Single-Ion Magnet Et 4 N[Co II (hfac) 3 ] with Nonuniaxial Anisotropy: Synthesis, Experimental Characterization, and Theoretical Modeling
In this article we report the synthesis and structure of the new Co(II) complex Et N[Co (hfac) ] (I) (hfac = hexafluoroacetylacetonate) exhibiting single-ion magnet (SIM) behavior. The performed analysis of the magnetic characteristics based on the complementary experimental techniques such as stati...
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| Published in | Inorganic chemistry Vol. 55; no. 19; pp. 9696 - 9706 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
03.10.2016
|
| Online Access | Get full text |
| ISSN | 0020-1669 1520-510X |
| DOI | 10.1021/acs.inorgchem.6b01473 |
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| Abstract | In this article we report the synthesis and structure of the new Co(II) complex Et
N[Co
(hfac)
] (I) (hfac = hexafluoroacetylacetonate) exhibiting single-ion magnet (SIM) behavior. The performed analysis of the magnetic characteristics based on the complementary experimental techniques such as static and dynamic magnetic measurements, electron paramagnetic resonance spectroscopy in conjunction with the theoretical modeling (parametric Hamiltonian and ab initio calculations) demonstrates that the SIM properties of I arise from the nonuniaxial magnetic anisotropy with strong positive axial and significant rhombic contributions. |
|---|---|
| AbstractList | In this article we report the synthesis and structure of the new Co(II) complex Et
N[Co
(hfac)
] (I) (hfac = hexafluoroacetylacetonate) exhibiting single-ion magnet (SIM) behavior. The performed analysis of the magnetic characteristics based on the complementary experimental techniques such as static and dynamic magnetic measurements, electron paramagnetic resonance spectroscopy in conjunction with the theoretical modeling (parametric Hamiltonian and ab initio calculations) demonstrates that the SIM properties of I arise from the nonuniaxial magnetic anisotropy with strong positive axial and significant rhombic contributions. |
| Author | Korchagin, Denis V. Morgunov, Roman B. Palii, Andrew V. Misochko, Eugenii Ya Yureva, Elena A. Talantsev, Artem D. Aldoshin, Sergey M. Tsukerblat, Boris S. Shilov, Gennady V. Akimov, Alexander V. |
| Author_xml | – sequence: 1 givenname: Andrew V. surname: Palii fullname: Palii, Andrew V. organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia, Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau, Moldova – sequence: 2 givenname: Denis V. surname: Korchagin fullname: Korchagin, Denis V. organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia – sequence: 3 givenname: Elena A. surname: Yureva fullname: Yureva, Elena A. organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia – sequence: 4 givenname: Alexander V. surname: Akimov fullname: Akimov, Alexander V. organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia – sequence: 5 givenname: Eugenii Ya surname: Misochko fullname: Misochko, Eugenii Ya organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia – sequence: 6 givenname: Gennady V. surname: Shilov fullname: Shilov, Gennady V. organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia – sequence: 7 givenname: Artem D. surname: Talantsev fullname: Talantsev, Artem D. organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia – sequence: 8 givenname: Roman B. surname: Morgunov fullname: Morgunov, Roman B. organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia – sequence: 9 givenname: Sergey M. surname: Aldoshin fullname: Aldoshin, Sergey M. organization: Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region, Russia – sequence: 10 givenname: Boris S. surname: Tsukerblat fullname: Tsukerblat, Boris S. organization: Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27632142$$D View this record in MEDLINE/PubMed |
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N[Co
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] (I) (hfac = hexafluoroacetylacetonate) exhibiting single-ion... |
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| Title | Single-Ion Magnet Et 4 N[Co II (hfac) 3 ] with Nonuniaxial Anisotropy: Synthesis, Experimental Characterization, and Theoretical Modeling |
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