Design and Synthesis of Cycloplatinated Polymer Dots as Photocatalysts for Visible-Light-Driven Hydrogen Evolution

By mimicking natural photosynthesis, generating hydrogen through visible-light-driven splitting of water would be an almost ideal process for converting abundant solar energy into a usable fuel in an environmentally friendly and high-energy-density manner. In a search for efficient photocatalysts th...

Full description

Saved in:
Bibliographic Details
Published inACS catalysis Vol. 8; no. 9; pp. 7766 - 7772
Main Authors Tseng, Po-Jung, Chang, Chih-Li, Chan, Yang-Hsiang, Ting, Li-Yu, Chen, Pei-Yu, Liao, Chia-Hsien, Tsai, Ming-Li, Chou, Ho-Hsiu
Format Journal Article
LanguageEnglish
Published American Chemical Society 07.09.2018
Subjects
hydrogen evolution
polymer dots
visible light
semiconducting polymers
photocatalysts
Online AccessGet full text
ISSN2155-5435
2155-5435
DOI10.1021/acscatal.8b01678

Cover

Abstract By mimicking natural photosynthesis, generating hydrogen through visible-light-driven splitting of water would be an almost ideal process for converting abundant solar energy into a usable fuel in an environmentally friendly and high-energy-density manner. In a search for efficient photocatalysts that mimic such a function, here we describe a series of cycloplatinated polymer dots (Pdots), in which the platinum complex unit is presynthesized as a comonomer and then covalently linked to a conjugated polymer backbone through Suzuki–Miyaura cross-coupling polymerization. On the basis of our design strategy, the hydrogen evolution rate (HER) of the cycloplatinated Pdots can be enhanced by 12 times in comparison to that of pristine Pdots under otherwise identical conditions. In comparison to the Pt-complex-blended counterpart Pdots, the HER of cycloplatinated Pdots is over 2 times higher than that of physically blended Pdots. Furthermore, enhancement of the photocatalytic reaction time with high eventual hydrogen production and low efficiency rolloff are observed by utilizing the cycloplatinated Pdots as photocatalysts. On the basis of their performance, our cyclometallic Pdot systems appear to be alternative types of promising photocatalysts for visible-light-driven hydrogen evolution.
AbstractList By mimicking natural photosynthesis, generating hydrogen through visible-light-driven splitting of water would be an almost ideal process for converting abundant solar energy into a usable fuel in an environmentally friendly and high-energy-density manner. In a search for efficient photocatalysts that mimic such a function, here we describe a series of cycloplatinated polymer dots (Pdots), in which the platinum complex unit is presynthesized as a comonomer and then covalently linked to a conjugated polymer backbone through Suzuki–Miyaura cross-coupling polymerization. On the basis of our design strategy, the hydrogen evolution rate (HER) of the cycloplatinated Pdots can be enhanced by 12 times in comparison to that of pristine Pdots under otherwise identical conditions. In comparison to the Pt-complex-blended counterpart Pdots, the HER of cycloplatinated Pdots is over 2 times higher than that of physically blended Pdots. Furthermore, enhancement of the photocatalytic reaction time with high eventual hydrogen production and low efficiency rolloff are observed by utilizing the cycloplatinated Pdots as photocatalysts. On the basis of their performance, our cyclometallic Pdot systems appear to be alternative types of promising photocatalysts for visible-light-driven hydrogen evolution.
Author Chan, Yang-Hsiang
Chen, Pei-Yu
Chou, Ho-Hsiu
Tseng, Po-Jung
Chang, Chih-Li
Ting, Li-Yu
Liao, Chia-Hsien
Tsai, Ming-Li
AuthorAffiliation Department of Chemistry
National Sun Yat-sen University
Department of Chemical Engineering
National Tsing Hua University
AuthorAffiliation_xml – name: Department of Chemical Engineering
– name: National Tsing Hua University
– name: Department of Chemistry
– name: National Sun Yat-sen University
Author_xml – sequence: 1
  givenname: Po-Jung
  surname: Tseng
  fullname: Tseng, Po-Jung
  organization: National Sun Yat-sen University
– sequence: 2
  givenname: Chih-Li
  surname: Chang
  fullname: Chang, Chih-Li
  organization: National Tsing Hua University
– sequence: 3
  givenname: Yang-Hsiang
  orcidid: 0000-0002-9007-3910
  surname: Chan
  fullname: Chan, Yang-Hsiang
  organization: National Sun Yat-sen University
– sequence: 4
  givenname: Li-Yu
  surname: Ting
  fullname: Ting, Li-Yu
  organization: National Tsing Hua University
– sequence: 5
  givenname: Pei-Yu
  surname: Chen
  fullname: Chen, Pei-Yu
  organization: National Tsing Hua University
– sequence: 6
  givenname: Chia-Hsien
  surname: Liao
  fullname: Liao, Chia-Hsien
  organization: National Sun Yat-sen University
– sequence: 7
  givenname: Ming-Li
  surname: Tsai
  fullname: Tsai, Ming-Li
  organization: National Sun Yat-sen University
– sequence: 8
  givenname: Ho-Hsiu
  orcidid: 0000-0003-3777-2277
  surname: Chou
  fullname: Chou, Ho-Hsiu
  email: hhchou@mx.nthu.edu.tw
  organization: National Tsing Hua University
BookMark eNp9UMtOAjEUbQwmIrJ32Q9wsJ1pO8PSAIoJiSQ-tpNO24GS0pK2kMzfWwQTY6J3cx_nnvs416BnnVUA3GI0wijH91wEwSM3o6pBmJXVBejnmNKMkoL2fsRXYBjCBiUjlFUl6gM_VUGvLORWwtfOxnVKA3QtnHTCuJ3hUVselYRLZ7qt8nDqYoA8wOXaRfe1tAup0joPP3TQjVHZQq_WMZt6fVAWzjvp3SoFs4Mz-6idvQGXLTdBDc9-AN4fZ2-TebZ4eXqePCwyXhAWMzZWjImKkDxHVSlwQZuyRAy3qFQsrwqZMFoiTqVqxrxlhBLEpRQct3lOlCwGgJ3mCu9C8KqthY78eEH0XJsao_ooXv0tXn0WLxHRL-LO6y333X-UuxMlIfXG7b1Nn_3d_gnrD4eq
CitedBy_id crossref_primary_10_1016_j_isci_2019_02_007
crossref_primary_10_1039_D0SC05866A
crossref_primary_10_1016_j_apcatb_2020_119802
crossref_primary_10_1021_acs_organomet_8b00461
crossref_primary_10_1002_smll_202402649
crossref_primary_10_1039_D0TA01200A
crossref_primary_10_1016_j_apsusc_2022_155182
crossref_primary_10_1002_cctc_201901725
crossref_primary_10_1039_D1TA02193A
crossref_primary_10_3390_app10207017
crossref_primary_10_1002_adom_202000641
crossref_primary_10_1021_acsaem_1c02772
crossref_primary_10_1038_s41467_022_33211_1
crossref_primary_10_1039_D0TC03800H
crossref_primary_10_1002_anie_202202733
crossref_primary_10_1016_j_apcatb_2020_119659
crossref_primary_10_1021_acsmacrolett_3c00016
crossref_primary_10_1016_j_ijhydene_2023_07_296
crossref_primary_10_1016_j_apcatb_2019_118436
crossref_primary_10_1039_C9TA06425G
crossref_primary_10_1016_j_cej_2024_149193
crossref_primary_10_1021_acsapm_9b00859
crossref_primary_10_1002_ange_202104233
crossref_primary_10_1002_ejic_202100732
crossref_primary_10_1039_C9TA04018H
crossref_primary_10_1039_D2TA00241H
crossref_primary_10_1016_j_enconman_2021_115133
crossref_primary_10_1039_C9TA06219J
crossref_primary_10_1021_acsapm_0c01070
crossref_primary_10_1039_D2NJ05555D
crossref_primary_10_1002_aenm_202300986
crossref_primary_10_1002_jccs_202300020
crossref_primary_10_1021_acsapm_0c00791
crossref_primary_10_1021_acsomega_2c07562
crossref_primary_10_1021_acsaelm_1c00031
crossref_primary_10_1002_aenm_202001935
crossref_primary_10_1016_j_apcatb_2021_120819
crossref_primary_10_1039_C8TA11383A
crossref_primary_10_1002_ange_202202733
crossref_primary_10_1002_bmm2_12126
crossref_primary_10_1002_anie_202104233
crossref_primary_10_3390_ma14154236
crossref_primary_10_1021_acs_macromol_9b00551
crossref_primary_10_1021_acs_macromol_2c02130
crossref_primary_10_1039_C8TA12146J
crossref_primary_10_1002_smll_202007576
crossref_primary_10_1016_j_jcis_2024_11_242
crossref_primary_10_1039_D0PY01351J
crossref_primary_10_1002_smll_202400259
crossref_primary_10_1039_D4CP04108A
crossref_primary_10_1039_C8TA09735F
crossref_primary_10_1039_C9CS00313D
crossref_primary_10_1039_D0CC00846J
crossref_primary_10_1021_acs_chemmater_3c02286
crossref_primary_10_1021_jacs_0c06104
crossref_primary_10_1039_C9EE01935A
crossref_primary_10_1016_j_apcatb_2022_121383
crossref_primary_10_1016_j_ijhydene_2022_06_296
crossref_primary_10_1039_D0CC00740D
crossref_primary_10_1021_acsapm_0c00715
crossref_primary_10_1038_s41467_018_07420_6
crossref_primary_10_1021_acs_organomet_2c00064
crossref_primary_10_1021_acsami_2c17829
crossref_primary_10_1021_acs_chemmater_0c04425
crossref_primary_10_1038_s41467_024_51097_z
crossref_primary_10_1016_j_ijhydene_2020_08_288
crossref_primary_10_1038_s41467_024_45085_6
crossref_primary_10_1039_D0TA04754F
crossref_primary_10_1002_adma_202210481
crossref_primary_10_1016_j_jece_2021_106927
crossref_primary_10_1016_j_apcatb_2019_118067
crossref_primary_10_1021_acs_jpcc_3c02247
crossref_primary_10_1039_D0NJ05037G
crossref_primary_10_1016_j_cocis_2021_101511
crossref_primary_10_1021_acsmaterialslett_9b00325
crossref_primary_10_1002_asia_202000247
crossref_primary_10_1021_acsanm_1c03872
crossref_primary_10_1039_D2CS00356B
crossref_primary_10_1002_er_7552
crossref_primary_10_1002_aenm_202303680
crossref_primary_10_1002_smll_202302682
crossref_primary_10_1002_smll_202304743
crossref_primary_10_1021_acs_macromol_1c00489
crossref_primary_10_1016_j_micromeso_2022_112258
crossref_primary_10_1016_j_cej_2021_129825
crossref_primary_10_1021_acs_chemmater_8b02833
crossref_primary_10_1039_D1NJ04242D
crossref_primary_10_1021_acsenergylett_0c00075
crossref_primary_10_2139_ssrn_4092250
crossref_primary_10_1002_adma_201907296
crossref_primary_10_1016_j_nanoen_2019_04_027
crossref_primary_10_1007_s11708_021_0767_7
crossref_primary_10_1039_D0NR07533G
crossref_primary_10_1039_D2SE00902A
crossref_primary_10_1039_D3TA06807B
crossref_primary_10_1016_j_apcata_2019_117352
crossref_primary_10_1016_j_polymer_2020_123079
crossref_primary_10_1016_j_ijhydene_2020_11_120
crossref_primary_10_1039_D0EE01213K
crossref_primary_10_1016_j_apcatb_2021_120184
crossref_primary_10_1002_solr_202300994
crossref_primary_10_1016_j_apsusc_2022_154425
crossref_primary_10_1021_jacs_2c03882
crossref_primary_10_1021_jacs_0c12654
crossref_primary_10_1039_D4MH00482E
crossref_primary_10_1021_acssuschemeng_8b05637
crossref_primary_10_1021_acsami_2c18831
crossref_primary_10_1002_marc_202200108
crossref_primary_10_1016_j_jorganchem_2022_122453
crossref_primary_10_1039_D0SE00928H
crossref_primary_10_1021_acs_chemmater_0c04348
Cites_doi 10.1021/acs.macromol.6b01764
10.1021/jacs.5b06710
10.1039/c39850000474
10.1039/C4SC00016A
10.1021/ja9034818
10.1002/anie.201510542
10.1002/aenm.201700479
10.1039/C4TC00871E
10.1021/acsnano.7b00215
10.1002/adma.201601168
10.1039/C1SC00257K
10.1038/nmat2317
10.1002/anie.200903886
10.1021/jp963973n
10.1039/C4TB01026D
10.1002/marc.201300227
10.1016/j.jcat.2009.06.024
10.1039/c3ta10851a
10.1002/adma.201104063
10.1021/acscatal.7b04091
10.1021/jacs.6b03472
10.1039/B800489G
10.1021/acscatal.8b00407
10.1021/acscatal.7b02331
10.1021/am506577r
10.1021/ar300227e
10.1021/ja511552k
10.1002/anie.201607018
10.1021/acs.chemmater.6b01477
10.1002/ente.201500478
10.1016/j.apcatb.2013.02.006
10.1021/acsmacrolett.5b00842
10.1002/anie.201603532
10.1038/nmat4049
10.1039/c0cc04057f
10.1016/j.apsusc.2015.08.173
10.1039/C7EE00751E
10.1016/j.solmat.2012.09.033
10.1021/j100368a063
10.1039/C6NR00160B
10.1039/C39920001652
10.1021/acscatal.7b00587
ContentType Journal Article
DBID AAYXX
CITATION
DOI 10.1021/acscatal.8b01678
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 2155-5435
EndPage 7772
ExternalDocumentID 10_1021_acscatal_8b01678
c473356986
GroupedDBID 53G
55A
7~N
AABXI
ABMVS
ABUCX
ACGFS
ACS
AEESW
AENEX
AFEFF
ALMA_UNASSIGNED_HOLDINGS
AQSVZ
EBS
ED
ED~
EJD
GNL
IH9
JG
JG~
RNS
ROL
UI2
VF5
VG9
W1F
.K2
AAHBH
AAYXX
ABBLG
ABJNI
ABLBI
ABQRX
ACGFO
ADHLV
AHGAQ
BAANH
CITATION
CUPRZ
GGK
ID FETCH-LOGICAL-a346t-69e66c84422087c135b77061f07e6283dc84570a5deb9af64540addca1f224ed3
IEDL.DBID ACS
ISSN 2155-5435
IngestDate Thu Apr 24 22:52:50 EDT 2025
Tue Jul 01 02:21:35 EDT 2025
Thu Aug 27 13:42:08 EDT 2020
IsPeerReviewed true
IsScholarly true
Issue 9
Keywords hydrogen evolution
polymer dots
visible light
semiconducting polymers
photocatalysts
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-a346t-69e66c84422087c135b77061f07e6283dc84570a5deb9af64540addca1f224ed3
ORCID 0000-0002-9007-3910
0000-0003-3777-2277
PageCount 7
ParticipantIDs crossref_citationtrail_10_1021_acscatal_8b01678
crossref_primary_10_1021_acscatal_8b01678
acs_journals_10_1021_acscatal_8b01678
ProviderPackageCode JG~
55A
AABXI
GNL
VF5
7~N
VG9
W1F
ACS
AEESW
AFEFF
ABMVS
ABUCX
IH9
AQSVZ
ED~
UI2
CITATION
AAYXX
PublicationCentury 2000
PublicationDate 2018-09-07
PublicationDateYYYYMMDD 2018-09-07
PublicationDate_xml – month: 09
  year: 2018
  text: 2018-09-07
  day: 07
PublicationDecade 2010
PublicationTitle ACS catalysis
PublicationTitleAlternate ACS Catal
PublicationYear 2018
Publisher American Chemical Society
Publisher_xml – name: American Chemical Society
References ref9/cit9
ref6/cit6
ref36/cit36
ref3/cit3
ref27/cit27
ref18/cit18
ref11/cit11
ref25/cit25
ref16/cit16
ref29/cit29
ref32/cit32
ref23/cit23
ref39/cit39
ref14/cit14
ref8/cit8
ref5/cit5
ref31/cit31
ref2/cit2
ref34/cit34
ref37/cit37
ref28/cit28
ref40/cit40
ref20/cit20
ref17/cit17
ref10/cit10
ref26/cit26
ref35/cit35
ref19/cit19
ref21/cit21
ref12/cit12
ref15/cit15
ref42/cit42
ref41/cit41
ref22/cit22
ref13/cit13
ref33/cit33
ref4/cit4
ref30/cit30
ref1/cit1
ref24/cit24
ref38/cit38
ref7/cit7
References_xml – ident: ref27/cit27
  doi: 10.1021/acs.macromol.6b01764
– ident: ref31/cit31
  doi: 10.1021/jacs.5b06710
– ident: ref8/cit8
  doi: 10.1039/c39850000474
– ident: ref17/cit17
  doi: 10.1039/C4SC00016A
– ident: ref39/cit39
  doi: 10.1021/ja9034818
– ident: ref10/cit10
  doi: 10.1002/anie.201510542
– ident: ref21/cit21
  doi: 10.1002/aenm.201700479
– ident: ref40/cit40
  doi: 10.1039/C4TC00871E
– ident: ref33/cit33
  doi: 10.1021/acsnano.7b00215
– ident: ref41/cit41
  doi: 10.1002/adma.201601168
– ident: ref14/cit14
  doi: 10.1039/C1SC00257K
– ident: ref6/cit6
  doi: 10.1038/nmat2317
– ident: ref25/cit25
  doi: 10.1002/anie.200903886
– ident: ref13/cit13
  doi: 10.1021/jp963973n
– ident: ref30/cit30
  doi: 10.1039/C4TB01026D
– ident: ref15/cit15
  doi: 10.1002/marc.201300227
– ident: ref36/cit36
  doi: 10.1016/j.jcat.2009.06.024
– ident: ref24/cit24
  doi: 10.1039/c3ta10851a
– ident: ref38/cit38
  doi: 10.1002/adma.201104063
– ident: ref4/cit4
  doi: 10.1021/acscatal.7b04091
– ident: ref26/cit26
  doi: 10.1021/jacs.6b03472
– ident: ref1/cit1
  doi: 10.1039/B800489G
– ident: ref20/cit20
  doi: 10.1021/acscatal.8b00407
– ident: ref2/cit2
  doi: 10.1021/acscatal.7b02331
– ident: ref29/cit29
  doi: 10.1021/am506577r
– ident: ref37/cit37
  doi: 10.1021/ar300227e
– ident: ref18/cit18
  doi: 10.1021/ja511552k
– ident: ref22/cit22
  doi: 10.1002/anie.201607018
– ident: ref28/cit28
  doi: 10.1021/acs.chemmater.6b01477
– ident: ref16/cit16
  doi: 10.1002/ente.201500478
– ident: ref35/cit35
  doi: 10.1016/j.apcatb.2013.02.006
– ident: ref32/cit32
  doi: 10.1021/acsmacrolett.5b00842
– ident: ref19/cit19
  doi: 10.1002/anie.201603532
– ident: ref42/cit42
  doi: 10.1038/nmat4049
– ident: ref11/cit11
  doi: 10.1039/c0cc04057f
– ident: ref7/cit7
  doi: 10.1016/j.apsusc.2015.08.173
– ident: ref23/cit23
  doi: 10.1039/C7EE00751E
– ident: ref34/cit34
  doi: 10.1016/j.solmat.2012.09.033
– ident: ref9/cit9
  doi: 10.1021/j100368a063
– ident: ref5/cit5
  doi: 10.1039/C6NR00160B
– ident: ref12/cit12
  doi: 10.1039/C39920001652
– ident: ref3/cit3
  doi: 10.1021/acscatal.7b00587
SSID ssj0000456870
Score 2.548207
Snippet By mimicking natural photosynthesis, generating hydrogen through visible-light-driven splitting of water would be an almost ideal process for converting...
SourceID crossref
acs
SourceType Enrichment Source
Index Database
Publisher
StartPage 7766
Title Design and Synthesis of Cycloplatinated Polymer Dots as Photocatalysts for Visible-Light-Driven Hydrogen Evolution
URI http://dx.doi.org/10.1021/acscatal.8b01678
Volume 8
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
journalDatabaseRights – providerCode: PRVABC
  databaseName: American Chemical Society Journals
  customDbUrl:
  eissn: 2155-5435
  dateEnd: 99991231
  omitProxy: false
  ssIdentifier: ssj0000456870
  issn: 2155-5435
  databaseCode: ACS
  dateStart: 20110107
  isFulltext: true
  titleUrlDefault: https://pubs.acs.org/action/showPublications?display=journals
  providerName: American Chemical Society
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1LT4QwEG50PejFt_GdHvTggZVCKd3jZtfNxqgx8ZG9kbaUaFzBUDTBX--0y6rxFa9ASzOd4fvoTL5B6IACpwAYibxOBr8oVHDm2SjydCoJExEXwvVPOb9gwxt6OopGHzI5XzP4ATkWyriTjDaXtmSez6K5gMWxLd_r9q7ez1MsNeGuNxyAWORFQAOarORPk1gsUuYTFn0ClcHSpDuRcVqEtpbkof1cybZ6_a7U-I_1LqPFhlvi7sQZVtCMzlfRfG_a0m0NlX1Xr4FFnuKrOgfuZ-4NLjLcq9W4eLJlcTlwzxRfFuP6UZe4X1QGC4Mv74qqcO-rDVwBootv7yGYxto7c0ok_dJ-NfGwTssCXBKfvDQuvY5uBifXvaHXNF3wREhZ5bGOZkxxSoPA57EiYSTjGEA_82PNgIukcC-KfRGlWnZEZgXBfNhdJUgGbECn4QZq5UWuNxEmlAiShowzP6M60FzJTFBFSKi0krKzhQ7BWEkTNCZx-fCAJFMLJo0Ft9DxdJsS1SiX2wYa4z9GHL2PeJqodvz67PY_V7GDFoAsuVoRP95Frap81ntASCq57zzxDWRn3h8
linkProvider American Chemical Society
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1LT9wwEB5ReqCX0vJQgT58gAOHLPHGdrxHtAvalgWh8hC3yHYcseo2QXFASn99xya7RVWp2qsTO6PxOPPZM_4GYJchpkA3wqNBgVsUpqSI_CqKbK6pUFwqFeqnnJ6J8RX7csNvloDO78KgEA5HciGI_4tdgB5gWzjQ6EntM-flC3jJBaN-v3U4vFgcq3iEIkOJOPRlPOKIBrrg5J8G8S7JuCcu6YlvOV6FrwupQkrJt959o3vmx2-Ejf8l9ht43SFNcvhoGm9hyZZrsDKcF3hbh3oUsjeIKnNy0ZaIBN3Ukaogw9bMqjufJFciEs3JeTVrv9uajKrGEeXI-W3VVOF7rcMWhL3keopLa2ajSeAlGdX-H0rGbV5XaKDk6KEz8A24Oj66HI6jrgRDpBImmkgMrBBGMtbvxzI1NOE6TRECFHFqBSKTHJ_xNFY8t3qgCk8PFuNcG0ULxAY2TzZhuaxK-w4IZVTRPBFSxAWzfSuNLhQzlCbGGq0HW7CHysq6JeSyEB3v02yuwazT4BYczGcrMx2PuS-nMftLj_1Fj7tHDo9n393-Ryk-wcr48nSSTT6fnezAK4RRIYskTt_DclPf2w8IVRr9MRjnT3j85oE
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlZ1Lb9QwEIBHpZWAC5RHRXkUH-DAIdt4YzveI9rtaltKtVJp1VvkV9SqS7KKU6Tw6xm72VWFAJWrEzsjeybzxZ7MAHxgyBToRngyKvEThSkpkmBFibOaCsWlUrF-ytcTMTtjRxf8YgP46l8YFMLjSD4e4gerXtqyzzBA97E9bmoMpA7R8_IBbHGBlh6IaHy63loJlCJjmTj0ZzzhSAT9AeWfBgluyfg7bumOf5k-hfO1ZDGs5Hpw0-qB-flb0sb_Fn0bnvTEST7fqsgz2HDVc3g0XhV6ewHNJEZxEFVZctpVSIT-ypO6JOPOLOplCJarkEgtmdeL7rtryKRuPVGezC_rto7P6zy2IP6S8ys0sYVLjmN-kkkT3qVk1tmmRkUlBz96RX8JZ9ODb-NZ0pdiSFTGRJuIkRPCSMaGw1TmhmZc5zmiQJnmTiChWLzG81Rx6_RIlSFNWIprbhQtkRGczXZgs6or9woIZVRRmwkp0pK5oZNGl4oZSjPjjNajXfiIk1X0puSLeEo-pMVqBot-Bndhf7VihenzmYeyGot_9Pi07rG8zeXx13tf31OK9_BwPpkWx4cnX97AY6SpGEyS5m9hs21u3DskllbvRf38Be3-6QQ
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Design+and+Synthesis+of+Cycloplatinated+Polymer+Dots+as+Photocatalysts+for+Visible-Light-Driven+Hydrogen+Evolution&rft.jtitle=ACS+catalysis&rft.au=Tseng%2C+Po-Jung&rft.au=Chang%2C+Chih-Li&rft.au=Chan%2C+Yang-Hsiang&rft.au=Ting%2C+Li-Yu&rft.date=2018-09-07&rft.issn=2155-5435&rft.eissn=2155-5435&rft.volume=8&rft.issue=9&rft.spage=7766&rft.epage=7772&rft_id=info:doi/10.1021%2Facscatal.8b01678&rft.externalDBID=n%2Fa&rft.externalDocID=10_1021_acscatal_8b01678
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2155-5435&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2155-5435&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2155-5435&client=summon