Alkynyl-Stabilized Superatomic Silver Clusters Showing Circularly Polarized Luminescence

We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag 17 , prepared from chiral alkynyl ligands. R-Ag 17 and S-Ag 17 possess C 3 symmetry and emit near-infrared (NIR) light with a quantum yield (QY) of 8.0% under ambient condition as well as NIR circularly polarized luminescence (...

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Published inJournal of the American Chemical Society Vol. 143; no. 16; pp. 6048 - 6053
Main Authors Zhang, Miao-Miao, Dong, Xi-Yan, Wang, Zhao-Yang, Luo, Xi-Ming, Huang, Jia-Hong, Zang, Shuang-Quan, Mak, Thomas C. W
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 28.04.2021
Subjects
ligands
luminescence
optical isomerism
silver
Online AccessGet full text
ISSN0002-7863
1520-5126
1520-5126
DOI10.1021/jacs.1c02098

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Abstract We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag 17 , prepared from chiral alkynyl ligands. R-Ag 17 and S-Ag 17 possess C 3 symmetry and emit near-infrared (NIR) light with a quantum yield (QY) of 8.0% under ambient condition as well as NIR circularly polarized luminescence (CPL) as a result of the chirality of the excited states. Both experiments and theoretical calculations indicate for the first time that the CPL originates from transitions between superatomic 1P z (along the C 3 axis) and 1S orbitals. This work opens a new avenue for CPL-active metal nanoclusters by utilizing chiral alkynyl ligands and enlightens the chirality transfer from chiral protecting ligands to superatomic states in metal clusters.
AbstractList We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag17, prepared from chiral alkynyl ligands. R-Ag17 and S-Ag17 possess C3 symmetry and emit near-infrared (NIR) light with a quantum yield (QY) of 8.0% under ambient condition as well as NIR circularly polarized luminescence (CPL) as a result of the chirality of the excited states. Both experiments and theoretical calculations indicate for the first time that the CPL originates from transitions between superatomic 1Pz (along the C3 axis) and 1S orbitals. This work opens a new avenue for CPL-active metal nanoclusters by utilizing chiral alkynyl ligands and enlightens the chirality transfer from chiral protecting ligands to superatomic states in metal clusters.We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag17, prepared from chiral alkynyl ligands. R-Ag17 and S-Ag17 possess C3 symmetry and emit near-infrared (NIR) light with a quantum yield (QY) of 8.0% under ambient condition as well as NIR circularly polarized luminescence (CPL) as a result of the chirality of the excited states. Both experiments and theoretical calculations indicate for the first time that the CPL originates from transitions between superatomic 1Pz (along the C3 axis) and 1S orbitals. This work opens a new avenue for CPL-active metal nanoclusters by utilizing chiral alkynyl ligands and enlightens the chirality transfer from chiral protecting ligands to superatomic states in metal clusters.
We report a new enantiomeric pair of superatomic silver clusters, , prepared from chiral alkynyl ligands. and possess symmetry and emit near-infrared (NIR) light with a quantum yield (QY) of 8.0% under ambient condition as well as NIR circularly polarized luminescence (CPL) as a result of the chirality of the excited states. Both experiments and theoretical calculations indicate for the first time that the CPL originates from transitions between superatomic 1P (along the axis) and 1S orbitals. This work opens a new avenue for CPL-active metal nanoclusters by utilizing chiral alkynyl ligands and enlightens the chirality transfer from chiral protecting ligands to superatomic states in metal clusters.
We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag₁₇, prepared from chiral alkynyl ligands. R-Ag₁₇ and S-Ag₁₇ possess C₃ symmetry and emit near-infrared (NIR) light with a quantum yield (QY) of 8.0% under ambient condition as well as NIR circularly polarized luminescence (CPL) as a result of the chirality of the excited states. Both experiments and theoretical calculations indicate for the first time that the CPL originates from transitions between superatomic 1Pz (along the C₃ axis) and 1S orbitals. This work opens a new avenue for CPL-active metal nanoclusters by utilizing chiral alkynyl ligands and enlightens the chirality transfer from chiral protecting ligands to superatomic states in metal clusters.
We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag 17 , prepared from chiral alkynyl ligands. R-Ag 17 and S-Ag 17 possess C 3 symmetry and emit near-infrared (NIR) light with a quantum yield (QY) of 8.0% under ambient condition as well as NIR circularly polarized luminescence (CPL) as a result of the chirality of the excited states. Both experiments and theoretical calculations indicate for the first time that the CPL originates from transitions between superatomic 1P z (along the C 3 axis) and 1S orbitals. This work opens a new avenue for CPL-active metal nanoclusters by utilizing chiral alkynyl ligands and enlightens the chirality transfer from chiral protecting ligands to superatomic states in metal clusters.
Author Zhang, Miao-Miao
Zang, Shuang-Quan
Dong, Xi-Yan
Luo, Xi-Ming
Wang, Zhao-Yang
Huang, Jia-Hong
Mak, Thomas C. W
AuthorAffiliation Department of Chemistry
College of Chemistry and Chemical Engineering
Henan Polytechnic University
The Chinese University of Hong Kong
Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry
AuthorAffiliation_xml – name: College of Chemistry and Chemical Engineering
– name: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry
– name: Department of Chemistry
– name: The Chinese University of Hong Kong
– name: Henan Polytechnic University
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  givenname: Miao-Miao
  surname: Zhang
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  organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry
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  givenname: Xi-Yan
  orcidid: 0000-0002-2429-546X
  surname: Dong
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  organization: Henan Polytechnic University
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  fullname: Wang, Zhao-Yang
  organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry
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  organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry
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  givenname: Jia-Hong
  surname: Huang
  fullname: Huang, Jia-Hong
  organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry
– sequence: 6
  givenname: Shuang-Quan
  orcidid: 0000-0002-6728-0559
  surname: Zang
  fullname: Zang, Shuang-Quan
  email: zangsqzg@zzu.edu.cn
  organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry
– sequence: 7
  givenname: Thomas C. W
  orcidid: 0000-0002-4316-2937
  surname: Mak
  fullname: Mak, Thomas C. W
  organization: The Chinese University of Hong Kong
BackLink https://www.ncbi.nlm.nih.gov/pubmed/33871986$$D View this record in MEDLINE/PubMed
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Snippet We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag 17 , prepared from chiral alkynyl ligands. R-Ag 17 and S-Ag 17 possess C 3 symmetry...
We report a new enantiomeric pair of superatomic silver clusters, , prepared from chiral alkynyl ligands. and possess symmetry and emit near-infrared (NIR)...
We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag17, prepared from chiral alkynyl ligands. R-Ag17 and S-Ag17 possess C3 symmetry and...
We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag₁₇, prepared from chiral alkynyl ligands. R-Ag₁₇ and S-Ag₁₇ possess C₃ symmetry and...
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SubjectTerms ligands
luminescence
optical isomerism
silver
Title Alkynyl-Stabilized Superatomic Silver Clusters Showing Circularly Polarized Luminescence
URI http://dx.doi.org/10.1021/jacs.1c02098
https://www.ncbi.nlm.nih.gov/pubmed/33871986
https://www.proquest.com/docview/2515682830
https://www.proquest.com/docview/2551916404
Volume 143
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