Highly Transparent, Underwater Self-Healing, and Ionic Conductive Elastomer Based on Multivalent Ion–Dipole Interactions
Ionic conductors that combine transparency, elasticity, and underwater self-healing capability are highly desirable because of their applications in biosensors, touch panels, marine ships, and so forth. Polymer materials based on ion–dipole interactions can meet these requirements. However, a key tr...
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| Published in | Chemistry of materials Vol. 32; no. 15; pp. 6310 - 6317 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
11.08.2020
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| Online Access | Get full text |
| ISSN | 0897-4756 1520-5002 |
| DOI | 10.1021/acs.chemmater.0c00096 |
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| Abstract | Ionic conductors that combine transparency, elasticity, and underwater self-healing capability are highly desirable because of their applications in biosensors, touch panels, marine ships, and so forth. Polymer materials based on ion–dipole interactions can meet these requirements. However, a key trade-off is their relatively weak mechanical properties because of the plasticizing effect. Here, we designed and synthesized a new ionic liquid building block to enable a new design of multivalent ion–dipole interaction. The resultant ion–dipole polymer complex not only enhances the Young’s modulus by more than 3 times but also possesses much better elasticity, without any sacrifice on the ionic conductivity or self-healing capability. |
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| AbstractList | Ionic conductors that combine transparency, elasticity, and underwater self-healing capability are highly desirable because of their applications in biosensors, touch panels, marine ships, and so forth. Polymer materials based on ion–dipole interactions can meet these requirements. However, a key trade-off is their relatively weak mechanical properties because of the plasticizing effect. Here, we designed and synthesized a new ionic liquid building block to enable a new design of multivalent ion–dipole interaction. The resultant ion–dipole polymer complex not only enhances the Young’s modulus by more than 3 times but also possesses much better elasticity, without any sacrifice on the ionic conductivity or self-healing capability. |
| Author | Li, Mengxue Wang, Chao Liu, Yuncong Chen, Lili Zhang, Xi Zhang, Yucheng Qin, Bo |
| AuthorAffiliation | Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry |
| AuthorAffiliation_xml | – name: Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry |
| Author_xml | – sequence: 1 givenname: Yucheng orcidid: 0000-0003-2474-2474 surname: Zhang fullname: Zhang, Yucheng – sequence: 2 givenname: Mengxue surname: Li fullname: Li, Mengxue – sequence: 3 givenname: Bo surname: Qin fullname: Qin, Bo – sequence: 4 givenname: Lili surname: Chen fullname: Chen, Lili – sequence: 5 givenname: Yuncong surname: Liu fullname: Liu, Yuncong – sequence: 6 givenname: Xi orcidid: 0000-0002-4823-9120 surname: Zhang fullname: Zhang, Xi – sequence: 7 givenname: Chao orcidid: 0000-0002-0739-6066 surname: Wang fullname: Wang, Chao email: chaowangthu@tsinghua.edu.cn |
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| Title | Highly Transparent, Underwater Self-Healing, and Ionic Conductive Elastomer Based on Multivalent Ion–Dipole Interactions |
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