Symmetry Breaking of Atomically Precise Fullerene-like Metal Nanoclusters
Here we report a neutral fullerene-like core–shell homosilver Ag13@Ag20 nanocluster that is fully protected by an achiral bidentate thiolate ligand (9,12-dimercapto-1,2-closo-carborane, C2B10H10S2H2), which crystallizes in centrosymmetric space group R3̅. Continuous Cu doping in the dodecahedral she...
Saved in:
| Published in | Journal of the American Chemical Society Vol. 143; no. 32; pp. 12439 - 12444 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
18.08.2021
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 0002-7863 1520-5126 1520-5126 |
| DOI | 10.1021/jacs.1c05568 |
Cover
| Abstract | Here we report a neutral fullerene-like core–shell homosilver Ag13@Ag20 nanocluster that is fully protected by an achiral bidentate thiolate ligand (9,12-dimercapto-1,2-closo-carborane, C2B10H10S2H2), which crystallizes in centrosymmetric space group R3̅. Continuous Cu doping in the dodecahedral shell first induced symmetry breaking to generate chiral Ag13@Ag20‑n Cu n (6 ≥ n ≥ 2) containing two acetonitrile ligands in space group P212121, and then produced symmetric all-thiolated Ag13@Ag20‑n Cu n (20 ≥ n ≥ 13) in the higher space group Im3̅. The selectively copper-doped Ag13@Ag20‑n Cu n (6 ≥ n ≥ 2) cluster has its structure reorganized to a lower symmetry that shows chiroptical activity. Moreover, structural distortion of Ag13@Ag20‑n Cu n (6 ≥ n ≥ 2) further expanded in chiral R-/S-propylene oxide, which induced a more prominent core-based CD response. This work revealed a novel mechanism of chirality generation at the atomic level through asymmetric shell-doping of metal nanoclusters, which provides new insight into the origin of chirality in inorganic nanostructures. |
|---|---|
| AbstractList | Here we report a neutral fullerene-like core-shell homosilver Ag13@Ag20 nanocluster that is fully protected by an achiral bidentate thiolate ligand (9,12-dimercapto-1,2-closo-carborane, C2B10H10S2H2), which crystallizes in centrosymmetric space group R3̅. Continuous Cu doping in the dodecahedral shell first induced symmetry breaking to generate chiral Ag13@Ag20-nCun (6 ≥ n ≥ 2) containing two acetonitrile ligands in space group P212121, and then produced symmetric all-thiolated Ag13@Ag20-nCun (20 ≥ n ≥ 13) in the higher space group Im3̅. The selectively copper-doped Ag13@Ag20-nCun (6 ≥ n ≥ 2) cluster has its structure reorganized to a lower symmetry that shows chiroptical activity. Moreover, structural distortion of Ag13@Ag20-nCun (6 ≥ n ≥ 2) further expanded in chiral R-/S-propylene oxide, which induced a more prominent core-based CD response. This work revealed a novel mechanism of chirality generation at the atomic level through asymmetric shell-doping of metal nanoclusters, which provides new insight into the origin of chirality in inorganic nanostructures.Here we report a neutral fullerene-like core-shell homosilver Ag13@Ag20 nanocluster that is fully protected by an achiral bidentate thiolate ligand (9,12-dimercapto-1,2-closo-carborane, C2B10H10S2H2), which crystallizes in centrosymmetric space group R3̅. Continuous Cu doping in the dodecahedral shell first induced symmetry breaking to generate chiral Ag13@Ag20-nCun (6 ≥ n ≥ 2) containing two acetonitrile ligands in space group P212121, and then produced symmetric all-thiolated Ag13@Ag20-nCun (20 ≥ n ≥ 13) in the higher space group Im3̅. The selectively copper-doped Ag13@Ag20-nCun (6 ≥ n ≥ 2) cluster has its structure reorganized to a lower symmetry that shows chiroptical activity. Moreover, structural distortion of Ag13@Ag20-nCun (6 ≥ n ≥ 2) further expanded in chiral R-/S-propylene oxide, which induced a more prominent core-based CD response. This work revealed a novel mechanism of chirality generation at the atomic level through asymmetric shell-doping of metal nanoclusters, which provides new insight into the origin of chirality in inorganic nanostructures. Here we report a neutral fullerene-like core–shell homosilver Ag13@Ag20 nanocluster that is fully protected by an achiral bidentate thiolate ligand (9,12-dimercapto-1,2-closo-carborane, C2B10H10S2H2), which crystallizes in centrosymmetric space group R3̅. Continuous Cu doping in the dodecahedral shell first induced symmetry breaking to generate chiral Ag13@Ag20‑n Cu n (6 ≥ n ≥ 2) containing two acetonitrile ligands in space group P212121, and then produced symmetric all-thiolated Ag13@Ag20‑n Cu n (20 ≥ n ≥ 13) in the higher space group Im3̅. The selectively copper-doped Ag13@Ag20‑n Cu n (6 ≥ n ≥ 2) cluster has its structure reorganized to a lower symmetry that shows chiroptical activity. Moreover, structural distortion of Ag13@Ag20‑n Cu n (6 ≥ n ≥ 2) further expanded in chiral R-/S-propylene oxide, which induced a more prominent core-based CD response. This work revealed a novel mechanism of chirality generation at the atomic level through asymmetric shell-doping of metal nanoclusters, which provides new insight into the origin of chirality in inorganic nanostructures. Here we report a neutral fullerene-like core–shell homosilver Ag₁₃@Ag₂₀ nanocluster that is fully protected by an achiral bidentate thiolate ligand (9,12-dimercapto-1,2-closo-carborane, C₂B₁₀H₁₀S₂H₂), which crystallizes in centrosymmetric space group R3̅. Continuous Cu doping in the dodecahedral shell first induced symmetry breaking to generate chiral Ag₁₃@Ag₂₀₋ₙCuₙ (6 ≥ n ≥ 2) containing two acetonitrile ligands in space group P2₁2₁2₁, and then produced symmetric all-thiolated Ag₁₃@Ag₂₀₋ₙCuₙ (20 ≥ n ≥ 13) in the higher space group Im3̅. The selectively copper-doped Ag₁₃@Ag₂₀₋ₙCuₙ (6 ≥ n ≥ 2) cluster has its structure reorganized to a lower symmetry that shows chiroptical activity. Moreover, structural distortion of Ag₁₃@Ag₂₀₋ₙCuₙ (6 ≥ n ≥ 2) further expanded in chiral R-/S-propylene oxide, which induced a more prominent core-based CD response. This work revealed a novel mechanism of chirality generation at the atomic level through asymmetric shell-doping of metal nanoclusters, which provides new insight into the origin of chirality in inorganic nanostructures. |
| Author | Zang, Shuang-Quan Dong, Xi-Yan Liu, Li-Ying Huang, Jia-Hong Wang, Zhao-Yang Mak, Thomas C. W Si, Yubing |
| AuthorAffiliation | Department of Chemistry College of Chemistry and Chemical Engineering Henan Polytechnic University Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry |
| AuthorAffiliation_xml | – name: College of Chemistry and Chemical Engineering – name: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry – name: Department of Chemistry – name: Henan Polytechnic University |
| Author_xml | – sequence: 1 givenname: Jia-Hong surname: Huang fullname: Huang, Jia-Hong organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry – sequence: 2 givenname: Yubing orcidid: 0000-0003-3593-5941 surname: Si fullname: Si, Yubing organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry – sequence: 3 givenname: Xi-Yan orcidid: 0000-0002-2429-546X surname: Dong fullname: Dong, Xi-Yan organization: Henan Polytechnic University – sequence: 4 givenname: Zhao-Yang surname: Wang fullname: Wang, Zhao-Yang organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry – sequence: 5 givenname: Li-Ying surname: Liu fullname: Liu, Li-Ying organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry – sequence: 6 givenname: Shuang-Quan orcidid: 0000-0002-6728-0559 surname: Zang fullname: Zang, Shuang-Quan email: zangsqzg@zzu.edu.cn organization: Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry – sequence: 7 givenname: Thomas C. W orcidid: 0000-0002-4316-2937 surname: Mak fullname: Mak, Thomas C. W organization: Department of Chemistry |
| BookMark | eNqFkE1PwzAMhiM0JMbgxg_okQMdSfqVHsfEYNL4kNi98lIHZUubkaSH_ns6bScE4mTZemy9fi7JqLUtEnLD6JRRzu63IP2USZpluTgjY5ZxGmeM5yMyppTyuBB5ckEuvd8ObcoFG5PlR980GFwfPTiEnW4_I6uiWbCNlmBMH707lNpjtOiMQYctxkbvMHrBACZ6hdZK0_mAzl-RcwXG4_WpTsh68bieP8ert6flfLaKIaU0xCWAyFkBqFSCKYONxBIyNYShUjEuykSomhU1LVNIi7KuBXK1KXihWAZUJRNyezy7d_arQx-qRnuJxkCLtvMVz5O8EGJ49380y8o0KVhCB_TuiEpnvXeoqr3TDbi-YrQ6uK0ObquT2wHnP3CpAwRt2-BAm7-WTnEOw63tXDto-h39BkRJjSU |
| CitedBy_id | crossref_primary_10_1038_s41467_022_28893_6 crossref_primary_10_1016_j_ccr_2023_215424 crossref_primary_10_1002_asia_202400633 crossref_primary_10_1039_D2CS00582D crossref_primary_10_1002_ange_202215741 crossref_primary_10_1002_ange_202407214 crossref_primary_10_1039_D2SC04204E crossref_primary_10_1002_anie_202208273 crossref_primary_10_1016_j_ccr_2022_214729 crossref_primary_10_1002_anie_202317471 crossref_primary_10_1021_acs_jpcc_1c08692 crossref_primary_10_1021_jacs_4c04294 crossref_primary_10_1021_acsnano_2c06492 crossref_primary_10_1002_anie_202401206 crossref_primary_10_1021_jacs_3c08241 crossref_primary_10_1021_acs_jpcc_2c04782 crossref_primary_10_1038_s41467_023_39462_w crossref_primary_10_1039_D2DT03423A crossref_primary_10_1002_advs_202401861 crossref_primary_10_1021_acs_jpclett_2c02420 crossref_primary_10_1039_D3NR03095D crossref_primary_10_1016_j_mattod_2024_04_010 crossref_primary_10_1021_acs_cgd_2c00168 crossref_primary_10_1021_acs_chemmater_4c01046 crossref_primary_10_1002_ange_202401206 crossref_primary_10_1021_acsnano_1c09911 crossref_primary_10_1021_jacsau_2c00517 crossref_primary_10_1002_agt2_508 crossref_primary_10_1002_ange_202217483 crossref_primary_10_1016_j_cclet_2023_109124 crossref_primary_10_3390_nano11102655 crossref_primary_10_1021_acscentsci_2c00754 crossref_primary_10_1039_D1QM01181B crossref_primary_10_1039_D2CC00794K crossref_primary_10_1007_s12274_023_5774_z crossref_primary_10_1002_chem_202404281 crossref_primary_10_1039_D3QI01035J crossref_primary_10_1002_anie_202217483 crossref_primary_10_1016_j_aca_2025_343930 crossref_primary_10_1002_anie_202407214 crossref_primary_10_1093_nsr_nwae192 crossref_primary_10_1080_14686996_2022_2119101 crossref_primary_10_1039_D1NR07690F crossref_primary_10_1021_acsanm_2c02496 crossref_primary_10_1002_smll_202306863 crossref_primary_10_1039_D3QM00747B crossref_primary_10_1039_D2NR05291A crossref_primary_10_1021_acsnano_2c07521 crossref_primary_10_1039_D3CC04432G crossref_primary_10_1016_j_jorganchem_2023_122867 crossref_primary_10_1038_s41467_023_39802_w crossref_primary_10_1002_cjoc_202200622 crossref_primary_10_1002_smtd_202401067 crossref_primary_10_1021_acs_inorgchem_2c02655 crossref_primary_10_1007_s40820_024_01528_9 crossref_primary_10_1002_ange_202208273 crossref_primary_10_1021_acsmaterialslett_1c00848 crossref_primary_10_1093_nsr_nwae174 crossref_primary_10_1002_ange_202317471 crossref_primary_10_1007_s12274_022_5285_3 crossref_primary_10_1021_acsami_2c18553 crossref_primary_10_1002_anie_202215741 |
| Cites_doi | 10.1021/jp9830528 10.1039/b800404h 10.1021/jacs.0c05866 10.1126/science.aak9750 10.1002/ppsc.201900043 10.1021/jacs.1c02098 10.1021/acs.chemrev.6b00769 10.1021/jacs.6b07178 10.1021/ja053504b 10.1039/C2CS35332F 10.1002/anie.202001034 10.1002/anie.201901478 10.1021/accountsmr.0c00057 10.1002/agt2.48 10.1038/s41467-020-18357-0 10.1021/jacs.6b10168 10.1080/23746149.2018.1509727 10.1039/D0CS01393E 10.1021/jacs.9b12493 10.1021/om400097m 10.1021/jacs.7b12136 10.1002/anie.201800327 10.1039/B511563A 10.1002/agt2.36 10.1021/acs.accounts.8b00412 10.1002/chem.202001877 10.1021/acsnano.0c05082 10.1038/ncomms1802 10.1002/adma.201905488 10.1021/jacs.0c11465 10.1073/pnas.0801001105 10.1002/anie.201805695 10.1038/s41586-018-0034-1 10.1021/acs.jpcc.5b12690 10.1002/chir.20473 10.1002/asia.201700023 10.1021/jacs.6b08100 10.1126/science.1082342 10.1021/ar400295d 10.1126/sciadv.1500045 10.1021/acs.accounts.7b00602 10.1021/ja907365f 10.1039/C6NR02251K 10.1039/C9CS00633H 10.1126/science.aat6228 10.1002/anie.201804087 10.1021/acs.chemrev.6b00755 10.1021/jacs.7b11285 10.1021/jacs.9b02162 10.1021/acscentsci.0c01045 10.1126/sciadv.aay0107 10.1021/acscentsci.0c01301 10.1002/anie.201712453 |
| ContentType | Journal Article |
| Copyright | 2021 American Chemical Society |
| Copyright_xml | – notice: 2021 American Chemical Society |
| DBID | AAYXX CITATION 7X8 7S9 L.6 |
| DOI | 10.1021/jacs.1c05568 |
| DatabaseName | CrossRef MEDLINE - Academic AGRICOLA AGRICOLA - Academic |
| DatabaseTitle | CrossRef MEDLINE - Academic AGRICOLA AGRICOLA - Academic |
| DatabaseTitleList | MEDLINE - Academic AGRICOLA |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1520-5126 |
| EndPage | 12444 |
| ExternalDocumentID | 10_1021_jacs_1c05568 c45875612 |
| GroupedDBID | - .K2 02 4.4 53G 55A 5GY 5RE 5VS 7~N 85S AABXI ABFLS ABFRP ABMVS ABPPZ ABPTK ABUCX ACGFS ACJ ACNCT ACS AEESW AENEX AETEA AFEFF AHGAQ ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH BKOMP CS3 DU5 DZ EBS ED ED~ ET F5P GGK GNL IH2 IH9 JG JG~ K2 LG6 P2P ROL RXW TAE TN5 UHB UI2 UKR UPT VF5 VG9 VQA W1F WH7 X XFK YZZ ZHY --- -DZ -ET -~X .DC AAHBH AAYXX ABBLG ABJNI ABLBI ABQRX ACBEA ACGFO ADHLV AGXLV CITATION CUPRZ XSW YQT ZCA ~02 7X8 AAYWT 7S9 L.6 |
| ID | FETCH-LOGICAL-a400t-9aa8617aeff3e41abce9a5f2810cf128938fd17d094a479dd8e2fb727f15a0f3 |
| IEDL.DBID | ACS |
| ISSN | 0002-7863 1520-5126 |
| IngestDate | Fri Sep 05 10:16:53 EDT 2025 Thu Sep 04 16:06:40 EDT 2025 Tue Jul 01 00:44:44 EDT 2025 Thu Apr 24 23:03:13 EDT 2025 Fri Aug 20 09:01:41 EDT 2021 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 32 |
| Language | English |
| License | https://doi.org/10.15223/policy-029 https://doi.org/10.15223/policy-037 https://doi.org/10.15223/policy-045 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a400t-9aa8617aeff3e41abce9a5f2810cf128938fd17d094a479dd8e2fb727f15a0f3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ORCID | 0000-0002-4316-2937 0000-0002-2429-546X 0000-0002-6728-0559 0000-0003-3593-5941 |
| PQID | 2559437130 |
| PQPubID | 23479 |
| PageCount | 6 |
| ParticipantIDs | proquest_miscellaneous_2636788002 proquest_miscellaneous_2559437130 crossref_primary_10_1021_jacs_1c05568 crossref_citationtrail_10_1021_jacs_1c05568 acs_journals_10_1021_jacs_1c05568 |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N ACJ VG9 GGK W1F ABFRP ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2021-08-18 |
| PublicationDateYYYYMMDD | 2021-08-18 |
| PublicationDate_xml | – month: 08 year: 2021 text: 2021-08-18 day: 18 |
| PublicationDecade | 2020 |
| PublicationTitle | Journal of the American Chemical Society |
| PublicationTitleAlternate | J. Am. Chem. Soc |
| PublicationYear | 2021 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | ref9/cit9 ref45/cit45 ref3/cit3 ref27/cit27 ref16/cit16 ref52/cit52 ref23/cit23 ref8/cit8 ref31/cit31 ref2/cit2 ref34/cit34 ref37/cit37 ref20/cit20 ref48/cit48 ref17/cit17 ref10/cit10 ref35/cit35 ref53/cit53 ref19/cit19 ref21/cit21 ref42/cit42 ref46/cit46 ref49/cit49 ref13/cit13 ref24/cit24 ref38/cit38 ref50/cit50 ref6/cit6 ref36/cit36 ref18/cit18 ref11/cit11 ref25/cit25 ref29/cit29 ref32/cit32 ref39/cit39 ref14/cit14 ref5/cit5 ref51/cit51 ref43/cit43 ref28/cit28 ref40/cit40 ref26/cit26 ref12/cit12 ref15/cit15 ref41/cit41 ref22/cit22 ref33/cit33 ref4/cit4 ref30/cit30 ref47/cit47 ref1/cit1 ref44/cit44 ref7/cit7 |
| References_xml | – ident: ref16/cit16 doi: 10.1021/jp9830528 – ident: ref1/cit1 doi: 10.1039/b800404h – ident: ref22/cit22 doi: 10.1021/jacs.0c05866 – ident: ref32/cit32 doi: 10.1126/science.aak9750 – ident: ref5/cit5 doi: 10.1002/ppsc.201900043 – ident: ref34/cit34 doi: 10.1021/jacs.1c02098 – ident: ref15/cit15 doi: 10.1021/acs.chemrev.6b00769 – ident: ref28/cit28 doi: 10.1021/jacs.6b07178 – ident: ref50/cit50 doi: 10.1021/ja053504b – ident: ref10/cit10 doi: 10.1039/C2CS35332F – ident: ref48/cit48 doi: 10.1002/anie.202001034 – ident: ref45/cit45 doi: 10.1002/anie.201901478 – ident: ref6/cit6 doi: 10.1021/accountsmr.0c00057 – ident: ref9/cit9 doi: 10.1002/agt2.48 – ident: ref39/cit39 doi: 10.1038/s41467-020-18357-0 – ident: ref41/cit41 doi: 10.1021/jacs.6b10168 – ident: ref2/cit2 doi: 10.1080/23746149.2018.1509727 – ident: ref21/cit21 doi: 10.1039/D0CS01393E – ident: ref8/cit8 doi: 10.1021/jacs.9b12493 – ident: ref43/cit43 doi: 10.1021/om400097m – ident: ref35/cit35 doi: 10.1021/jacs.7b12136 – ident: ref40/cit40 doi: 10.1002/anie.201800327 – ident: ref52/cit52 doi: 10.1039/B511563A – ident: ref49/cit49 doi: 10.1002/agt2.36 – ident: ref24/cit24 doi: 10.1021/acs.accounts.8b00412 – ident: ref25/cit25 doi: 10.1002/chem.202001877 – ident: ref47/cit47 doi: 10.1021/acsnano.0c05082 – ident: ref37/cit37 doi: 10.1038/ncomms1802 – ident: ref3/cit3 doi: 10.1002/adma.201905488 – ident: ref23/cit23 doi: 10.1021/jacs.0c11465 – ident: ref44/cit44 doi: 10.1073/pnas.0801001105 – ident: ref26/cit26 doi: 10.1002/anie.201805695 – ident: ref13/cit13 doi: 10.1038/s41586-018-0034-1 – ident: ref53/cit53 doi: 10.1021/acs.jpcc.5b12690 – ident: ref17/cit17 doi: 10.1002/chir.20473 – ident: ref14/cit14 doi: 10.1002/asia.201700023 – ident: ref51/cit51 doi: 10.1021/jacs.6b08100 – ident: ref46/cit46 doi: 10.1126/science.1082342 – ident: ref18/cit18 doi: 10.1021/ar400295d – ident: ref31/cit31 doi: 10.1126/sciadv.1500045 – ident: ref7/cit7 doi: 10.1021/acs.accounts.7b00602 – ident: ref36/cit36 doi: 10.1021/ja907365f – ident: ref38/cit38 doi: 10.1039/C6NR02251K – ident: ref19/cit19 doi: 10.1039/C9CS00633H – ident: ref11/cit11 doi: 10.1126/science.aat6228 – ident: ref27/cit27 doi: 10.1002/anie.201804087 – ident: ref4/cit4 doi: 10.1021/acs.chemrev.6b00755 – ident: ref42/cit42 doi: 10.1021/jacs.7b11285 – ident: ref20/cit20 doi: 10.1021/jacs.9b02162 – ident: ref29/cit29 doi: 10.1021/acscentsci.0c01045 – ident: ref33/cit33 doi: 10.1126/sciadv.aay0107 – ident: ref30/cit30 doi: 10.1021/acscentsci.0c01301 – ident: ref12/cit12 doi: 10.1002/anie.201712453 |
| SSID | ssj0004281 |
| Score | 2.5855637 |
| Snippet | Here we report a neutral fullerene-like core–shell homosilver Ag13@Ag20 nanocluster that is fully protected by an achiral bidentate thiolate ligand... Here we report a neutral fullerene-like core-shell homosilver Ag13@Ag20 nanocluster that is fully protected by an achiral bidentate thiolate ligand... Here we report a neutral fullerene-like core–shell homosilver Ag₁₃@Ag₂₀ nanocluster that is fully protected by an achiral bidentate thiolate ligand... |
| SourceID | proquest crossref acs |
| SourceType | Aggregation Database Enrichment Source Index Database Publisher |
| StartPage | 12439 |
| SubjectTerms | acetonitrile ligands optical isomerism |
| Title | Symmetry Breaking of Atomically Precise Fullerene-like Metal Nanoclusters |
| URI | http://dx.doi.org/10.1021/jacs.1c05568 https://www.proquest.com/docview/2559437130 https://www.proquest.com/docview/2636788002 |
| Volume | 143 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1LS8NAEF60HvTiW6wvtqAnSck7m2Mt1ipUhFboLWw2uyBNEzHJof56Z9LE0krVWwgTyE5md77JzHxDyDX2M9pSWBoXTGqwE6Xmu2akKQ-pIKXNDQObkwfPbv_Vfho740WB7GoG30R-IIHlQUj6wjbJlukyF6230x0u-h9NZtQw12OuVRW4rz6NDkhkyw5o-fwtnUpvjzzUrTnzWpJJu8jDtvj8ydT4x_vuk90KV9LO3BAOyIZMDsl2tx7ndkQeh7PpVMIlvQOciD_IaapoJ09LvoB4Rl-Q5yKTFIPScmSKFr9NJB1IgOcUDuFUxAWyKmTHZNS7H3X7WjVHQeOwQ3PN55wBUOFSKUvaBg-F9LmjQGm6UOCffIupyPAiiPS47flRxKSpQgA2ynC4rqwT0kjSRJ4SGrHI8fQQCX9cm3sR981QeSEOiRG2rowmacHqg2obZEGZ4TYhwsC7lU6a5LbWfyAqHnIchxGvkb75ln6f82-skWvVnzIAxWLWgycyLbIAYybbglhc_0XGtcBpI3Y--8cKzsmOiZUtSIzLLkgj_yjkJUCTPLwq7fIL2Rfd1g |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1La8JAEF5ae7CXvkvtc4X2VCJ5Z3O0UtFWpaAFb2Gz2YXiI6VJDvbXdyZGRcHiLYRJ2J19zDe7M98Q8oj5jLYUlsYFkxqsRKn5rhlpykMqSGlzw8Dk5G7PbX3ab0NnWCSrYy4MNCKBPyX5Jf6KXQBpggRGCSH3C9snB4BDDIzgqjf6qzRIkxkLtOsx1yri3De_RjskknU7tL4N57aleUx6y1blISWjWpaGNfG7Qdi4c7NPyFGBMml9Pi1OyZ6cnpFyY1Hc7Zy0-7PJRMIjfQHUiMflNFa0nsY5e8B4Rj-Q9SKRFF3UvICKNv4aSdqVANYpbMmxGGfIsZBckEHzddBoaUVVBY3Dek01n3MGsIVLpSxpGzwU0ueOAt3pQoG18i2mIsOLwO_jtudHEZOmCgHmKMPhurIuSWkaT-UVoRGLHE8Pkf7HtbkXcd8MlRdiyRhh68qokCr0PigWRRLk990m-Bv4ttBJhTwvhiEQBSs5FscYb5F-Wkp_z9k4tshVFyMagGLxDoRPZZwlAXpQtgWeuf6PjGuBCUckfb1DDx5IuTXodoJOu_d-Qw5NjHlBylx2S0rpTybvALSk4X0-Vf8AFe7mNg |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1ZS8NAEB6qgvriLd6uoE-SkqvJ5rFWi1dL8YC-hc0eIK2NmPRBf70zMalYUPQthEnYa3a-2Z35BuCY8hl9LT1LSK4t1ERtRYGrLBMSFaT2heNQcnKnG1w--tf9Rr8GTpULg43I8E9ZcYlPWv2iTMkwQFRBkiKFiP-Fz8AcYRGK4mq27r9SIV3uVIg35IFXxrpPf022SGbfbdH3rbiwL-1luJu0rAgrGdTHeVKX71Okjf9q-goslWiTNT-XxyrU9GgNFlpVkbd1uLp_e37W-MjOED3SsTlLDWvmacEiMHxjPWK_yDQjV7UopGINnwaadTSCdoZbcyqHY-JayDbgoX3x0Lq0yuoKlkC9za1ICI7wRWhjPO07IpE6Eg2D42dLg1Yr8rhRTqjQ_xN-GCnFtWsShDvGaQjbeJswO0pHeguY4qoR2gnRAAW-CJWI3MSECZWOkb5tnG04wt7HpXJkcXHv7aLfQW_LMdmG02oqYlmyk1ORjOEP0icT6ZdPVo4f5I6qWY1xYOkuRIx0Os5i8qR8Dz10-xeZwENTToh65w89OIT53nk7vr3q3uzCokuhL8Scy_dgNn8d633ELnlyUKzWD6Sg6Lk |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Symmetry+Breaking+of+Atomically+Precise+Fullerene-like+Metal+Nanoclusters&rft.jtitle=Journal+of+the+American+Chemical+Society&rft.au=Huang%2C+Jia-Hong&rft.au=Si%2C+Yubing&rft.au=Dong%2C+Xi-Yan&rft.au=Wang%2C+Zhao-Yang&rft.date=2021-08-18&rft.pub=American+Chemical+Society&rft.issn=0002-7863&rft.eissn=1520-5126&rft.volume=143&rft.issue=32&rft.spage=12439&rft.epage=12444&rft_id=info:doi/10.1021%2Fjacs.1c05568&rft.externalDocID=c45875612 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0002-7863&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0002-7863&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0002-7863&client=summon |