Strategies toward Controlling the Topology of Nonlinear Poly(thiophenes)

We report the synthesis of all-conjugated branched poly­(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first approach a branched monomer is polymerized using three different catalysts which differentiate in the degree of association to the π-system of th...

Full description

Saved in:
Bibliographic Details
Published inMacromolecules Vol. 49; no. 23; pp. 8951 - 8959
Main Authors Steverlynck, Joost, Monnaie, Frederic, Warniez, Emeline, Lazzaroni, Roberto, Leclère, Philippe, Koeckelberghs, Guy
Format Journal Article
LanguageEnglish
Published American Chemical Society 13.12.2016
Subjects
Online AccessGet full text
ISSN0024-9297
1520-5835
1520-5835
DOI10.1021/acs.macromol.6b02223

Cover

Abstract We report the synthesis of all-conjugated branched poly­(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first approach a branched monomer is polymerized using three different catalysts which differentiate in the degree of association to the π-system of the polymer backbone. In the second approach a copolymerization is performed with the branched and a linear monomer. In a next step the influence of the different degrees of nonlinearity on the optoelectronic properties is investigated by UV–vis and fluorescence spectroscopy. Finally, the thermal behavior, the morphology, and the electrical properties at the nanoscale of the material in solid state are studied using DSC and AFM techniques.
AbstractList We report the synthesis of all-conjugated branched poly(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first approach a branched monomer is polymerized using three different catalysts which differentiate in the degree of association to the π-system of the polymer backbone. In the second approach a copolymerization is performed with the branched and a linear monomer. In a next step the influence of the different degrees of nonlinearity on the optoelectronic properties is investigated by UV–vis and fluorescence spectroscopy. Finally, the thermal behavior, the morphology, and the electrical properties at the nanoscale of the material in solid state are studied using DSC and AFM techniques.
We report the synthesis of all-conjugated branched poly­(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first approach a branched monomer is polymerized using three different catalysts which differentiate in the degree of association to the π-system of the polymer backbone. In the second approach a copolymerization is performed with the branched and a linear monomer. In a next step the influence of the different degrees of nonlinearity on the optoelectronic properties is investigated by UV–vis and fluorescence spectroscopy. Finally, the thermal behavior, the morphology, and the electrical properties at the nanoscale of the material in solid state are studied using DSC and AFM techniques.
Author Leclère, Philippe
Lazzaroni, Roberto
Monnaie, Frederic
Steverlynck, Joost
Warniez, Emeline
Koeckelberghs, Guy
AuthorAffiliation Laboratory for Polymer Synthesis
Service de Chimie des Matériaux Nouveaux
AuthorAffiliation_xml – name: Laboratory for Polymer Synthesis
– name: Service de Chimie des Matériaux Nouveaux
Author_xml – sequence: 1
  givenname: Joost
  surname: Steverlynck
  fullname: Steverlynck, Joost
– sequence: 2
  givenname: Frederic
  surname: Monnaie
  fullname: Monnaie, Frederic
– sequence: 3
  givenname: Emeline
  surname: Warniez
  fullname: Warniez, Emeline
– sequence: 4
  givenname: Roberto
  surname: Lazzaroni
  fullname: Lazzaroni, Roberto
– sequence: 5
  givenname: Philippe
  surname: Leclère
  fullname: Leclère, Philippe
  email: philippe.leclere@umons.ac.be
– sequence: 6
  givenname: Guy
  orcidid: 0000-0003-1412-8454
  surname: Koeckelberghs
  fullname: Koeckelberghs, Guy
  email: guy.koeckelberghs@chem.kuleuven.be
BookMark eNqFkEFLwzAUx4NMcJt-Aw89zkPnS5quqTcZ6oShgvMc0jbdMtKkJhmyb2_G5sWDnh68__v94f1GaGCskQhdY5hiIPhW1H7aidrZzurprAJCSHaGhjgnkOYsywdoCEBoWpKyuEAj77cAGOc0G6LFe3AiyLWSPgn2S7gmmVsTnNVamXUSNjJZ2d5qu94ntk1erIl7KVzyZvV-EjbK9htppL-5ROet0F5eneYYfTw-rOaLdPn69Dy_X6aCEhbSguaiqRidAYAEkhWsKoUgBS0pbVtgDMqGSklqYJjVIi9JXWGSYRqDvCqbbIwmx97e2c-d9IF3ytdSa2Gk3XlOgNFYM4vfjdHd8TSa8d7JltcqiKAO_wmlOQZ-0MejPv6jj5_0RZj-gnunOuH2_2FwxA7p1u6ciTL-Rr4B56iLAw
CitedBy_id crossref_primary_10_1016_j_polymer_2021_123630
crossref_primary_10_1002_macp_201800024
crossref_primary_10_1002_macp_201700391
crossref_primary_10_1021_acsapm_8b00149
crossref_primary_10_1002_anie_201713026
crossref_primary_10_1002_ange_201713026
crossref_primary_10_1021_acs_macromol_8b00138
Cites_doi 10.1039/c4py00305e
10.1002/pola.27967
10.1021/ma034012r
10.1021/ma2026644
10.1002/chem.201203331
10.1002/marc.201100316
10.1002/marc.201400525
10.1002/marc.201400061
10.1063/1.1592869
10.1002/pola.23399
10.1002/adma.200700135
10.1002/pola.25014
10.1021/ma5009435
10.1021/ma502294n
10.1039/c3py00412k
10.1021/ma0357063
10.1039/b605338f
10.1002/anie.200602653
10.1021/ja0710306
10.1007/s11434-008-0356-8
10.1016/j.orgel.2009.10.019
10.1021/acs.macromol.5b01512
10.1021/ol025943a
10.1039/C5PY00945F
10.1021/ma902396n
10.1021/acs.macromol.5b01830
10.1021/mz3000368
10.1021/ma901410k
10.1016/j.solmat.2008.12.017
10.1021/ma9905324
10.1039/c3py00236e
10.1021/jp1014077
10.1002/marc.200900186
10.1016/S0040-4039(02)01367-9
10.1080/15421406.2012.702445
10.1039/C4PY00899E
10.1002/adfm.200600680
10.1021/acsmacrolett.5b00541
10.1021/ma300313y
10.1021/ma035396o
10.1021/ma2021503
10.1002/pola.27443
10.1002/pola.26169
10.1021/ma901888h
10.1002/jms.1886
10.1002/macp.200900375
10.1021/ma400043s
10.1039/C3PY01442H
10.1021/ja073216a
10.1021/ma201192p
10.1021/ja0556880
10.1002/pola.22424
10.1039/C3PY01037F
ContentType Journal Article
Copyright Copyright © 2016 American Chemical Society
Copyright_xml – notice: Copyright © 2016 American Chemical Society
DBID AAYXX
CITATION
7S9
L.6
DOI 10.1021/acs.macromol.6b02223
DatabaseName CrossRef
AGRICOLA
AGRICOLA - Academic
DatabaseTitle CrossRef
AGRICOLA
AGRICOLA - Academic
DatabaseTitleList AGRICOLA

DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1520-5835
EndPage 8959
ExternalDocumentID 10_1021_acs_macromol_6b02223
f76757648
GroupedDBID .K2
53G
55A
5GY
5VS
7~N
AABXI
ABFLS
ABMVS
ABPPZ
ABPTK
ABUCX
ACGFS
ACJ
ACNCT
ACS
AEESW
AENEX
AFEFF
ALMA_UNASSIGNED_HOLDINGS
AQSVZ
BAANH
CS3
DU5
EBS
ED
ED~
EJD
F5P
GNL
IH9
IHE
JG
JG~
K2
LG6
P2P
ROL
TN5
TWZ
UI2
VF5
VG9
W1F
WH7
X
YZZ
-~X
4.4
AAHBH
AAYXX
ABBLG
ABJNI
ABLBI
ABQRX
ACBEA
ACGFO
ADHLV
AGXLV
AHGAQ
CITATION
CUPRZ
GGK
7S9
L.6
ID FETCH-LOGICAL-a428t-745adb846000e02378b9aa274944ff08809d4ee2c0818ca592cb123148095b9d3
IEDL.DBID ACS
ISSN 0024-9297
1520-5835
IngestDate Thu Jul 10 19:16:50 EDT 2025
Tue Jul 01 03:46:39 EDT 2025
Thu Apr 24 23:03:35 EDT 2025
Thu Aug 27 13:52:07 EDT 2020
IsPeerReviewed true
IsScholarly true
Issue 23
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-a428t-745adb846000e02378b9aa274944ff08809d4ee2c0818ca592cb123148095b9d3
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ORCID 0000-0003-1412-8454
PQID 2084088654
PQPubID 24069
PageCount 9
ParticipantIDs proquest_miscellaneous_2084088654
crossref_citationtrail_10_1021_acs_macromol_6b02223
crossref_primary_10_1021_acs_macromol_6b02223
acs_journals_10_1021_acs_macromol_6b02223
ProviderPackageCode JG~
55A
AABXI
GNL
VF5
7~N
ACJ
VG9
W1F
ACS
AEESW
AFEFF
.K2
ABMVS
ABUCX
IH9
BAANH
AQSVZ
ED~
UI2
CITATION
AAYXX
PublicationCentury 2000
PublicationDate 2016-12-13
PublicationDateYYYYMMDD 2016-12-13
PublicationDate_xml – month: 12
  year: 2016
  text: 2016-12-13
  day: 13
PublicationDecade 2010
PublicationTitle Macromolecules
PublicationTitleAlternate Macromolecules
PublicationYear 2016
Publisher American Chemical Society
Publisher_xml – name: American Chemical Society
References ref9/cit9
ref45/cit45
ref3/cit3
ref27/cit27
ref16/cit16
ref52/cit52
ref23/cit23
ref8/cit8
ref31/cit31
ref2/cit2
ref34/cit34
ref37/cit37
ref20/cit20
ref48/cit48
ref17/cit17
ref10/cit10
ref35/cit35
ref53/cit53
ref19/cit19
ref21/cit21
ref42/cit42
ref46/cit46
ref49/cit49
ref13/cit13
ref24/cit24
ref38/cit38
ref50/cit50
ref6/cit6
ref36/cit36
ref18/cit18
ref11/cit11
ref25/cit25
ref29/cit29
ref32/cit32
ref39/cit39
ref14/cit14
ref5/cit5
ref51/cit51
ref43/cit43
ref28/cit28
ref40/cit40
ref26/cit26
ref12/cit12
ref15/cit15
ref41/cit41
ref22/cit22
ref33/cit33
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref44/cit44
ref7/cit7
References_xml – ident: ref21/cit21
  doi: 10.1039/c4py00305e
– ident: ref2/cit2
  doi: 10.1002/pola.27967
– ident: ref20/cit20
  doi: 10.1021/ma034012r
– ident: ref35/cit35
  doi: 10.1021/ma2026644
– ident: ref9/cit9
  doi: 10.1002/chem.201203331
– ident: ref41/cit41
  doi: 10.1002/marc.201100316
– ident: ref30/cit30
  doi: 10.1002/marc.201400525
– ident: ref6/cit6
  doi: 10.1002/marc.201400061
– ident: ref25/cit25
  doi: 10.1063/1.1592869
– ident: ref31/cit31
  doi: 10.1002/pola.23399
– ident: ref23/cit23
  doi: 10.1002/adma.200700135
– ident: ref40/cit40
  doi: 10.1002/pola.25014
– ident: ref3/cit3
  doi: 10.1021/ma5009435
– ident: ref7/cit7
  doi: 10.1021/ma502294n
– ident: ref32/cit32
  doi: 10.1039/c3py00412k
– ident: ref42/cit42
  doi: 10.1021/ma0357063
– ident: ref11/cit11
  doi: 10.1039/b605338f
– ident: ref13/cit13
  doi: 10.1002/anie.200602653
– ident: ref45/cit45
  doi: 10.1021/ja0710306
– ident: ref19/cit19
  doi: 10.1007/s11434-008-0356-8
– ident: ref26/cit26
  doi: 10.1016/j.orgel.2009.10.019
– ident: ref36/cit36
  doi: 10.1021/acs.macromol.5b01512
– ident: ref10/cit10
  doi: 10.1021/ol025943a
– ident: ref29/cit29
  doi: 10.1039/C5PY00945F
– ident: ref34/cit34
  doi: 10.1021/ma902396n
– ident: ref1/cit1
  doi: 10.1021/acs.macromol.5b01830
– ident: ref8/cit8
  doi: 10.1021/mz3000368
– ident: ref46/cit46
  doi: 10.1021/ma901410k
– ident: ref33/cit33
  doi: 10.1016/j.solmat.2008.12.017
– ident: ref48/cit48
  doi: 10.1021/ma9905324
– ident: ref50/cit50
  doi: 10.1039/c3py00236e
– ident: ref17/cit17
  doi: 10.1021/jp1014077
– ident: ref22/cit22
  doi: 10.1002/marc.200900186
– ident: ref27/cit27
  doi: 10.1016/S0040-4039(02)01367-9
– ident: ref18/cit18
  doi: 10.1080/15421406.2012.702445
– ident: ref28/cit28
  doi: 10.1039/C4PY00899E
– ident: ref12/cit12
  doi: 10.1002/adfm.200600680
– ident: ref5/cit5
  doi: 10.1021/acsmacrolett.5b00541
– ident: ref37/cit37
  doi: 10.1021/ma300313y
– ident: ref43/cit43
  doi: 10.1021/ma035396o
– ident: ref51/cit51
  doi: 10.1021/ma2021503
– ident: ref24/cit24
  doi: 10.1002/pola.27443
– ident: ref16/cit16
  doi: 10.1002/pola.26169
– ident: ref38/cit38
  doi: 10.1021/ma901888h
– ident: ref47/cit47
  doi: 10.1002/jms.1886
– ident: ref49/cit49
  doi: 10.1002/macp.200900375
– ident: ref4/cit4
  doi: 10.1021/ma400043s
– ident: ref52/cit52
  doi: 10.1039/C3PY01442H
– ident: ref15/cit15
  doi: 10.1021/ja073216a
– ident: ref39/cit39
  doi: 10.1021/ma201192p
– ident: ref44/cit44
  doi: 10.1021/ja0556880
– ident: ref14/cit14
  doi: 10.1002/pola.22424
– ident: ref53/cit53
  doi: 10.1039/C3PY01037F
SSID ssj0011543
Score 2.2488453
Snippet We report the synthesis of all-conjugated branched poly­(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first...
We report the synthesis of all-conjugated branched poly(thiophenes) with a control over the degree of nonlinearity via two different routes. In the first...
SourceID proquest
crossref
acs
SourceType Aggregation Database
Enrichment Source
Index Database
Publisher
StartPage 8951
SubjectTerms catalysts
copolymerization
electrical properties
fluorescence emission spectroscopy
polymers
thermal properties
thiophenes
topology
ultraviolet-visible spectroscopy
Title Strategies toward Controlling the Topology of Nonlinear Poly(thiophenes)
URI http://dx.doi.org/10.1021/acs.macromol.6b02223
https://www.proquest.com/docview/2084088654
Volume 49
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3NS8MwFA86D3rxW5xfRPDgDp1rm6TtcRTHEJyCG-xWkjRBcbaydof51_vSj8kUmV7bpoT3kvd-P94XQlfCY5IGQEuksGOLaAF3LoiF1dGEg0txuXJNofD9gPVH5G5Mx19E8XsE37FvuMzab7xITpu0mTAExV1HGw7zbUO2uuHTImoAcKCMKDvEArfv1aVyv_zFOCSZLTukZXtcOJneDnqoS3XK3JLX9iwXbfnxs3PjH_e_i7YrvIm75QHZQ2sq2UebYT3m7QD16_60KsN5kUOLwzJ93RSqY8CHeFgOUpjjVONB2VqDT_FjOplf588vpjEB2MvWIRr1bodh36rGK1gcOEdueYTyWAD-AKuowHV7vgg4B5YaEKI1WJ9OEBOlHGm63kkOGgV9Ahwk8IKKIHaPUCNJE3WMMPFcRj2lBQt8YgtqoEUstc00i6knVRO1QAxRdT2yqIh8O3ZkHtayiSrZNJFb6yOSVZ9yMy5jsmKVtVj1XvbpWPH9Za3qCARuoiQ8Ueksi5wOcF7fZ5Sc_GPXp2gLoFQx0sh2z1Ajn87UOcCVXFwUZ_QTvdXnmA
linkProvider American Chemical Society
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3dT8IwEL8gPuCL30b8rIkP8jBkrN3YoyESVCAmguFtabsuGhEMGw_413vtNgwmhvC6rU131_Z-l7v7HcC18FzJfHRLpLBDi0YCz5wfCqsWUY4mxeHK0YXC3Z7bHtDHIRsWgOW1MLiIGGeKTRD_l13AvtXPPrnJURtVXaH9FGcDNg0ZikZEzZdF8ABRQRpYrlMLrb-XV8z9M4u2SzJetkvL17KxNa0deF2s0qSYfFRniajK7z8Ejmv_xi5sZ-iT3KXbZQ8KarwPpWbe9O0A2jlbrYpJYjJqSTNNZtdl6wTRIumnbRXmZBKRXkq0wafkeTKa3yRv75qmAG_PyiEMWvf9ZtvKmi1YHD2QxPIo46FANIJ3pEJD7jWEzzn6rD6lUYR3Uc0PqVJ1qTnwJEf9onYRHFJ8wYQfOkdQHE_G6hgI9RyXeSoSrt-gtmAaaIQyst3IDZknVRkqKIYgOyxxYOLgdTvQD3PZBJlsyuDkaglkxlqum2eMVoyyFqO-UtaOFd9f5RoPUOA6ZsLHajKLg3oNPeBGw2X0ZI1VX0Kp3e92gs5D7-kUthBkmWZHtnMGxWQ6U-cIZBJxYbbtDwIr8AM
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3dS8MwEA86QX3xW5yfEXxwD51rm_TjUapjfo2BGwxfSpImKM51rN3D_Ou99GM4QYa-tk1I75K733GX3yF0wV1HUB_CEsHNyCCKw5nzI240FGHgUmwmbX1R-KnttHrkvk_731p9wSISmCnJkvj6VI8iVTAMmFf6-QfL6tQGdYfrWMVeRitUs8BpVBQ8zxIIgAzy5LJFDEAAbnlr7pdZtG8SybxvmjfNmb9pbqKX2UqzMpP3-iTldfH5g8TxX7-yhTYKFIqv822zjZbkcAetBWXzt13UKllrZYLTrLIWB3lRu76-jgE14m7eXmGKY4XbOeEGG-NOPJhepq9vmq4ArGhtD_Wat92gZRRNFwwGkUhquISyiAMqAVspwaG7HvcZg9jVJ0QpsEkNPyJSWkJz4QkGegYtA0gk8IJyP7L3UWUYD-UBwsS1HepKxR3fIyanGnBEQpmOciLqCllFNRBDWByaJMzy4ZYZ6oelbMJCNlVkl6oJRcFerptoDBaMMmajRjl7x4Lvz0uthyBwnTthQxlPktBqQCTseQ4lh39Y9Rla7dw0w8e79sMRWgeslfU8Mu1jVEnHE3kCeCblp9nO_QKtnfJ9
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Strategies+toward+Controlling+the+Topology+of+Nonlinear+Poly%28thiophenes%29&rft.jtitle=Macromolecules&rft.au=Steverlynck%2C+Joost&rft.au=Monnaie%2C+Frederic&rft.au=Warniez%2C+Emeline&rft.au=Lazzaroni%2C+Roberto&rft.date=2016-12-13&rft.issn=0024-9297&rft.eissn=1520-5835&rft.volume=49&rft.issue=23&rft.spage=8951&rft.epage=8959&rft_id=info:doi/10.1021%2Facs.macromol.6b02223&rft.externalDBID=n%2Fa&rft.externalDocID=10_1021_acs_macromol_6b02223
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0024-9297&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0024-9297&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0024-9297&client=summon