Significantly Enhanced Electrocatalytic Reduction of Chloramphenicol from Water Mediated by Fe–F–N Co-doped Carbon Materials
Chloramphenicol (CAP) is a widely used antibiotic drug and poses a great threat to human health and the ecosystem. In this work, an iron–fluorine–nitrogen (Fe–F–N) co-doped porous carbon material was innovatively prepared and applied for the electrocatalytic reduction of CAP from water, and excellen...
Saved in:
| Published in | ACS ES&T water Vol. 3; no. 5; pp. 1385 - 1394 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
12.05.2023
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 2690-0637 2690-0637 |
| DOI | 10.1021/acsestwater.3c00059 |
Cover
| Abstract | Chloramphenicol (CAP) is a widely used antibiotic drug and poses a great threat to human health and the ecosystem. In this work, an iron–fluorine–nitrogen (Fe–F–N) co-doped porous carbon material was innovatively prepared and applied for the electrocatalytic reduction of CAP from water, and excellent treatment performance was achieved. For an initial CAP concentration of 10 mg/L, after 60 min operation, almost 100% of CAP was removed. The active Fe(II) sites and the F-doping-induced electronic structure of Fe-FNC facilitated the electrocatalytic reductive degradation of CAP by promoting electron transfer, rather than the H*-mediated indirect reduction process. Therefore, a better treatment performance was obtained by Fe-FNC compared to other catalysts such as Fe-NC and FNC. The reaction pathways for CAP reduction were elucidated, and the ecotoxicity of the reaction products was assessed. The toxicity of the intermediate products was found to be significantly reduced, indicative of the good prospect of this method for CAP-containing wastewater pretreatment. |
|---|---|
| AbstractList | Chloramphenicol (CAP) is a widely used antibiotic drug and poses a great threat to human health and the ecosystem. In this work, an iron–fluorine–nitrogen (Fe–F–N) co-doped porous carbon material was innovatively prepared and applied for the electrocatalytic reduction of CAP from water, and excellent treatment performance was achieved. For an initial CAP concentration of 10 mg/L, after 60 min operation, almost 100% of CAP was removed. The active Fe(II) sites and the F-doping-induced electronic structure of Fe-FNC facilitated the electrocatalytic reductive degradation of CAP by promoting electron transfer, rather than the H*-mediated indirect reduction process. Therefore, a better treatment performance was obtained by Fe-FNC compared to other catalysts such as Fe-NC and FNC. The reaction pathways for CAP reduction were elucidated, and the ecotoxicity of the reaction products was assessed. The toxicity of the intermediate products was found to be significantly reduced, indicative of the good prospect of this method for CAP-containing wastewater pretreatment. |
| Author | Tang, Wangwang Jin, Wanwan Feng, Jing Xing, Wenle |
| AuthorAffiliation | School of Resources and Environment PowerChina Zhongnan Engineering Corporation Limited College of Environmental Science and Engineering and Key Laboratory of Environmental Biology and Pollution Control (Ministry of Education) Hunan University of Technology and Business |
| AuthorAffiliation_xml | – name: Hunan University of Technology and Business – name: School of Resources and Environment – name: College of Environmental Science and Engineering and Key Laboratory of Environmental Biology and Pollution Control (Ministry of Education) – name: PowerChina Zhongnan Engineering Corporation Limited |
| Author_xml | – sequence: 1 givenname: Wanwan surname: Jin fullname: Jin, Wanwan organization: College of Environmental Science and Engineering and Key Laboratory of Environmental Biology and Pollution Control (Ministry of Education) – sequence: 2 givenname: Jing surname: Feng fullname: Feng, Jing organization: PowerChina Zhongnan Engineering Corporation Limited – sequence: 3 givenname: Wenle surname: Xing fullname: Xing, Wenle organization: Hunan University of Technology and Business – sequence: 4 givenname: Wangwang orcidid: 0000-0001-7774-7493 surname: Tang fullname: Tang, Wangwang email: wtang@hnu.edu.cn organization: College of Environmental Science and Engineering and Key Laboratory of Environmental Biology and Pollution Control (Ministry of Education) |
| BookMark | eNqFkEtOwzAQhi1UJErpCdj4Amn9SNJkiaIWkFqQeIhlNHFs6iq1K8cVyq534IacBEftArGAxWhGM_P9mvkv0cBYIxG6pmRCCaNTEK1s_Qd46SZcEEKS_AwNWZqTiKR8NvhRX6Bx227CCuNJRmfZEB2e9bvRSgswvunw3KzBCFnjeSOFd1aAh6bzWuAnWe-F19Zgq3CxbqyD7W4tjRa2wcrZLX7rL8ArWetQ1Ljq8EJ-HT4XIR5wYaPa7kK7AFcFkVW_rKFpr9C5CkmOT3mEXhfzl-IuWj7e3hc3ywhYlvuI8SyrVEpJDSKZMZZwRnlaq5jEACnkuaJVTBIhKlLxOM8Zg0xxmQlIFFQM-AjlR13hbNs6qUqhPfQPeQe6KSkpezfLH26WJzcDy3-xO6e34Lp_qOmRCsNyY_fOhP_-JL4BJEuT0g |
| CitedBy_id | crossref_primary_10_1016_j_seppur_2024_126849 crossref_primary_10_1016_j_envres_2024_118357 crossref_primary_10_1016_j_coche_2024_101016 crossref_primary_10_1016_j_ccr_2024_216357 crossref_primary_10_1002_smll_202407104 crossref_primary_10_1016_j_cej_2024_158987 crossref_primary_10_1016_j_apcatb_2023_123437 crossref_primary_10_1016_j_jhazmat_2024_135036 crossref_primary_10_1016_j_seppur_2024_126564 crossref_primary_10_1016_j_cej_2024_152447 crossref_primary_10_1016_j_watres_2025_123432 crossref_primary_10_1016_j_seppur_2023_124388 crossref_primary_10_1016_j_desal_2024_117603 crossref_primary_10_3390_gels10010077 crossref_primary_10_1016_j_cej_2023_148454 crossref_primary_10_1016_j_seppur_2024_127813 crossref_primary_10_1016_j_jiec_2024_05_036 crossref_primary_10_1016_j_cej_2023_144521 crossref_primary_10_1016_j_seppur_2023_124519 crossref_primary_10_1007_s00604_024_06930_z crossref_primary_10_1016_j_seppur_2024_129030 crossref_primary_10_1016_j_memsci_2024_123527 crossref_primary_10_1016_j_jhazmat_2024_133484 crossref_primary_10_1016_j_jece_2025_115613 crossref_primary_10_1016_j_indcrop_2024_120431 crossref_primary_10_1016_j_apcatb_2023_123401 crossref_primary_10_1016_j_chemosphere_2023_140998 crossref_primary_10_1016_j_seppur_2023_124155 crossref_primary_10_1016_j_jcis_2024_06_106 crossref_primary_10_1016_j_desal_2024_118109 crossref_primary_10_1016_j_desal_2024_117852 crossref_primary_10_1016_j_cej_2023_145400 crossref_primary_10_1002_anie_202501797 crossref_primary_10_1016_j_cej_2023_147268 crossref_primary_10_1016_j_psep_2024_12_004 crossref_primary_10_1021_acsestengg_4c00727 crossref_primary_10_1016_j_jfca_2024_106114 crossref_primary_10_1016_j_jhazmat_2024_137030 crossref_primary_10_1016_j_seppur_2024_126385 crossref_primary_10_1016_j_cej_2024_157953 crossref_primary_10_1021_acsestwater_3c00511 crossref_primary_10_1016_j_jhazmat_2023_132106 crossref_primary_10_1016_j_psep_2025_106847 crossref_primary_10_1002_ange_202501797 crossref_primary_10_1021_acsaem_4c03212 crossref_primary_10_1016_j_envres_2024_118643 crossref_primary_10_1016_j_jhazmat_2024_135002 crossref_primary_10_1016_j_psep_2024_11_013 crossref_primary_10_1016_j_ccr_2025_216545 crossref_primary_10_1016_j_envres_2025_121318 crossref_primary_10_1016_j_jcis_2024_12_201 crossref_primary_10_1016_j_desal_2024_117918 crossref_primary_10_1016_j_jallcom_2024_177618 crossref_primary_10_1016_j_jes_2024_01_046 crossref_primary_10_1016_j_jhazmat_2023_132750 crossref_primary_10_1016_j_seppur_2024_130555 crossref_primary_10_1002_smll_202410721 crossref_primary_10_1016_j_jhazmat_2025_137604 crossref_primary_10_1016_j_apsusc_2025_163024 |
| Cites_doi | 10.1016/j.cej.2023.142332 10.1007/s12274-022-4441-0 10.1016/j.apmt.2021.101161 10.1016/j.cej.2019.03.097 10.1016/j.ccr.2021.214277 10.1002/elan.201700780 10.1016/j.electacta.2019.135187 10.1016/j.envint.2017.10.016 10.1016/j.cej.2022.139161 10.1002/anie.201802055 10.1016/j.apcatb.2019.118160 10.1016/j.nanoen.2016.10.037 10.1021/acs.est.5b00729 10.1016/j.jwpe.2022.103080 10.1016/j.cej.2017.09.094 10.1016/j.cej.2021.131403 10.1016/j.ccr.2022.214811 10.1016/j.seppur.2019.116322 10.1007/s11356-021-14248-z 10.1016/j.seppur.2022.121374 10.1007/s10311-023-01561-x 10.1016/j.jhazmat.2022.130023 10.1016/j.apcatb.2020.119591 10.1016/j.cej.2021.129041 10.1007/s12274-022-4306-6 10.1016/j.watres.2023.119831 10.1016/j.talanta.2022.123487 10.1016/j.scitotenv.2018.01.271 10.1021/acscatal.9b00016 10.1016/s1473-3099(20)30332-7 10.1016/j.cej.2022.137356 10.1039/d0nr04920d 10.1016/j.seppur.2020.117376 10.1016/j.jhazmat.2019.121344 10.1016/j.watres.2017.03.054 10.1016/j.fct.2019.01.033 10.1016/j.cej.2018.08.051 10.1016/j.apcatb.2022.122076 10.1016/j.watres.2022.119324 10.1016/j.jhazmat.2021.125162 10.1016/j.coelec.2020.04.005 10.1016/j.seppur.2021.119329 10.1016/j.apcatb.2021.120439 10.1088/1361-6528/ac530c |
| ContentType | Journal Article |
| Copyright | 2023 American Chemical Society |
| Copyright_xml | – notice: 2023 American Chemical Society |
| DBID | AAYXX CITATION |
| DOI | 10.1021/acsestwater.3c00059 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Geography |
| EISSN | 2690-0637 |
| EndPage | 1394 |
| ExternalDocumentID | 10_1021_acsestwater_3c00059 b731787586 |
| GroupedDBID | ABQRX ACS AHGAQ ALMA_UNASSIGNED_HOLDINGS GGK VF5 VG9 AAYXX ABBLG ABJNI ABLBI BAANH CITATION CUPRZ EBS |
| ID | FETCH-LOGICAL-a289t-2388bf610dac5722532136df404aa6a99f1b405ccb0b349922a8f3e8ca5fab2a3 |
| IEDL.DBID | ACS |
| ISSN | 2690-0637 |
| IngestDate | Tue Jul 01 04:22:14 EDT 2025 Thu Apr 24 23:01:51 EDT 2025 Thu Jul 06 08:30:36 EDT 2023 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 5 |
| Keywords | electrochemical reduction chloramphenicol water treatment Fe−F−N co-doped carbon |
| Language | English |
| License | https://doi.org/10.15223/policy-029 https://doi.org/10.15223/policy-037 https://doi.org/10.15223/policy-045 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a289t-2388bf610dac5722532136df404aa6a99f1b405ccb0b349922a8f3e8ca5fab2a3 |
| ORCID | 0000-0001-7774-7493 |
| PageCount | 10 |
| ParticipantIDs | crossref_citationtrail_10_1021_acsestwater_3c00059 crossref_primary_10_1021_acsestwater_3c00059 acs_journals_10_1021_acsestwater_3c00059 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2023-05-12 |
| PublicationDateYYYYMMDD | 2023-05-12 |
| PublicationDate_xml | – month: 05 year: 2023 text: 2023-05-12 day: 12 |
| PublicationDecade | 2020 |
| PublicationTitle | ACS ES&T water |
| PublicationTitleAlternate | ACS EST Water |
| PublicationYear | 2023 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | ref9/cit9 ref6/cit6 ref36/cit36 ref3/cit3 ref27/cit27 ref18/cit18 ref11/cit11 ref25/cit25 ref16/cit16 ref29/cit29 ref32/cit32 ref23/cit23 ref39/cit39 ref14/cit14 ref8/cit8 ref5/cit5 ref31/cit31 ref2/cit2 ref43/cit43 ref34/cit34 ref37/cit37 ref28/cit28 ref40/cit40 ref20/cit20 ref17/cit17 ref10/cit10 ref26/cit26 ref35/cit35 ref19/cit19 ref21/cit21 ref12/cit12 ref15/cit15 ref42/cit42 ref41/cit41 ref22/cit22 ref13/cit13 ref33/cit33 ref4/cit4 ref30/cit30 ref1/cit1 ref24/cit24 ref38/cit38 ref44/cit44 ref7/cit7 |
| References_xml | – ident: ref27/cit27 doi: 10.1016/j.cej.2023.142332 – ident: ref38/cit38 doi: 10.1007/s12274-022-4441-0 – ident: ref4/cit4 doi: 10.1016/j.apmt.2021.101161 – ident: ref41/cit41 doi: 10.1016/j.cej.2019.03.097 – ident: ref11/cit11 doi: 10.1016/j.ccr.2021.214277 – ident: ref26/cit26 doi: 10.1002/elan.201700780 – ident: ref25/cit25 doi: 10.1016/j.electacta.2019.135187 – ident: ref1/cit1 doi: 10.1016/j.envint.2017.10.016 – ident: ref24/cit24 doi: 10.1016/j.cej.2022.139161 – ident: ref37/cit37 doi: 10.1002/anie.201802055 – ident: ref40/cit40 doi: 10.1016/j.apcatb.2019.118160 – ident: ref29/cit29 doi: 10.1016/j.nanoen.2016.10.037 – ident: ref6/cit6 doi: 10.1021/acs.est.5b00729 – ident: ref9/cit9 doi: 10.1016/j.jwpe.2022.103080 – ident: ref16/cit16 doi: 10.1016/j.cej.2017.09.094 – ident: ref33/cit33 doi: 10.1016/j.cej.2021.131403 – ident: ref18/cit18 doi: 10.1016/j.ccr.2022.214811 – ident: ref22/cit22 doi: 10.1016/j.seppur.2019.116322 – ident: ref34/cit34 doi: 10.1007/s11356-021-14248-z – ident: ref14/cit14 doi: 10.1016/j.seppur.2022.121374 – ident: ref20/cit20 doi: 10.1007/s10311-023-01561-x – ident: ref17/cit17 doi: 10.1016/j.jhazmat.2022.130023 – ident: ref31/cit31 doi: 10.1016/j.apcatb.2020.119591 – ident: ref13/cit13 doi: 10.1016/j.cej.2021.129041 – ident: ref10/cit10 doi: 10.1007/s12274-022-4306-6 – ident: ref21/cit21 doi: 10.1016/j.watres.2023.119831 – ident: ref39/cit39 doi: 10.1016/j.talanta.2022.123487 – ident: ref5/cit5 doi: 10.1016/j.scitotenv.2018.01.271 – ident: ref35/cit35 doi: 10.1021/acscatal.9b00016 – ident: ref2/cit2 doi: 10.1016/s1473-3099(20)30332-7 – ident: ref19/cit19 doi: 10.1016/j.cej.2022.137356 – ident: ref36/cit36 doi: 10.1039/d0nr04920d – ident: ref23/cit23 doi: 10.1016/j.seppur.2020.117376 – ident: ref15/cit15 doi: 10.1016/j.jhazmat.2019.121344 – ident: ref44/cit44 doi: 10.1016/j.watres.2017.03.054 – ident: ref8/cit8 doi: 10.1016/j.fct.2019.01.033 – ident: ref32/cit32 doi: 10.1016/j.cej.2018.08.051 – ident: ref12/cit12 doi: 10.1016/j.apcatb.2022.122076 – ident: ref7/cit7 doi: 10.1016/j.watres.2022.119324 – ident: ref43/cit43 doi: 10.1016/j.jhazmat.2021.125162 – ident: ref28/cit28 doi: 10.1016/j.coelec.2020.04.005 – ident: ref42/cit42 doi: 10.1016/j.seppur.2021.119329 – ident: ref3/cit3 doi: 10.1016/j.apcatb.2021.120439 – ident: ref30/cit30 doi: 10.1088/1361-6528/ac530c |
| SSID | ssj0002358178 |
| Score | 2.4872646 |
| Snippet | Chloramphenicol (CAP) is a widely used antibiotic drug and poses a great threat to human health and the ecosystem. In this work, an iron–fluorine–nitrogen... |
| SourceID | crossref acs |
| SourceType | Enrichment Source Index Database Publisher |
| StartPage | 1385 |
| Title | Significantly Enhanced Electrocatalytic Reduction of Chloramphenicol from Water Mediated by Fe–F–N Co-doped Carbon Materials |
| URI | http://dx.doi.org/10.1021/acsestwater.3c00059 |
| Volume | 3 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVABC databaseName: American Chemical Society Journals customDbUrl: eissn: 2690-0637 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0002358178 issn: 2690-0637 databaseCode: ACS dateStart: 20220211 isFulltext: true titleUrlDefault: https://pubs.acs.org/action/showPublications?display=journals providerName: American Chemical Society |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV07T8MwELZ4DLDwRpSXPDAwYEjsvDqiqBVCagcegi062zFFlBTRVqhM_Af-Ib-EuzRFFSDEkCWyHet8uZfvvmPswEgntQoTkVgdiQAUiHqYW-HVdYhS0dnAULyj1Y7OroPz2_B2qlj92w2-9E_A9FE-vgD1jlKmBBSZZfMySnzytU7Ty6-QClV9-qXslejzCVS-8QRn6Pd1SCOZ_pRGmlItzWXWnhTojDNKHo6HA31sXn_iNf5v1ytsqTIy-emYK1bZTF6ssYWq33lntM7eLu_vCkoSQrp2R7xRdMpEAN4YN8UpYzojnMwvCNmVzo73HE876NzDI2WFEf9wKk3hN_Rx3io7fuAKesSb-cfbexOfNk97wvae8HUKzxoXadFg4vgNdt1sXKVnourFIABdsoFAzZ5oh7aWBRPGKASU9FVkXeAFABHU687XaPsZoz2tAgK7hcSpPDEQOtAS1CabK3pFvsW48mxsIIqljVE1Ko0mZuI8rXWUGA9sVGOHSL2s-pf6WXlNLv1siqRZRdIak5Ojy0yFaU6tNbp_Tzr6mvQ0hvT4a_j2_7ezwxapGz0lF_hyl80Nnof5HtosA71fcuonUsbt2w |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1LT8MwDI54HODCG_EmBw4cCLRJXzuiatN4bAdggluVR8MQ0CE2hMaJ_8A_5JdgZ2VMCCE49BI1ruW4tpPYnwnZ0dxyJcKEJUZFLJBCskqYG-ZVVAhW0ZpA43lHoxnVW8HxVXhVFoVhLQww0QVKXXeJ_4Uu4B_AGJjJZ4ktpIR2uCLjZNJhoWBAlJ4PT1aw-NN3JpjD1o-BD44_4YZ-poOOSXdHHNOIh6nNktaQN5dYcrv_1FP7-uUbbON_mZ8jM2XISQ8HOjJPxvJigUyV3c_b_UXyen5zXWDKEEj5rk-rRdulBdDqoEWOO-Hpw2R6hjivuJK0Y2nahq2-vMccMdQmioUq9BI_Thuu_wdQUH1ay99f32rwNGnaYabzAMOpfFRApIEvo_4vkVatepHWWdmZgUnYoPUY-PlEWYi8jNRhDCZBcF9ExgZeIGUkKxXrK4gEtVaeEgFC38rEijzRMrRScSmWyUTRKfIVQoVnYi2jmJsYHKVQEHAm1lNKRYn2pIlWyS5ILyv_rG7mLs25n42INCtFukr45wpmukQ4x0Ybd79P2htOehgAfPz2-trf2dkmU_WLxml2etQ8WSfT2Kce0w58vkEmeo9P-SZEMz215ZT3AwFx9kY |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LTxsxEB5RKlEutNBWPErrAwcONd2195UjWrKij0SIh0pPKz_WDQI2EQlC4cR_4B_2l3TG2URRVaGqh71Y61nv2J4Z2-PvA9gxwgkt44xnVic8UlLxVlxZHrR0jFbR2cjQfkenmxyeRV_O4_MFyKZ3YbARQ5Q09If4NKsH1jUIA-EnLEdTeaeIRkoajy3yDJ7HBAJHQVF-MttdoQugoTfDApd_HP1wOoUc-rscck5mOOec5rxM8RJ-zNrnk0su925Hes_c_wHd-D8_8ApWmtCT7U_GyiosVPUavGhY0Hvj1_BwcvGzptQh1PbVmLXrnk8PYO0JVY7f6RljZXZMeK_Uo6zvWN7DJb-6plwxGlWMLqyw7_Rx1vE8IChBj1lR_Xp4LPDpsrzPbX-Axbm60SikQy_TPHgDZ0X7ND_kDUMDV7hQG3H095l2GIFZZeIUTYMUoUysi4JIqUS1Wi7UGBEaowMtI4LAVZmTVWZU7JQWSr6FxbpfV-vAZGBTo5JU2BQdptQYeGYu0FonmQmUTTZgF7VXNjNsWPrDcxGWcyotG5VugJj2YmkapHMi3Lh6utLHWaXBBOjjqdc3_705H2Dp6KAov33uft2CZaKrp-yDULyDxdHNbbWNQc1Iv_fj9ze1b_jA |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Significantly+Enhanced+Electrocatalytic+Reduction+of+Chloramphenicol+from+Water+Mediated+by+Fe%E2%80%93F%E2%80%93N+Co-doped+Carbon+Materials&rft.jtitle=ACS+ES%26T+water&rft.au=Jin%2C+Wanwan&rft.au=Feng%2C+Jing&rft.au=Xing%2C+Wenle&rft.au=Tang%2C+Wangwang&rft.date=2023-05-12&rft.issn=2690-0637&rft.eissn=2690-0637&rft.volume=3&rft.issue=5&rft.spage=1385&rft.epage=1394&rft_id=info:doi/10.1021%2Facsestwater.3c00059&rft.externalDBID=n%2Fa&rft.externalDocID=10_1021_acsestwater_3c00059 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2690-0637&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2690-0637&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2690-0637&client=summon |