Temperature and pressure effects on the partitioning of V and Sc between clinopyroxene and silicate melt; implications for mantle oxygen fugacity

• Published in: The American mineralogist Vol. 103; no. 5; pp. 819 - 823
• Main Author: Li Yuan, Li Yuan
• Format: Journal Article
• Language: English
• Published: Washington Mineralogical Society of America 01.05.2018; Walter de Gruyter GmbH
• Subjects: amphibole group; Arrays; Basalt; basalts; chain silicates; clinoamphibole; clinopyroxene; Coefficients; Composition; effects; electron probe data; experimental studies; Fractionation; Fugacity; Geophysics; high pressure; high temperature; hornblende; igneous rocks; Magma; Mantle; Melts; Meltwater; metals; mid-ocean ridge basalts; mineral properties; Moisture content; oxidation; Oxygen; Oxygen fugacity; partition coefficients; Partitioning; Pressure; Pressure effects; pyroxene group; rare earths; scandium; silicate melt; silicate melts; Silicates; Systematics; temperature; Temperature effects; trace elements; upper mantle; valency; vanadium; volcanic rocks; Water content
• ISSN: 0003-004X; 1945-3027
• DOI: 10.2138/am-2018-6464

The partition coefficients of V and Sc between clinopyroxene and silicate melt (DVCpx/SM and DScCpx/SM) have been determined experimentally at 1200-1400 °C and 0.8-2.3 GPa, using a hornblende- and clinopyroxene-rich mantle rock in graphite-lined Pt95Rh05 capsules. The results show that the DVCpx/SM and DScCpx/SM values decrease from 3.8 to 2.3 and from 2.6 to 1.1, respectively, as the experimental temperature and pressure vary from 1200 °C and 0.8 GPa to 1400 °C and 2.3 GPa. The presence of water in silicate melts may also reduce DVCpx/SM and DScCpx/SM. These results imply that the effects of temperature, pressure, and melt water content on DVCpx/SM should be considered when using V systematics in cratonic mantle peridotites to constrain cratonic mantle oxygen fugacity (fO2). However, although the dominant V in the present silicate melt is mixed V3+ and V4+, the DVCpx/SM/DScCpx/SM together with literature data obtained at similar fO2 shows a nearly constant value of 1.68 ± 0.26, regardless of temperature, pressure, melt composition, and melt water content, indicating that these factors cannot cause fractionation of Sc3+ from mixed V3+ and V4+ in mantle melts through clinopyroxene/silicate melt partitioning. Therefore, in combination with V/Sc systematics in primitive MORBs and arc basalts, using DVCpx/SM and DScCpx/SM obtained at 1 bar and dry conditions should be valid to constrain mantle fO2, except for the case that the DCpx/SM for Sc3+ can be demonstrated to be fractionated from the DCpx/SM for mixed V4+ and V5+, which are present in oxidized basalts.