016.05.008 10.1021/acsnano.5b07676 10.1002/adfm.201401279 10.1021/acsami.6b12060 10.1021/acscatal.6b00922 10.1002/anie.201813417 10.1038/414625a 10.1002/smll.201600382 10.1039/C7RA05770A 10.1016/j.apcatb.2011.10.028 10.1039/b922793h 10.1021/cm1019102 10.1039/c2cc35862j 10.1021/jp405562b 10.1021/acsnano.8b01271 10.1021/jacs.7b08657 10.1038/238037a0 |
| ContentType | Journal Article |
| DBID | AAYXX CITATION |
| DOI | 10.1002/cctc.201901258 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | CrossRef |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1867-3899 |
| EndPage | 5153 |
| ExternalDocumentID | 10_1002_cctc_201901258 |
| GroupedDBID | 05W 0R~ 1OC 33P 4.4 5DZ 77Q 8-1 AAESR AAHQN AAIHA AAMMB AAMNL AANLZ AASGY AAXRX AAYCA AAYXX AAZKR ABCUV ABDBF ACAHQ ACCZN ACGFS ACIWK ACPOU ACUHS ACXBN ACXQS ADBBV ADKYN ADMGS ADOZA ADXAS ADZMN AEFGJ AEIGN AENEX AEUYR AEYWJ AFBPY AFFPM AFGKR AFWVQ AFZJQ AGHNM AGXDD AGYGG AHBTC AIDQK AIDYY AITYG AIURR ALMA_UNASSIGNED_HOLDINGS ALUQN ALVPJ AMYDB AZVAB BDRZF BFHJK BMXJE BRXPI CITATION DCZOG DRFUL DRSTM DU5 EBS EJD ESX G-S HGLYW HZ~ I-F LATKE LEEKS LITHE LOXES LUTES LYRES MEWTI MXFUL MXSTM MY~ NNB O9- P2W ROL SUPJJ TUS WBKPD WOHZO WXSBR XV2 ZZTAW |
| ID | FETCH-LOGICAL-c169t-7b2ead2df07d453458d94188fc7d31b4d3ab1e323a2bbe0a5e48e9af458377a63 |
| ISSN | 1867-3880 |
| IngestDate | Thu Apr 24 23:08:55 EDT 2025 Thu Oct 16 04:25:59 EDT 2025 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 20 |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c169t-7b2ead2df07d453458d94188fc7d31b4d3ab1e323a2bbe0a5e48e9af458377a63 |
| ORCID | 0000-0003-2830-4383 |
| PageCount | 9 |
| ParticipantIDs | crossref_primary_10_1002_cctc_201901258 crossref_citationtrail_10_1002_cctc_201901258 |
| PublicationCentury | 2000 |
| PublicationDate | 2019-10-18 |
| PublicationDateYYYYMMDD | 2019-10-18 |
| PublicationDate_xml | – month: 10 year: 2019 text: 2019-10-18 day: 18 |
| PublicationDecade | 2010 |
| PublicationTitle | ChemCatChem |
| PublicationYear | 2019 |
| References | e_1_2_7_5_1 Lang D. (e_1_2_7_20_2) 2015 e_1_2_7_9_1 Cao R. Y. (e_1_2_7_7_2) 2018 e_1_2_7_19_1 e_1_2_7_17_2 e_1_2_7_15_2 e_1_2_7_41_1 e_1_2_7_1_1 e_1_2_7_43_1 e_1_2_7_11_2 e_1_2_7_45_2 e_1_2_7_47_1 e_1_2_7_26_2 e_1_2_7_49_1 e_1_2_7_28_1 Xing W. N. (e_1_2_7_13_2) 2016 Kong X. K. (e_1_2_7_30_1) 2017 e_1_2_7_50_1 e_1_2_7_25_1 e_1_2_7_31_1 e_1_2_7_52_1 e_1_2_7_23_2 e_1_2_7_54_1 e_1_2_7_21_2 e_1_2_7_33_2 e_1_2_7_35_1 e_1_2_7_56_1 e_1_2_7_37_1 e_1_2_7_58_1 e_1_2_7_39_2 e_1_2_7_6_1 e_1_2_7_4_1 e_1_2_7_2_2 e_1_2_7_8_2 e_1_2_7_18_2 Du X. Q. (e_1_2_7_34_2) 2016 e_1_2_7_16_2 e_1_2_7_40_1 e_1_2_7_14_1 e_1_2_7_42_1 e_1_2_7_12_2 e_1_2_7_10_2 e_1_2_7_44_2 e_1_2_7_46_1 e_1_2_7_48_1 e_1_2_7_29_1 Shen S. L. (e_1_2_7_27_2) 2015 Zhao Y. (e_1_2_7_3_2) 2018 e_1_2_7_51_1 e_1_2_7_53_1 e_1_2_7_24_2 e_1_2_7_55_1 e_1_2_7_32_2 e_1_2_7_22_1 e_1_2_7_57_1 e_1_2_7_36_1 e_1_2_7_38_2 |
| References_xml | – ident: e_1_2_7_11_2 doi: 10.1002/jctb.5779 – ident: e_1_2_7_2_2 doi: 10.1021/acscatal.8b03233 – start-page: 10 year: 2018 ident: e_1_2_7_7_2 publication-title: ChemCatChem – ident: e_1_2_7_21_2 doi: 10.1016/j.cattod.2018.05.041 – start-page: 8 year: 2016 ident: e_1_2_7_34_2 publication-title: ChemCatChem – ident: e_1_2_7_25_1 – ident: e_1_2_7_41_1 doi: 10.1021/nl803025e – ident: e_1_2_7_45_2 doi: 10.1016/j.jphotochem.2018.06.002 – ident: e_1_2_7_48_1 doi: 10.1016/j.nanoen.2016.08.041 – ident: e_1_2_7_32_2 doi: 10.1016/j.apsusc.2018.02.074 – ident: e_1_2_7_57_1 doi: 10.1039/b504818d – ident: e_1_2_7_15_2 doi: 10.1039/C4TA04182H – start-page: 8 year: 2016 ident: e_1_2_7_13_2 publication-title: ChemCatChem – ident: e_1_2_7_39_2 doi: 10.1039/C9TC03539G – ident: e_1_2_7_52_1 doi: 10.1126/science.aaa3145 – ident: e_1_2_7_50_1 doi: 10.1038/nmat2317 – ident: e_1_2_7_47_1 doi: 10.1039/C8EE01046C – ident: e_1_2_7_58_1 doi: 10.1021/cm0630800 – ident: e_1_2_7_35_1 doi: 10.1016/j.carbon.2014.11.002 – ident: e_1_2_7_19_1 – ident: e_1_2_7_46_1 doi: 10.1021/cs4000975 – ident: e_1_2_7_17_2 doi: 10.1021/acsami.5b02641 – ident: e_1_2_7_36_1 doi: 10.1002/anie.201310635 – ident: e_1_2_7_43_1 – ident: e_1_2_7_23_2 doi: 10.1016/j.apsusc.2015.08.177 – start-page: 9 year: 2017 ident: e_1_2_7_30_1 publication-title: ChemCatChem – ident: e_1_2_7_38_2 doi: 10.1007/s12274-017-1703-3 – ident: e_1_2_7_56_1 doi: 10.1021/cm071588c – ident: e_1_2_7_29_1 doi: 10.1021/acs.langmuir.6b03317 – ident: e_1_2_7_37_1 – ident: e_1_2_7_26_2 doi: 10.1002/adma.201301207 – ident: e_1_2_7_33_2 doi: 10.1002/smll.201203021 – start-page: 7 year: 2015 ident: e_1_2_7_20_2 publication-title: ChemCatChem – ident: e_1_2_7_14_1 – ident: e_1_2_7_12_2 doi: 10.1016/j.nantod.2016.05.008 – ident: e_1_2_7_42_1 doi: 10.1021/acsnano.5b07676 – ident: e_1_2_7_28_1 doi: 10.1002/adfm.201401279 – ident: e_1_2_7_40_1 doi: 10.1021/acsami.6b12060 – ident: e_1_2_7_22_1 – ident: e_1_2_7_18_2 doi: 10.1021/acscatal.6b00922 – ident: e_1_2_7_10_2 doi: 10.1002/anie.201813417 – start-page: 7 year: 2015 ident: e_1_2_7_27_2 publication-title: ChemCatChem – ident: e_1_2_7_54_1 doi: 10.1038/414625a – ident: e_1_2_7_24_2 doi: 10.1002/smll.201600382 – ident: e_1_2_7_44_2 doi: 10.1039/C7RA05770A – ident: e_1_2_7_1_1 – ident: e_1_2_7_49_1 doi: 10.1016/j.apcatb.2011.10.028 – ident: e_1_2_7_55_1 doi: 10.1039/b922793h – ident: e_1_2_7_53_1 doi: 10.1021/cm1019102 – ident: e_1_2_7_51_1 doi: 10.1039/c2cc35862j – ident: e_1_2_7_16_2 doi: 10.1021/jp405562b – ident: e_1_2_7_6_1 – ident: e_1_2_7_8_2 doi: 10.1021/acsnano.8b01271 – ident: e_1_2_7_9_1 – start-page: 10 year: 2018 ident: e_1_2_7_3_2 publication-title: ChemCatChem – ident: e_1_2_7_4_1 doi: 10.1021/jacs.7b08657 – ident: e_1_2_7_31_1 – ident: e_1_2_7_5_1 doi: 10.1038/238037a0 |
| SSID | ssj0069375 |
| Score | 2.3652747 |
| Snippet | Graphene‐based materials are considered as one of the promising photocatalysts for hydrogen production from solar‐driven water splitting yet subject to zero... |
| SourceID | crossref |
| SourceType | Enrichment Source Index Database |
| StartPage | 5145 |
| Title | P‐Type Boron‐Doped Monolayer Graphene with Tunable Bandgap for Enhanced Photocatalytic H 2 Evolution under Visible‐Light Irradiation |
| Volume | 11 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVEBS databaseName: Academic Search Ultimate [EBSCO] customDbUrl: https://search.ebscohost.com/login.aspx?authtype=ip,shib&custid=s3936755&profile=ehost&defaultdb=asn eissn: 1867-3899 dateEnd: 20241105 omitProxy: true ssIdentifier: ssj0069375 issn: 1867-3880 databaseCode: ABDBF dateStart: 20110509 isFulltext: true titleUrlDefault: https://search.ebscohost.com/direct.asp?db=asn providerName: EBSCOhost |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3LjtMwFLVKZwGbEU8xw0NeILGIAonjPLycdjoUBKiLDozYVH51WlSSTpUgwYo1K76FT-JLuI4TT4qKNLBJ2ys7aXpPzr12r48RehIwReehIj7hMvCppMJnJA1hlJJBfI45k5lZO_zmbTI-pa_O4rNe72enaqkqxTP5dee6kv_xKtjAr2aV7D941p0UDPAe_AtH8DAcr-TjiStVMMNJb2DUCJzpuFhDMgnPLAxeIa_2XhhpamA2O_U6reyiqQHP1Tlf19WGo3xh6wEmi6Is6omdL0bPdewRb_S5uZN649yN924Jz9JKu6u9NoN87-VmY7QOnLNbCYSF_jTkpXlxQaCqyb_6WOWXJFgzoJnCXi27bGTXnL3nF9xVEn9Y2P5FdbHsTlyEzDD-FtdmwNFGi8aGoq7N7pnkCDrsAJEEHbqFbC_uhG4AV7QzLFiZWSlr0UqTAhGrF7-tv_1HXHTVilbZmcxM_5nrfw3tEYgkQR_tHQ2OBydt_E8g4TOFs-72WqnQgDzf_gadVKiT00xvov1mMIKPLLJuoZ7Ob6Prw3YPwDvo--TXtx8GW7jGFnyoUYUdqnCLKmxQhRtU4QZVGFCFW1ThbVThMSbYoQrXqMINquA6NZ5wB0930enJaDoc-83uHb4ME1b6qSDAUkTNg1TROKJxphgNs2wuUxWFgqqIi1BHJOJECB3wWNNMMz43f-SnKU-ie6ifF7m-j3DKBZgyyTRjVCvKqGRMJAp6QKxOsgPktz_kTDbS9maHldVst-sO0FPXfm1FXf7S8vDKLR-gG5cgf4j65abSjyBfLcXjBiC_AZ4ils8 |
| linkProvider | EBSCOhost |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=P%E2%80%90Type+Boron%E2%80%90Doped+Monolayer+Graphene+with+Tunable+Bandgap+for+Enhanced+Photocatalytic+H+2+Evolution+under+Visible%E2%80%90Light+Irradiation&rft.jtitle=ChemCatChem&rft.au=Wu%2C+Yujun&rft.au=Han%2C+Zhanli&rft.au=Younas%2C+Waqar&rft.au=Zhu%2C+Youqi&rft.date=2019-10-18&rft.issn=1867-3880&rft.eissn=1867-3899&rft.volume=11&rft.issue=20&rft.spage=5145&rft.epage=5153&rft_id=info:doi/10.1002%2Fcctc.201901258&rft.externalDBID=n%2Fa&rft.externalDocID=10_1002_cctc_201901258 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1867-3880&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1867-3880&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1867-3880&client=summon |