Supramolecular Differentiation for Construction of Anisotropic Fullerene Nanostructures by Time-Programmed Control of Interfacial Growth

Supramolecular assembly can be used to construct a wide variety of ordered structures by exploiting the cumulative effects of multiple noncovalent interactions. However, the construction of anisotropic nanostructures remains subject to some limitations. Here, we demonstrate the preparation of anisot...

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Published inACS nano Vol. 10; no. 9; pp. 8796 - 8802
Main Authors Bairi, Partha, Minami, Kosuke, Hill, Jonathan P, Nakanishi, Waka, Shrestha, Lok Kumar, Liu, Chao, Harano, Koji, Nakamura, Eiichi, Ariga, Katsuhiko
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 27.09.2016
Subjects
self-assembly
nanostructure
fullerenes
carbon nanostructures
liquid−liquid interface
Online AccessGet full text
ISSN1936-0851
1936-086X
1936-086X
DOI10.1021/acsnano.6b04535

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Abstract Supramolecular assembly can be used to construct a wide variety of ordered structures by exploiting the cumulative effects of multiple noncovalent interactions. However, the construction of anisotropic nanostructures remains subject to some limitations. Here, we demonstrate the preparation of anisotropic fullerene-based nanostructures by supramolecular differentiation, which is the programmed control of multiple assembly strategies. We have carefully combined interfacial assembly and local phase separation phenomena. Two fullerene derivatives, PhH and C12H, were together formed into self-assembled anisotropic nanostructures by using this approach. This technique is applicable for the construction of anisotropic nanostructures without requiring complex molecular design or complicated methodology.
AbstractList Supramolecular assembly can be used to construct a wide variety of ordered structures by exploiting the cumulative effects of multiple noncovalent interactions. However, the construction of anisotropic nanostructures remains subject to some limitations. Here, we demonstrate the preparation of anisotropic fullerene-based nanostructures by supramolecular differentiation, which is the programmed control of multiple assembly strategies. We have carefully combined interfacial assembly and local phase separation phenomena. Two fullerene derivatives, PhH and C12H, were together formed into self-assembled anisotropic nanostructures by using this approach. This technique is applicable for the construction of anisotropic nanostructures without requiring complex molecular design or complicated methodology.
Author Minami, Kosuke
Harano, Koji
Liu, Chao
Bairi, Partha
Ariga, Katsuhiko
Nakanishi, Waka
Hill, Jonathan P
Nakamura, Eiichi
Shrestha, Lok Kumar
AuthorAffiliation Department of Chemistry
World Premier International Center for Materials Nanoarchitectonics (WPI-MANA)
National Institute for Material Science (NIMS)
The University of Tokyo
AuthorAffiliation_xml – name: World Premier International Center for Materials Nanoarchitectonics (WPI-MANA)
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/27541964$$D View this record in MEDLINE/PubMed
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nanostructure
fullerenes
carbon nanostructures
liquid−liquid interface
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Title Supramolecular Differentiation for Construction of Anisotropic Fullerene Nanostructures by Time-Programmed Control of Interfacial Growth
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