The structures of two reaction products of ditertiary-butylacetylene with diiron nonacarbonyl. A new ironiron double bond
The reaction of a commercial sample of 5-BuCC-t-Bu with Fe 2(CO) 9 gave two products. One is green (OC) 3 Fe(μ-t-BuCC-t-Bu)Fe(CO) 3; it contains an FeFe (double) bond with a length of 2.316(4) Å. The other, dark orange, product arises from reaction of Fe 2(CO) 9 with the impurity CH 2C(CH 3)CC-...
Saved in:
| Published in | Journal of organometallic chemistry Vol. 94; no. 3; pp. C53 - C55 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.08.1975
|
| Online Access | Get full text |
| ISSN | 0022-328X 1872-8561 |
| DOI | 10.1016/S0022-328X(00)86963-6 |
Cover
| Abstract | The reaction of a commercial sample of 5-BuCC-t-Bu with Fe
2(CO)
9 gave two products. One is green (OC)
3 Fe(μ-t-BuCC-t-Bu)Fe(CO)
3; it contains an FeFe (double) bond with a length of 2.316(4) Å. The other, dark orange, product arises from reaction of Fe
2(CO)
9 with the impurity CH
2C(CH
3)CC-t-Bu (L) and has the formula (LCO)Fe
2(CO)
6. The structures of both compounds as obtained from isotropic refinement of X-ray data are reported. |
|---|---|
| AbstractList | The reaction of a commercial sample of 5-BuCC-t-Bu with Fe
2(CO)
9 gave two products. One is green (OC)
3 Fe(μ-t-BuCC-t-Bu)Fe(CO)
3; it contains an FeFe (double) bond with a length of 2.316(4) Å. The other, dark orange, product arises from reaction of Fe
2(CO)
9 with the impurity CH
2C(CH
3)CC-t-Bu (L) and has the formula (LCO)Fe
2(CO)
6. The structures of both compounds as obtained from isotropic refinement of X-ray data are reported. |
| Author | Cotton, F.Albert Stults, B.Ray Jamerson, Jackie D. |
| Author_xml | – sequence: 1 givenname: F.Albert surname: Cotton fullname: Cotton, F.Albert – sequence: 2 givenname: Jackie D. surname: Jamerson fullname: Jamerson, Jackie D. – sequence: 3 givenname: B.Ray surname: Stults fullname: Stults, B.Ray |
| BookMark | eNqFkMtKAzEUQINUsD4-QchSF1NvMp1MBhdSii8ouFDBXcgktxgZJyWTWgr-h7_iV_kNZqq4cNNNsjg5l9yzTwatb5GQYwYjBkyc3QNwnuVcPp0AnEpRiTwTO2TIZMkzWQg2IMO_J3tkv-teAIDlIIfk_eEZaRfD0sRlwI76OY0rTwNqE51v6SJ4m9gGWBcxRKfDOquXcd1og-nEFunKxeeEXUhG-pw2OtS-XTcjOqEtrmgPvj4-N9z6Zd0gTdwekt25bjo8-r0PyOPV5cP0JpvdXd9OJ7PMsGIsMtTAoWJQaSYkVpUpxbgoeF3AvOCillDlBiW3lplc27rStRCllYJxLrAsx_kBKX7mmuC7LuBcLYJ7TXsoBqpPqDYJVd9HAahNQiWSd_7PMy7qvksM2jVb7YsfG9Nqbw6D6ozD1qB1AU1U1rstE74B8ruRHw |
| CitedBy_id | crossref_primary_10_1039_C7SC00570A crossref_primary_10_1002_ejic_202000897 crossref_primary_10_1016_S0022_328X_00_95281_1 crossref_primary_10_1016_j_jorganchem_2009_10_005 crossref_primary_10_1021_jp104689r crossref_primary_10_1021_om3008426 crossref_primary_10_1002_chin_197551078 crossref_primary_10_1016_S0020_1693_00_81988_X crossref_primary_10_1021_acs_chemrev_8b00297 crossref_primary_10_1016_0039_6028_81_90274_0 crossref_primary_10_1016_S0022_328X_00_90569_2 crossref_primary_10_1016_0301_0104_81_85116_6 crossref_primary_10_1016_S0022_328X_00_90046_9 crossref_primary_10_1016_j_ccr_2017_07_001 crossref_primary_10_1016_j_poly_2018_06_003 crossref_primary_10_1016_S0022_328X_00_80885_2 crossref_primary_10_1021_om801211g |
| Cites_doi | 10.1039/C39740000563 10.1039/C29710000608 10.1016/S0022-328X(00)93021-3 10.1021/ja00787a056 10.1021/ja01510a005 10.1515/znb-1973-7-829 |
| ContentType | Journal Article |
| Copyright | 1975 |
| Copyright_xml | – notice: 1975 |
| DBID | AAYXX CITATION |
| DOI | 10.1016/S0022-328X(00)86963-6 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1872-8561 |
| EndPage | C55 |
| ExternalDocumentID | 10_1016_S0022_328X_00_86963_6 S0022328X00869636 |
| GroupedDBID | --K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 29L 3EH 4.4 457 4G. 5GY 5VS 6TJ 7-5 71M 8P~ 9JM 9JN AABNK AABXZ AACTN AAEDT AAEDW AAEPC AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO ABEFU ABFNM ABFRF ABGSF ABJNI ABMAC ABUDA ABXDB ABXRA ABYKQ ACBEA ACDAQ ACGFO ACGFS ACNCT ACNNM ACRLP ADBBV ADECG ADEZE ADIYS ADMUD ADUVX AEBSH AEFWE AEHWI AEKER AENEX AEZYN AFKWA AFRZQ AFTJW AFXIZ AFZHZ AGHFR AGRDE AGUBO AGYEJ AHHHB AI. AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BBWZM BKOJK BLXMC CS3 DOVZS EBS EFJIC EFLBG EJD EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HMH HVGLF HZ~ H~9 IHE J1W K-O KOM M23 M41 MAGPM MO0 N9A NDZJH O-L O9- OAUVE OHT OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SCB SCC SDF SDG SDP SES SEW SIC SPC SPCBC SSK SSM SSU SSZ T5K TN5 TWZ UQL VH1 WH7 WUQ XFK XJT XPP YK3 YQT ZCG ZMT ~G- AATTM AAXKI AAYWO AAYXX ABWVN ACRPL ACVFH ADCNI ADNMO AEIPS AEUPX AFJKZ AFPUW AGCQF AGQPQ AGRNS AIGII AIIUN AKBMS AKRWK AKYEP ANKPU APXCP BNPGV CITATION SSH |
| ID | FETCH-LOGICAL-c1546-ea0209109a168e99c764552b50f526b8093ce82dd1c3adb9ab667d861226e7743 |
| ISSN | 0022-328X |
| IngestDate | Thu Apr 24 22:51:05 EDT 2025 Tue Jul 01 04:04:01 EDT 2025 Fri Feb 23 02:26:38 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 3 |
| Language | English |
| License | https://www.elsevier.com/tdm/userlicense/1.0 |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c1546-ea0209109a168e99c764552b50f526b8093ce82dd1c3adb9ab667d861226e7743 |
| ParticipantIDs | crossref_primary_10_1016_S0022_328X_00_86963_6 crossref_citationtrail_10_1016_S0022_328X_00_86963_6 elsevier_sciencedirect_doi_10_1016_S0022_328X_00_86963_6 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 1900 |
| PublicationDate | 1975-8-00 |
| PublicationDateYYYYMMDD | 1975-08-01 |
| PublicationDate_xml | – month: 08 year: 1975 text: 1975-8-00 |
| PublicationDecade | 1970 |
| PublicationTitle | Journal of organometallic chemistry |
| PublicationYear | 1975 |
| Publisher | Elsevier B.V |
| Publisher_xml | – name: Elsevier B.V |
| References | Calderon, Fontana, Frauendorfer, Day, Iske (BIB5) 1974; 64 Murahashi, Mizoguchi, Hosokawa, Moritani, Kai, Kohara, Yasuoka, Kasai (BIB6) 1974 Nicholas, Bray, Davis, Pettit (BIB3) 1971 Sly (BIB2) 1959; 81 Hübel (BIB1) 1968; 1 Dapporto, Fallani, Midollini, Sacconi (BIB7) 1973; 95 Schmitt, Ziegler (BIB4) 1973; 28 Schmitt (10.1016/S0022-328X(00)86963-6_BIB4) 1973; 28 Nicholas (10.1016/S0022-328X(00)86963-6_BIB3) 1971 Murahashi (10.1016/S0022-328X(00)86963-6_BIB6) 1974 Sly (10.1016/S0022-328X(00)86963-6_BIB2) 1959; 81 Calderon (10.1016/S0022-328X(00)86963-6_BIB5) 1974; 64 Hübel (10.1016/S0022-328X(00)86963-6_BIB1) 1968; 1 Dapporto (10.1016/S0022-328X(00)86963-6_BIB7) 1973; 95 |
| References_xml | – start-page: 563 year: 1974 ident: BIB6 publication-title: J. Chem. Soc. Chem. Comm. – volume: 95 start-page: 2021 year: 1973 ident: BIB7 publication-title: J. Amer. Chem. Soc. – volume: 64 start-page: C16 year: 1974 ident: BIB5 publication-title: J. Organometal. Chem. – volume: 1 start-page: 273 year: 1968 end-page: 342 ident: BIB1 publication-title: Organic Syntheses via Metal Carbonyls – volume: 81 start-page: 18 year: 1959 ident: BIB2 publication-title: J. Amer. Chem. Soc. – start-page: 608 year: 1971 ident: BIB3 publication-title: Chem. Commun. – volume: 28 start-page: 508 year: 1973 ident: BIB4 publication-title: Z. Naturforsch. B – start-page: 563 year: 1974 ident: 10.1016/S0022-328X(00)86963-6_BIB6 publication-title: J. Chem. Soc. Chem. Comm. doi: 10.1039/C39740000563 – start-page: 608 year: 1971 ident: 10.1016/S0022-328X(00)86963-6_BIB3 publication-title: Chem. Commun. doi: 10.1039/C29710000608 – volume: 64 start-page: C16 year: 1974 ident: 10.1016/S0022-328X(00)86963-6_BIB5 publication-title: J. Organometal. Chem. doi: 10.1016/S0022-328X(00)93021-3 – volume: 95 start-page: 2021 year: 1973 ident: 10.1016/S0022-328X(00)86963-6_BIB7 publication-title: J. Amer. Chem. Soc. doi: 10.1021/ja00787a056 – volume: 81 start-page: 18 year: 1959 ident: 10.1016/S0022-328X(00)86963-6_BIB2 publication-title: J. Amer. Chem. Soc. doi: 10.1021/ja01510a005 – volume: 28 start-page: 508 year: 1973 ident: 10.1016/S0022-328X(00)86963-6_BIB4 publication-title: Z. Naturforsch. B doi: 10.1515/znb-1973-7-829 – volume: 1 start-page: 273 year: 1968 ident: 10.1016/S0022-328X(00)86963-6_BIB1 |
| SSID | ssj0001308 |
| Score | 1.2243404 |
| Snippet | The reaction of a commercial sample of 5-BuCC-t-Bu with Fe
2(CO)
9 gave two products. One is green (OC)
3 Fe(μ-t-BuCC-t-Bu)Fe(CO)
3; it contains an FeFe... |
| SourceID | crossref elsevier |
| SourceType | Enrichment Source Index Database Publisher |
| StartPage | C53 |
| Title | The structures of two reaction products of ditertiary-butylacetylene with diiron nonacarbonyl. A new ironiron double bond |
| URI | https://dx.doi.org/10.1016/S0022-328X(00)86963-6 |
| Volume | 94 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVLSH databaseName: Elsevier Journals customDbUrl: mediaType: online eissn: 1872-8561 dateEnd: 99991231 omitProxy: true ssIdentifier: ssj0001308 issn: 0022-328X databaseCode: AKRWK dateStart: 19631001 isFulltext: true providerName: Library Specific Holdings |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3LbtQwFLWG6QI2iKcoBeQFI4FGCWniOPZyOkxVUcGitKK7KHEcqVLbVKNEVRH_wU_wAXwV38Bx7CRTWl7dRKPYHo_uPb4-9twHIS9FmQRaCebpTOceY6XyRJnFnsJxi8VhFqi2SsT7D3zngL07jA9Ho28rXktNnfvq87VxJTfRKt5BryZK9j80238pXuAz9IsnNIznP-vYJoBtljZ5bH1eTUEDbf3vM5vNtW0oTKgxVvPywsub-sJcnuMJQ2dvYosjE-42PQUvV9kyN-7qPmwGOPfUNEwWi4lMJlui7VVUjYm3Qq9LVT5XuG1bK6o60WD2Jom26qrK9f94VLVz29_2ZybLVu98Y7x2ly4KzMT_H-npW7-_Bqqb47oF3pa_57x_ChvCl8S9v5y7RrsSSjOEFYRtnWFsTNYaiwTmOrbZ2jtzbWsiO1hGK7Z3brMOu218brP_Xtkh7GXFx3468HhTDlsKDlPk_ZKVu93n276mqzn-oRO_RdbChPNwTNZmu3ufdvudH3xA9NnpMWCIGHszTPgqCF67ya7nQiv8Zv8eueuUR2cWZffJSJ8-ILfnneYeki9AGx3QRquSAm20Qxvt0GYafos2atBGLdroJbTRGQXaqGn48fV7225xRg3OHpGD7cX-fMdztTs8BVLOsfRxDgEVldkmF1pKlXAWx2EeB2Uc8lwEMlJahEWxqaKsyGWWc54UAnw75BpHkugxGeNX6CeESp6pUJeRTkrOlOQQnowZy3GUKSFxuU5YJ8VUucT2pr7KcTp4MEL4qRF-GgRpK_yUrxO_H3ZmM7v8bYDoVJQ6emppZwps_Xno05sP3SB3hjX0jIyhZv0cPLjOXzj4_QRzD7Ic |
| linkProvider | Library Specific Holdings |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=The+structures+of+two+reaction+products+of+ditertiary-butylacetylene+with+diiron+nonacarbonyl.+A+new+iron%EE%97%B8iron+double+bond&rft.jtitle=Journal+of+organometallic+chemistry&rft.au=Cotton%2C+F.Albert&rft.au=Jamerson%2C+Jackie+D.&rft.au=Stults%2C+B.Ray&rft.date=1975-08-01&rft.pub=Elsevier+B.V&rft.issn=0022-328X&rft.eissn=1872-8561&rft.volume=94&rft.issue=3&rft.spage=C53&rft.epage=C55&rft_id=info:doi/10.1016%2FS0022-328X%2800%2986963-6&rft.externalDocID=S0022328X00869636 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0022-328X&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0022-328X&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0022-328X&client=summon |