Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers

The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a var...

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Published inMacromolecules Vol. 49; no. 10; pp. 3706 - 3715
Main Authors Hayes, Colin O, Chen, Peng-hao, Thedford, R. Paxton, Ellison, Christopher J, Dong, Guangbin, Willson, C. Grant
Format Journal Article
LanguageEnglish
Published American Chemical Society 24.05.2016
Subjects
crosslinking
polystyrenes
temperature
Online AccessGet full text
ISSN0024-9297
1520-5835
1520-5835
DOI10.1021/acs.macromol.6b00316

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Abstract The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.
AbstractList The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.
Author Willson, C. Grant
Chen, Peng-hao
Ellison, Christopher J
Dong, Guangbin
Thedford, R. Paxton
Hayes, Colin O
AuthorAffiliation Department of Chemistry
The University of Texas at Austin
McKetta Department of Chemical Engineering
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Snippet The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many...
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SubjectTerms crosslinking
polystyrenes
temperature
Title Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers
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