Revisiting Fluorenone Photophysics via Dipolar Fluorenone Derivatives
The nonradiative decay of four dipolar fluorenone derivatives (FODs) was systematically investigated using steady state and time-resolved UV–vis absorption and fluorescence measurements combined with cyclic voltammetry. Analysis of the frontier orbital localization of the global minimum geometry and...
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| Published in | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 115; no. 24; pp. 6366 - 6375 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
23.06.2011
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1089-5639 1520-5215 1520-5215 |
| DOI | 10.1021/jp200507j |
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| Abstract | The nonradiative decay of four dipolar fluorenone derivatives (FODs) was systematically investigated using steady state and time-resolved UV–vis absorption and fluorescence measurements combined with cyclic voltammetry. Analysis of the frontier orbital localization of the global minimum geometry and the vertical transitions was carried out from DFT calculations. The first singlet excited state was found to be π–π* in all derivatives regardless of the polarity of the solvent. Charge separation/recombination dominates the singlet excited state deactivation for carbazole-containing FODs. Intersystem crossing (ISC) operates exclusively in the 3,6-disubstituted variants as evidenced by phosphorescence experiments. In the case of CPAFO36, ISC competes disadvantageously with CT deactivation. |
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| AbstractList | The nonradiative decay of four dipolar fluorenone derivatives (FODs) was systematically investigated using steady state and time-resolved UV-vis absorption and fluorescence measurements combined with cyclic voltammetry. Analysis of the frontier orbital localization of the global minimum geometry and the vertical transitions was carried out from DFT calculations. The first singlet excited state was found to be π-π* in all derivatives regardless of the polarity of the solvent. Charge separation/recombination dominates the singlet excited state deactivation for carbazole-containing FODs. Intersystem crossing (ISC) operates exclusively in the 3,6-disubstituted variants as evidenced by phosphorescence experiments. In the case of CPAFO36, ISC competes disadvantageously with CT deactivation.The nonradiative decay of four dipolar fluorenone derivatives (FODs) was systematically investigated using steady state and time-resolved UV-vis absorption and fluorescence measurements combined with cyclic voltammetry. Analysis of the frontier orbital localization of the global minimum geometry and the vertical transitions was carried out from DFT calculations. The first singlet excited state was found to be π-π* in all derivatives regardless of the polarity of the solvent. Charge separation/recombination dominates the singlet excited state deactivation for carbazole-containing FODs. Intersystem crossing (ISC) operates exclusively in the 3,6-disubstituted variants as evidenced by phosphorescence experiments. In the case of CPAFO36, ISC competes disadvantageously with CT deactivation. The nonradiative decay of four dipolar fluorenone derivatives (FODs) was systematically investigated using steady state and time-resolved UV-vis absorption and fluorescence measurements combined with cyclic voltammetry. Analysis of the frontier orbital localization of the global minimum geometry and the vertical transitions was carried out from DFT calculations. The first singlet excited state was found to be π-π* in all derivatives regardless of the polarity of the solvent. Charge separation/recombination dominates the singlet excited state deactivation for carbazole-containing FODs. Intersystem crossing (ISC) operates exclusively in the 3,6-disubstituted variants as evidenced by phosphorescence experiments. In the case of CPAFO36, ISC competes disadvantageously with CT deactivation. |
| Author | Estrada, Leandro A Neckers, Douglas C Yarnell, James E |
| AuthorAffiliation | Bowling Green State University |
| AuthorAffiliation_xml | – name: Bowling Green State University |
| Author_xml | – sequence: 1 givenname: Leandro A surname: Estrada fullname: Estrada, Leandro A – sequence: 2 givenname: James E surname: Yarnell fullname: Yarnell, James E – sequence: 3 givenname: Douglas C surname: Neckers fullname: Neckers, Douglas C email: neckers@photo.bgsu.edu |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/21591713$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1021/cr940745l 10.1039/a708655e 10.1021/jp010546n 10.1021/ja063449m 10.1039/b009860o 10.1021/jp053136y 10.1070/RC1981v050n07ABEH002656 10.1063/1.1677527 10.1021/jp030953u 10.1021/j150665a053 10.1021/jp805950v 10.1021/jp9911651 10.1021/j100137a012 10.1021/ja9600789 10.1103/PhysRevB.37.785 10.1039/b516078b 10.1021/jp990932t 10.1021/jp990208a 10.1021/jp907391y 10.1016/0009-2614(89)87234-3 10.1016/0301-0104(82)85072-6 10.1021/ma00219a023 10.1021/jp003599y 10.1039/df9500900014 10.1039/an9830801067 10.1063/1.1727883 10.1021/jp111431r 10.1021/ja00752a009 10.1021/ja809555c 10.1016/0009-2614(76)80593-3 10.1021/ja01075a005 10.1063/1.475855 10.1063/1.1700519 10.1021/ja01037a015 10.1021/jp980158u 10.1021/jp050848f 10.1021/ma0601262 10.1021/j100324a033 10.1021/jp806879c 10.1246/bcsj.37.1540 10.1021/jp0726945 10.1063/1.477483 10.1524/zpch.1982.133.1.093 10.1002/cphc.200900309 10.1016/0301-0104(81)85090-2 10.1021/ja029489h 10.1021/jo901869g 10.1021/j100600a020 10.1021/j100608a006 10.1016/S0040-4039(01)88102-8 10.1002/ijch.197000029 10.1016/S0040-4039(01)97699-3 10.1063/1.464913 10.1016/S0040-4039(01)88101-6 10.1016/0009-2614(96)00440-X 10.1021/ma990157f 10.1021/j100510a011 10.1002/hlca.19780610122 10.1021/j100216a020 |
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| References | Thompson A. L. (ref19/cit19b) 2004; 108 Varne M. (ref17/cit17) 2009; 10 Davis G. A. (ref43/cit43a) 1969; 91 Singer L. A. (ref4/cit4a) 1969 Weller A. (ref33/cit33c) 1982; 133 Estrada L. A. (ref39/cit39) 2011; 115 Stratmann R. E. (ref27/cit27a) 1998; 109 Miehlich B. (ref25/cit25b) 1989; 157 Bauernschmitt R. (ref27/cit27b) 1996; 256 Turro N. J. (ref18/cit18) 2009 Miertus S. (ref29/cit29b) 1981; 55 Tsujii Y. (ref46/cit46) 1990; 23 Biczók L. (ref16/cit16) 2001; 3 Chen K. S. (ref43/cit43b) 1971; 93 Samant V. (ref11/cit11) 2005; 109 Kasha M. (ref38/cit38b) 1950; 9 Uckert F. (ref1/cit1c) 1999; 32 Williams A. (ref21/cit21) 1983; 108 Murov S. L. (ref35/cit35) 1993 Estrada L. A. (ref20/cit20) 2009; 74 Biczók L. (ref45/cit45) 1993; 97 Behrendt A. (ref32/cit32) 1998 Kapturkiewicz A. (ref47/cit47) 1999; 103 McConnell H. (ref38/cit38a) 1952; 20 Lee C. (ref25/cit25a) 1988; 37 Becke A., D. (ref24/cit24) 1993; 98 Adhikari R. M. (ref41/cit41) 2009; 113 Zhou X.-H. (ref1/cit1d) 2006; 39 Gaab K. M. (ref19/cit19a) 2003; 125 Kavarnos G. J. (ref33/cit33e) 1993 Casida M. E. (ref27/cit27c) 1998; 108 Coe B. J. (ref28/cit28) 2006; 128 Pesteil P. (ref3/cit3b) 1954; 255 Hersktroeter W. G. (ref3/cit3c) 1964; 86 Biczók L. (ref14/cit14) 1999; 103 Okhrimenko A. N. (ref22/cit22c) 2005; 109 Shida T. (ref43/cit43c) 1974; 78 Dufresne S. (ref44/cit44) 2009; 113 Biczók L. (ref10/cit10) 1988; 92 Miertus S. (ref29/cit29a) 1982; 65 Yatsuhashi T. (ref13/cit13) 1998; 102 Nikolaitchik A. V. (ref22/cit22a) 1999; 103 Kuboyama A. (ref2/cit2) 1964; 37 Oldridge L. (ref1/cit1b) 2006; 8 Weller A. Z. (ref33/cit33b) 1982; 133 Hoshino M. (ref43/cit43d) 1974; 78 Hehre W., J. (ref26/cit26) 1972; 56 Dorr F. (ref3/cit3a) 1957; 61 Yoshihara K. (ref6/cit6) 1966; 45 Pelliccioli A. P. (ref22/cit22b) 2001; 105 Usta H. (ref1/cit1a) 2009; 131 Biczók L. (ref12/cit12) 1993; 97 Caldwell R. A. (ref4/cit4b) 1969 Guttenplan J. B. (ref5/cit5a) 1969 Tsuchida A. (ref31/cit31) 1984; 88 Andrews L. J. (ref9/cit9) 1978; 82 Rehm D. (ref33/cit33a) 1970; 8 Huggenberger C. (ref8/cit8) 1978; 61 Frisch M. J. (ref23/cit23) 2004 Greenfield S. R. (ref34/cit34) 1996; 118 Grisorio R. (ref1/cit1e) 2008; 112 Chibisov A. (ref33/cit33d) 1981; 50 Estrada L. A. (ref42/cit42) 2007; 111 Birckner E. (ref37/cit37) 2001; 105 Kobayashi T. (ref7/cit7) 1976; 43 Grabowski Z. R. (ref40/cit40) 2003; 103 Caldwell R. A. (ref5/cit5b) 1971; 93 Fessenden R. W. (ref30/cit30) 1982; 86 |
| References_xml | – volume: 103 start-page: 3899 year: 2003 ident: ref40/cit40 publication-title: Chem. Rev. doi: 10.1021/cr940745l – start-page: 2039 year: 1998 ident: ref32/cit32 publication-title: J. Chem. Soc., Perkin Trans. 2 doi: 10.1039/a708655e – volume: 105 start-page: 10307 year: 2001 ident: ref37/cit37 publication-title: J. Phys. Chem. A doi: 10.1021/jp010546n – volume: 255 start-page: 255 year: 1954 ident: ref3/cit3b publication-title: C. R. Hebd. Seances Acad. Sci. – volume: 128 start-page: 12192 year: 2006 ident: ref28/cit28 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja063449m – volume: 3 start-page: 980 year: 2001 ident: ref16/cit16 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b009860o – volume: 109 start-page: 7653 year: 2005 ident: ref22/cit22c publication-title: J. Phys. Chem. A doi: 10.1021/jp053136y – volume: 50 start-page: 1169 year: 1981 ident: ref33/cit33d publication-title: Russ. Chem. Rev. doi: 10.1070/RC1981v050n07ABEH002656 – volume: 56 start-page: 2257 year: 1972 ident: ref26/cit26 publication-title: J. Chem. Phys. doi: 10.1063/1.1677527 – volume: 108 start-page: 671 year: 2004 ident: ref19/cit19b publication-title: J. Phys. Chem. A doi: 10.1021/jp030953u – volume: 88 start-page: 5064 year: 1984 ident: ref31/cit31 publication-title: J. Phys. Chem. doi: 10.1021/j150665a053 – volume: 113 start-page: 417 year: 2009 ident: ref41/cit41 publication-title: J. Phys. Chem. A doi: 10.1021/jp805950v – volume-title: Gaussian 03, Revision C.02 year: 2004 ident: ref23/cit23 – volume: 103 start-page: 7587 year: 1999 ident: ref22/cit22a publication-title: J. Phys. Chem. A doi: 10.1021/jp9911651 – volume: 97 start-page: 8895 year: 1993 ident: ref45/cit45 publication-title: J. Phys. Chem. doi: 10.1021/j100137a012 – volume: 93 start-page: 533 year: 1971 ident: ref5/cit5b publication-title: J. Am. Chem. Soc. – volume: 97 start-page: 8895 year: 1993 ident: ref12/cit12 publication-title: J. Phys. Chem. doi: 10.1021/j100137a012 – volume: 118 start-page: 6767 year: 1996 ident: ref34/cit34 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja9600789 – volume: 37 start-page: 785 year: 1988 ident: ref25/cit25a publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.37.785 – volume: 8 start-page: 885 year: 2006 ident: ref1/cit1b publication-title: Chem. Commun. doi: 10.1039/b516078b – volume: 103 start-page: 8145 year: 1999 ident: ref47/cit47 publication-title: J. Phys. Chem. A doi: 10.1021/jp990932t – volume: 103 start-page: 3837 year: 1999 ident: ref14/cit14 publication-title: J. Phys. Chem. A doi: 10.1021/jp990208a – volume: 113 start-page: 15541 year: 2009 ident: ref44/cit44 publication-title: J. Phys. Chem. B doi: 10.1021/jp907391y – volume: 61 start-page: 950 year: 1957 ident: ref3/cit3a publication-title: Z. Elektrochem. – volume: 157 start-page: 200 year: 1989 ident: ref25/cit25b publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(89)87234-3 – volume: 65 start-page: 239 year: 1982 ident: ref29/cit29a publication-title: Chem. Phys. doi: 10.1016/0301-0104(82)85072-6 – volume: 23 start-page: 4019 year: 1990 ident: ref46/cit46 publication-title: Macromolecules doi: 10.1021/ma00219a023 – volume: 105 start-page: 1757 year: 2001 ident: ref22/cit22b publication-title: J. Phys. Chem. A doi: 10.1021/jp003599y – volume: 9 start-page: 14 year: 1950 ident: ref38/cit38b publication-title: Discuss. Faraday Soc. doi: 10.1039/df9500900014 – volume: 108 start-page: 1067 year: 1983 ident: ref21/cit21 publication-title: Analyst doi: 10.1039/an9830801067 – volume: 45 start-page: 1991 year: 1966 ident: ref6/cit6 publication-title: J. Chem. Phys. doi: 10.1063/1.1727883 – volume: 115 start-page: 2184 year: 2011 ident: ref39/cit39 publication-title: J. Phys. Chem. A doi: 10.1021/jp111431r – volume: 93 start-page: 6004 year: 1971 ident: ref43/cit43b publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00752a009 – volume: 131 start-page: 5586 year: 2009 ident: ref1/cit1a publication-title: J. Am. Chem. Soc. doi: 10.1021/ja809555c – volume: 43 start-page: 429 year: 1976 ident: ref7/cit7 publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(76)80593-3 – volume: 86 start-page: 4537 year: 1964 ident: ref3/cit3c publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01075a005 – volume: 108 start-page: 4439 year: 1998 ident: ref27/cit27c publication-title: J. Chem. Phys. doi: 10.1063/1.475855 – volume: 20 start-page: 700 year: 1952 ident: ref38/cit38a publication-title: J. Chem. Phys. doi: 10.1063/1.1700519 – volume: 91 start-page: 2264 year: 1969 ident: ref43/cit43a publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01037a015 – volume: 102 start-page: 3018 year: 1998 ident: ref13/cit13 publication-title: J. Phys. Chem. A doi: 10.1021/jp980158u – volume: 109 start-page: 8693 year: 2005 ident: ref11/cit11 publication-title: J. Phys. Chem. A doi: 10.1021/jp050848f – volume: 39 start-page: 3830 year: 2006 ident: ref1/cit1d publication-title: Macromolecules doi: 10.1021/ma0601262 – volume: 133 start-page: 93 year: 1982 ident: ref33/cit33b publication-title: J. Phys. Chem. – volume: 92 start-page: 3842 year: 1988 ident: ref10/cit10 publication-title: J. Phys. Chem. doi: 10.1021/j100324a033 – volume-title: Fundamentals of Photoinduced Electron Transfer year: 1993 ident: ref33/cit33e – volume: 112 start-page: 20076 year: 2008 ident: ref1/cit1e publication-title: J. Phys. Chem. C doi: 10.1021/jp806879c – volume: 37 start-page: 1540 year: 1964 ident: ref2/cit2 publication-title: Bull. Chem. Soc. Jpn. doi: 10.1246/bcsj.37.1540 – volume: 111 start-page: 6983 year: 2007 ident: ref42/cit42 publication-title: J. Phys. Chem. B doi: 10.1021/jp0726945 – volume: 109 start-page: 8218 year: 1998 ident: ref27/cit27a publication-title: J. Chem. Phys. doi: 10.1063/1.477483 – volume: 133 start-page: 93 year: 1982 ident: ref33/cit33c publication-title: Z. Phys. Chem. (Muenchen, Ger.) doi: 10.1524/zpch.1982.133.1.093 – volume: 10 start-page: 2979 year: 2009 ident: ref17/cit17 publication-title: Phys. Chem. Phys. Chem. doi: 10.1002/cphc.200900309 – volume: 55 start-page: 117 year: 1981 ident: ref29/cit29b publication-title: Chem. Phys. doi: 10.1016/0301-0104(81)85090-2 – volume-title: Handbook of Photochemistry year: 1993 ident: ref35/cit35 – volume: 125 start-page: 9288 year: 2003 ident: ref19/cit19a publication-title: J. Am. Chem. Soc. doi: 10.1021/ja029489h – volume: 74 start-page: 8484 year: 2009 ident: ref20/cit20 publication-title: J. Org. Chem. doi: 10.1021/jo901869g – volume: 78 start-page: 741 year: 1974 ident: ref43/cit43c publication-title: J. Phys. Chem. doi: 10.1021/j100600a020 – volume: 78 start-page: 1473 year: 1974 ident: ref43/cit43d publication-title: J. Phys. Chem. doi: 10.1021/j100608a006 – start-page: 2125 year: 1969 ident: ref5/cit5a publication-title: Tetrahedron Lett. doi: 10.1016/S0040-4039(01)88102-8 – volume: 8 start-page: 259 year: 1970 ident: ref33/cit33a publication-title: Isr. J. Chem. doi: 10.1002/ijch.197000029 – start-page: 923 year: 1969 ident: ref4/cit4a publication-title: Tetrahedron Lett. doi: 10.1016/S0040-4039(01)97699-3 – volume-title: Principles of Molecular Photochemistry: An Introduction year: 2009 ident: ref18/cit18 – volume: 98 start-page: 5648 year: 1993 ident: ref24/cit24 publication-title: J. Chem. Phys. doi: 10.1063/1.464913 – start-page: 2121 year: 1969 ident: ref4/cit4b publication-title: Tetrahedron Lett. doi: 10.1016/S0040-4039(01)88101-6 – volume: 256 start-page: 454 year: 1996 ident: ref27/cit27b publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(96)00440-X – volume: 32 start-page: 4519 year: 1999 ident: ref1/cit1c publication-title: Macromolecules doi: 10.1021/ma990157f – volume: 82 start-page: 2304 year: 1978 ident: ref9/cit9 publication-title: J. Phys. Chem. doi: 10.1021/j100510a011 – volume: 61 start-page: 250 year: 1978 ident: ref8/cit8 publication-title: Helv. Chim. Acta doi: 10.1002/hlca.19780610122 – volume: 86 start-page: 3803 year: 1982 ident: ref30/cit30 publication-title: J. Phys. Chem. doi: 10.1021/j100216a020 |
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| Snippet | The nonradiative decay of four dipolar fluorenone derivatives (FODs) was systematically investigated using steady state and time-resolved UV–vis absorption and... The nonradiative decay of four dipolar fluorenone derivatives (FODs) was systematically investigated using steady state and time-resolved UV-vis absorption and... |
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| Title | Revisiting Fluorenone Photophysics via Dipolar Fluorenone Derivatives |
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