Strategies toward Controlling the Topology of Nonlinear Poly(thiophenes)
We report the synthesis of all-conjugated branched poly(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first approach a branched monomer is polymerized using three different catalysts which differentiate in the degree of association to the π-system of th...
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Published in | Macromolecules Vol. 49; no. 23; pp. 8951 - 8959 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
13.12.2016
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Subjects | |
Online Access | Get full text |
ISSN | 0024-9297 1520-5835 1520-5835 |
DOI | 10.1021/acs.macromol.6b02223 |
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Abstract | We report the synthesis of all-conjugated branched poly(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first approach a branched monomer is polymerized using three different catalysts which differentiate in the degree of association to the π-system of the polymer backbone. In the second approach a copolymerization is performed with the branched and a linear monomer. In a next step the influence of the different degrees of nonlinearity on the optoelectronic properties is investigated by UV–vis and fluorescence spectroscopy. Finally, the thermal behavior, the morphology, and the electrical properties at the nanoscale of the material in solid state are studied using DSC and AFM techniques. |
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AbstractList | We report the synthesis of all-conjugated branched poly(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first approach a branched monomer is polymerized using three different catalysts which differentiate in the degree of association to the π-system of the polymer backbone. In the second approach a copolymerization is performed with the branched and a linear monomer. In a next step the influence of the different degrees of nonlinearity on the optoelectronic properties is investigated by UV–vis and fluorescence spectroscopy. Finally, the thermal behavior, the morphology, and the electrical properties at the nanoscale of the material in solid state are studied using DSC and AFM techniques. We report the synthesis of all-conjugated branched poly(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first approach a branched monomer is polymerized using three different catalysts which differentiate in the degree of association to the π-system of the polymer backbone. In the second approach a copolymerization is performed with the branched and a linear monomer. In a next step the influence of the different degrees of nonlinearity on the optoelectronic properties is investigated by UV–vis and fluorescence spectroscopy. Finally, the thermal behavior, the morphology, and the electrical properties at the nanoscale of the material in solid state are studied using DSC and AFM techniques. |
Author | Leclère, Philippe Lazzaroni, Roberto Monnaie, Frederic Steverlynck, Joost Warniez, Emeline Koeckelberghs, Guy |
AuthorAffiliation | Laboratory for Polymer Synthesis Service de Chimie des Matériaux Nouveaux |
AuthorAffiliation_xml | – name: Laboratory for Polymer Synthesis – name: Service de Chimie des Matériaux Nouveaux |
Author_xml | – sequence: 1 givenname: Joost surname: Steverlynck fullname: Steverlynck, Joost – sequence: 2 givenname: Frederic surname: Monnaie fullname: Monnaie, Frederic – sequence: 3 givenname: Emeline surname: Warniez fullname: Warniez, Emeline – sequence: 4 givenname: Roberto surname: Lazzaroni fullname: Lazzaroni, Roberto – sequence: 5 givenname: Philippe surname: Leclère fullname: Leclère, Philippe email: philippe.leclere@umons.ac.be – sequence: 6 givenname: Guy orcidid: 0000-0003-1412-8454 surname: Koeckelberghs fullname: Koeckelberghs, Guy email: guy.koeckelberghs@chem.kuleuven.be |
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Snippet | We report the synthesis of all-conjugated branched poly(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first... We report the synthesis of all-conjugated branched poly(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first... |
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SubjectTerms | catalysts copolymerization electrical properties fluorescence emission spectroscopy polymers thermal properties thiophenes topology ultraviolet-visible spectroscopy |
Title | Strategies toward Controlling the Topology of Nonlinear Poly(thiophenes) |
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