Valence electron modulation strategy in high–entropy alloy nanozyme with cold-adapted properties integrated with mobile APP for detecting antioxidants in cold-chain transportation of beverages
The continuous monitoring of food quality in refrigerated environments has been a subject of considerable research interest. High-entropy alloys (HEAs) show great potential in extreme environments owing to their unique thermodynamic characteristics and synergistic performance enhancements derived fr...
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| Published in | Sensors and actuators. B, Chemical Vol. 446; p. 138711 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.01.2026
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0925-4005 |
| DOI | 10.1016/j.snb.2025.138711 |
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| Abstract | The continuous monitoring of food quality in refrigerated environments has been a subject of considerable research interest. High-entropy alloys (HEAs) show great potential in extreme environments owing to their unique thermodynamic characteristics and synergistic performance enhancements derived from multi-element compositions. Herein, a lower temperature (170 ℃) synthetic strategy was developed for the preparation of high-entropy alloy nanozyme (HEAzyme). The study demonstrates that the HEAzyme exhibits cold-adapted peroxidase-like activity, maintaining comparable catalytic efficacy at 4 ℃ and 20 ℃, and exhibiting 69.9 % efficiency even at −20 ℃. This cold-adapted activity is attributable to the incorporation of Ce element with a variable oxidation state (Ce3 +/Ce4+), which endows metals with multivalent electron transfer ability while forming a synergistic catalytic center with other metals. A mobile APP was developed to assist in detecting antioxidant content during cold-chain transportation (4 ℃), greatly simplifying the testing process.
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•Rational selection of five metals in HEAzyme.•HEAzyme with excellent cold-adapted peroxidase-like activity.•Development of mobile APP for point-of-care and on-site detection.•Food quality monitoring in cold-chain environments. |
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| AbstractList | The continuous monitoring of food quality in refrigerated environments has been a subject of considerable research interest. High-entropy alloys (HEAs) show great potential in extreme environments owing to their unique thermodynamic characteristics and synergistic performance enhancements derived from multi-element compositions. Herein, a lower temperature (170 ℃) synthetic strategy was developed for the preparation of high-entropy alloy nanozyme (HEAzyme). The study demonstrates that the HEAzyme exhibits cold-adapted peroxidase-like activity, maintaining comparable catalytic efficacy at 4 ℃ and 20 ℃, and exhibiting 69.9 % efficiency even at −20 ℃. This cold-adapted activity is attributable to the incorporation of Ce element with a variable oxidation state (Ce3 +/Ce4+), which endows metals with multivalent electron transfer ability while forming a synergistic catalytic center with other metals. A mobile APP was developed to assist in detecting antioxidant content during cold-chain transportation (4 ℃), greatly simplifying the testing process.
[Display omitted]
•Rational selection of five metals in HEAzyme.•HEAzyme with excellent cold-adapted peroxidase-like activity.•Development of mobile APP for point-of-care and on-site detection.•Food quality monitoring in cold-chain environments. |
| ArticleNumber | 138711 |
| Author | Ma, Yu Ru, Yi Li, Jie Han, Qing Huang, Hui Li, Yongxin Zheng, Xingna |
| Author_xml | – sequence: 1 givenname: Jie surname: Li fullname: Li, Jie organization: College of Food Science and Engineering, Jilin University, Changchun 130062, PR China – sequence: 2 givenname: Yu surname: Ma fullname: Ma, Yu organization: College of Food Science and Engineering, Jilin University, Changchun 130062, PR China – sequence: 3 givenname: Qing surname: Han fullname: Han, Qing organization: Key Laboratory of Groundwater Resources and Environment (Jilin University), Ministry of Education, College of New Energy and Environment, Jilin University, Changchun 130021, PR China – sequence: 4 givenname: Xingna surname: Zheng fullname: Zheng, Xingna organization: College of Food Science and Engineering, Jilin University, Changchun 130062, PR China – sequence: 5 givenname: Yi surname: Ru fullname: Ru, Yi organization: College of Food Science and Engineering, Jilin University, Changchun 130062, PR China – sequence: 6 givenname: Yongxin surname: Li fullname: Li, Yongxin organization: Key Laboratory of Groundwater Resources and Environment (Jilin University), Ministry of Education, College of New Energy and Environment, Jilin University, Changchun 130021, PR China – sequence: 7 givenname: Hui orcidid: 0000-0002-9256-5169 surname: Huang fullname: Huang, Hui email: huanghui@jlu.edu.cn organization: College of Food Science and Engineering, Jilin University, Changchun 130062, PR China |
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| Keywords | Cold-chain monitoring High-entropy alloy nanozyme Cold-adapted properties Mobile APP |
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