Effects of Polymer Coatings on Electrodeposited Lithium Metal
The electrodeposition of lithium metal is a key process in next-generation, high energy density storage devices. However, the high reactivity of the lithium metal causes short cycling lifetimes and dendrite growth that can pose a serious safety issue. Recently, a number of approaches have been pursu...
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| Published in | Journal of the American Chemical Society Vol. 140; no. 37; pp. 11735 - 11744 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
19.09.2018
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0002-7863 1520-5126 1520-5126 |
| DOI | 10.1021/jacs.8b06047 |
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| Abstract | The electrodeposition of lithium metal is a key process in next-generation, high energy density storage devices. However, the high reactivity of the lithium metal causes short cycling lifetimes and dendrite growth that can pose a serious safety issue. Recently, a number of approaches have been pursued to stabilize the lithium metal–electrolyte interface, including soft polymeric coatings that have shown the ability to enable high-rate and high-capacity lithium metal cycling, but a clear understanding of how to design and modify these coatings has not yet been established. In this work, we studied the effects of several polymers with systematically varied chemical and mechanical properties as coatings on the lithium metal anode. By examining the early stages of lithium metal deposition, we determine that the morphology of the lithium particles is strongly influenced by the chemistry of the polymer coating. We have identified polymer dielectric constant and surface energy as two key descriptors of the lithium deposit size. Low surface energy polymers were found to promote larger deposits with smaller surface areas. This may be explained by a reduced interaction between the coating and the lithium surface and thus an increase in the interfacial energy. On the other hand, high dielectric constant polymers were found to increase the exchange current and gave larger lithium deposits due to the decreased overpotentials at a fixed current density. We also observed that the thickness of the polymer coating should be optimized for each individual polymer. Furthermore, polymer reactivity was found to strongly influence the Coulombic efficiency. Overall, this work offers new fundamental insights into lithium electrodeposition processes and provides direction for the design of new polymer coatings to better stabilize the lithium metal anode. |
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| AbstractList | The electrodeposition of lithium metal is a key process in next-generation, high energy density storage devices. However, the high reactivity of the lithium metal causes short cycling lifetimes and dendrite growth that can pose a serious safety issue. Recently, a number of approaches have been pursued to stabilize the lithium metal–electrolyte interface, including soft polymeric coatings that have shown the ability to enable high-rate and high-capacity lithium metal cycling, but a clear understanding of how to design and modify these coatings has not yet been established. In this work, we studied the effects of several polymers with systematically varied chemical and mechanical properties as coatings on the lithium metal anode. By examining the early stages of lithium metal deposition, we determine that the morphology of the lithium particles is strongly influenced by the chemistry of the polymer coating. We have identified polymer dielectric constant and surface energy as two key descriptors of the lithium deposit size. Low surface energy polymers were found to promote larger deposits with smaller surface areas. This may be explained by a reduced interaction between the coating and the lithium surface and thus an increase in the interfacial energy. On the other hand, high dielectric constant polymers were found to increase the exchange current and gave larger lithium deposits due to the decreased overpotentials at a fixed current density. We also observed that the thickness of the polymer coating should be optimized for each individual polymer. Furthermore, polymer reactivity was found to strongly influence the Coulombic efficiency. Overall, this work offers new fundamental insights into lithium electrodeposition processes and provides direction for the design of new polymer coatings to better stabilize the lithium metal anode. The electrodeposition of lithium metal is a key process in next-generation, high energy density storage devices. However, the high reactivity of the lithium metal causes short cycling lifetimes and dendrite growth that can pose a serious safety issue. Recently, a number of approaches have been pursued to stabilize the lithium metal-electrolyte interface, including soft polymeric coatings that have shown the ability to enable high-rate and high-capacity lithium metal cycling, but a clear understanding of how to design and modify these coatings has not yet been established. In this work, we studied the effects of several polymers with systematically varied chemical and mechanical properties as coatings on the lithium metal anode. By examining the early stages of lithium metal deposition, we determine that the morphology of the lithium particles is strongly influenced by the chemistry of the polymer coating. We have identified polymer dielectric constant and surface energy as two key descriptors of the lithium deposit size. Low surface energy polymers were found to promote larger deposits with smaller surface areas. This may be explained by a reduced interaction between the coating and the lithium surface and thus an increase in the interfacial energy. On the other hand, high dielectric constant polymers were found to increase the exchange current and gave larger lithium deposits due to the decreased overpotentials at a fixed current density. We also observed that the thickness of the polymer coating should be optimized for each individual polymer. Furthermore, polymer reactivity was found to strongly influence the Coulombic efficiency. Overall, this work offers new fundamental insights into lithium electrodeposition processes and provides direction for the design of new polymer coatings to better stabilize the lithium metal anode.The electrodeposition of lithium metal is a key process in next-generation, high energy density storage devices. However, the high reactivity of the lithium metal causes short cycling lifetimes and dendrite growth that can pose a serious safety issue. Recently, a number of approaches have been pursued to stabilize the lithium metal-electrolyte interface, including soft polymeric coatings that have shown the ability to enable high-rate and high-capacity lithium metal cycling, but a clear understanding of how to design and modify these coatings has not yet been established. In this work, we studied the effects of several polymers with systematically varied chemical and mechanical properties as coatings on the lithium metal anode. By examining the early stages of lithium metal deposition, we determine that the morphology of the lithium particles is strongly influenced by the chemistry of the polymer coating. We have identified polymer dielectric constant and surface energy as two key descriptors of the lithium deposit size. Low surface energy polymers were found to promote larger deposits with smaller surface areas. This may be explained by a reduced interaction between the coating and the lithium surface and thus an increase in the interfacial energy. On the other hand, high dielectric constant polymers were found to increase the exchange current and gave larger lithium deposits due to the decreased overpotentials at a fixed current density. We also observed that the thickness of the polymer coating should be optimized for each individual polymer. Furthermore, polymer reactivity was found to strongly influence the Coulombic efficiency. Overall, this work offers new fundamental insights into lithium electrodeposition processes and provides direction for the design of new polymer coatings to better stabilize the lithium metal anode. |
| Author | Pei, Allen Wang, Ging-Ji Nathan Lopez, Jeffrey Bao, Zhenan Oh, Jin Young Cui, Yi |
| AuthorAffiliation | Department of Chemistry Department of Chemical Engineering Department of Materials Science and Engineering Stanford Institute for Materials and Energy Sciences SLAC National Accelerator Laboratory |
| AuthorAffiliation_xml | – name: Department of Chemical Engineering – name: Department of Chemistry – name: Stanford Institute for Materials and Energy Sciences – name: SLAC National Accelerator Laboratory – name: Department of Materials Science and Engineering |
| Author_xml | – sequence: 1 givenname: Jeffrey orcidid: 0000-0002-6425-5550 surname: Lopez fullname: Lopez, Jeffrey – sequence: 2 givenname: Allen orcidid: 0000-0001-8930-2125 surname: Pei fullname: Pei, Allen – sequence: 3 givenname: Jin Young orcidid: 0000-0003-2260-9960 surname: Oh fullname: Oh, Jin Young organization: Department of Chemical Engineering – sequence: 4 givenname: Ging-Ji Nathan orcidid: 0000-0002-5432-3046 surname: Wang fullname: Wang, Ging-Ji Nathan – sequence: 5 givenname: Yi orcidid: 0000-0002-6103-6352 surname: Cui fullname: Cui, Yi email: yicui@stanford.edu organization: SLAC National Accelerator Laboratory – sequence: 6 givenname: Zhenan orcidid: 0000-0002-0972-1715 surname: Bao fullname: Bao, Zhenan email: zbao@stanford.edu |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30152228$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1002/aenm.201702097 10.1038/nmat4041 10.1021/jacs.6b13314 10.1002/adma.201504723 10.1038/ncomms7362 10.1007/s12274-017-1596-1 10.1007/978-3-319-26073-0 10.1038/srep14458 10.1038/nmat4777 10.1002/adma.201605531 10.1002/adma.201604460 10.1002/anie.201710806 10.1021/nl503125u 10.1149/1.1850854 10.1073/pnas.1708224114 10.1016/j.joule.2017.08.009 10.1016/j.chempr.2017.12.003 10.1038/nnano.2014.152 10.1126/sciadv.1600320 10.1021/acs.chemrev.7b00115 10.1002/adma.201701169 10.1021/jacs.7b06437 10.1016/j.jpowsour.2013.01.051 10.1038/ncomms8436 10.1109/JPROC.2012.2190170 10.1038/nenergy.2017.12 10.1038/nmat4834 10.1149/1.1391968 10.1038/nmat3191 10.1038/nmat3602 10.1039/C3EE40795K 10.1002/adma.201603755 10.1021/jacs.7b10864 10.1038/nenergy.2016.132 10.1038/ncomms7152 10.1073/pnas.1806878115 10.1038/ncomms10101 10.1021/ja502133j 10.1021/acs.nanolett.6b04755 10.1021/acsenergylett.6b00456 10.1038/nenergy.2016.128 10.1038/nnano.2017.16 10.1002/aenm.201701482 10.1021/j150553a013 |
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