Competition of Hydrogen-Bonding and Electrostatic Interactions within Hybrid Polymer Multilayers
Using a layer-by-layer sequential adsorption technique, we report the construction of hybrid films in which layers of hydrogen-bonded polymers are embedded within electrostatically associated polyelectrolytes. The components of the hybrid film include a neutral hydrogen-bonding polymer, a weak polyc...
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| Published in | Langmuir Vol. 20; no. 24; pp. 10712 - 10717 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
23.11.2004
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0743-7463 1520-5827 |
| DOI | 10.1021/la0484321 |
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| Abstract | Using a layer-by-layer sequential adsorption technique, we report the construction of hybrid films in which layers of hydrogen-bonded polymers are embedded within electrostatically associated polyelectrolytes. The components of the hybrid film include a neutral hydrogen-bonding polymer, a weak polycarboxylic acid, and a strong polycation. Depending on the pH value used for the deposition of the electrostatic film, we found two distinctive regimes of film growth. At pHs lower than a critical value, deposition of electrostatic layers occurred on top of hydrogen-bonded stacks to produce hybrid, three-component films. At pHs higher than a critical value, neutral, hydrogen-bonded chains were displaced by the adsorbing chains of the polycation, producing two-component films. The property of the hydrogen-bonded stacks of hybrid films to be selectively dissolved by exposing them to a high pH makes these films promising candidates for producing free polyelectrolyte films. |
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| AbstractList | Using a layer-by-layer sequential adsorption technique, we report the construction of hybrid films in which layers of hydrogen-bonded polymers are embedded within electrostatically associated polyelectrolytes. The components of the hybrid film include a neutral hydrogen-bonding polymer, a weak polycarboxylic acid, and a strong polycation. Depending on the pH value used for the deposition of the electrostatic film, we found two distinctive regimes of film growth. At pHs lower than a critical value, deposition of electrostatic layers occurred on top of hydrogen-bonded stacks to produce hybrid, three-component films. At pHs higher than a critical value, neutral, hydrogen-bonded chains were displaced by the adsorbing chains of the polycation, producing two-component films. The property of the hydrogen-bonded stacks of hybrid films to be selectively dissolved by exposing them to a high pH makes these films promising candidates for producing free polyelectrolyte films. Using a layer-by-layer sequential adsorption technique, we report the construction of hybrid films in which layers of hydrogen-bonded polymers are embedded within electrostatically associated polyelectrolytes. The components of the hybrid film include a neutral hydrogen-bonding polymer, a weak polycarboxylic acid, and a strong polycation. Depending on the pH value used for the deposition of the electrostatic film, we found two distinctive regimes of film growth. At pHs lower than a critical value, deposition of electrostatic layers occurred on top of hydrogen-bonded stacks to produce hybrid, three-component films. At pHs higher than a critical value, neutral, hydrogen-bonded chains were displaced by the adsorbing chains of the polycation, producing two-component films. The property of the hydrogen-bonded stacks of hybrid films to be selectively dissolved by exposing them to a high pH makes these films promising candidates for producing free polyelectrolyte films.Using a layer-by-layer sequential adsorption technique, we report the construction of hybrid films in which layers of hydrogen-bonded polymers are embedded within electrostatically associated polyelectrolytes. The components of the hybrid film include a neutral hydrogen-bonding polymer, a weak polycarboxylic acid, and a strong polycation. Depending on the pH value used for the deposition of the electrostatic film, we found two distinctive regimes of film growth. At pHs lower than a critical value, deposition of electrostatic layers occurred on top of hydrogen-bonded stacks to produce hybrid, three-component films. At pHs higher than a critical value, neutral, hydrogen-bonded chains were displaced by the adsorbing chains of the polycation, producing two-component films. The property of the hydrogen-bonded stacks of hybrid films to be selectively dissolved by exposing them to a high pH makes these films promising candidates for producing free polyelectrolyte films. |
| Author | Kharlampieva, Eugenia Sukhishvili, Svetlana A |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/15544406$$D View this record in MEDLINE/PubMed |
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| SubjectTerms | Adsorption Electrolytes - chemistry Hydrogen Bonding Hydrogen-Ion Concentration Membranes, Artificial Molecular Structure Polymers - chemistry Static Electricity Time Factors |
| Title | Competition of Hydrogen-Bonding and Electrostatic Interactions within Hybrid Polymer Multilayers |
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