Second-Order Analytical Uncertainty Analysis in Life Cycle Assessment

• Published in: Environmental science & technology Vol. 51; no. 22; pp. 13199 - 13204
• Main Authors: von Pfingsten, Sarah, Broll, David Oliver, von der Assen, Niklas, Bardow, André
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 21.11.2017
• Subjects: analytical methods; Computer simulation; Hydrogen; Hydrogen production; Life cycle analysis; Life cycle assessment; Life cycle engineering; Life cycles; Mathematical analysis; Methane; Monte Carlo Method; Monte Carlo simulation; production technology; recycling; Series expansion; Statistics; Taylor series; Uncertainty; Uncertainty analysis; Variances
• ISSN: 0013-936X; 1520-5851; 1520-5851
• DOI: 10.1021/acs.est.7b01406

Life cycle assessment (LCA) results are inevitably subject to uncertainties. Since the complete elimination of uncertainties is impossible, LCA results should be complemented by an uncertainty analysis. However, the approaches currently used for uncertainty analysis have some shortcomings: statistical uncertainty analysis via Monte Carlo simulations are inherently uncertain due to their statistical nature and can become computationally inefficient for large systems; analytical approaches use a linear approximation to the uncertainty by a first-order Taylor series expansion and thus, they are only precise for small input uncertainties. In this article, we refine the analytical uncertainty analysis by a more precise, second-order Taylor series expansion. The presented approach considers uncertainties from process data, allocation, and characterization factors. We illustrate the refined approach for hydrogen production from methane-cracking. The production system contains a recycling loop leading to nonlinearities. By varying the strength of the loop, we analyze the precision of the first- and second-order analytical uncertainty approaches by comparing analytical variances to variances from statistical Monte Carlo simulations. For the case without loops, the second-order approach is practically exact. In all cases, the second-order Taylor series approach is more precise than the first-order approach, in particular for large uncertainties and for production systems with nonlinearities, for example, from loops. For analytical uncertainty analysis, we recommend using the second-order approach since it is more precise and still computationally cheap.