Structure of Isolated Xanthone in the T 1 State Obtained via Combined UV/IR Spectroscopy
In order to extend combined UV/IR spectroscopy to triplet states, xanthone has been chosen as a model system due to its efficient intersystem crossing (ISC). The IR/R2PI (resonant two‐photon ionisation) spectrum of the electronic ground state (S 0 ) as well as the IR spectrum of the T 1 state have b...
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| Published in | Chemphyschem Vol. 10; no. 11; pp. 1882 - 1886 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
03.08.2009
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| Online Access | Get full text |
| ISSN | 1439-4235 1439-7641 |
| DOI | 10.1002/cphc.200900097 |
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| Abstract | In order to extend combined UV/IR spectroscopy to triplet states, xanthone has been chosen as a model system due to its efficient intersystem crossing (ISC). The IR/R2PI (resonant two‐photon ionisation) spectrum of the electronic ground state (S
0
) as well as the IR spectrum of the T
1
state have been recorded in a supersonic jet. We show that the IR spectrum of a triplet state can be recorded subsequent to an ISC. In combination with DFT and TDDFT calculations, structural assignments are performed and geometrical changes are identified. |
|---|---|
| AbstractList | In order to extend combined UV/IR spectroscopy to triplet states, xanthone has been chosen as a model system due to its efficient intersystem crossing (ISC). The IR/R2PI (resonant two‐photon ionisation) spectrum of the electronic ground state (S
0
) as well as the IR spectrum of the T
1
state have been recorded in a supersonic jet. We show that the IR spectrum of a triplet state can be recorded subsequent to an ISC. In combination with DFT and TDDFT calculations, structural assignments are performed and geometrical changes are identified. |
| Author | Funk, Andreas Bartl, Kristina Gerhards, Markus |
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| Title | Structure of Isolated Xanthone in the T 1 State Obtained via Combined UV/IR Spectroscopy |
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