Comparative Study of Solid-Phase Extraction and Liquid−Liquid Extraction for the Reliable Quantification of High Value Added Compounds from Oxidation Processes of Wood-Derived Lignin
Technologies and processes for lignocellulosic conversion in biorefineries are emergent subjects of research for which a reliable analysis of raw materials and quantification of yields of reaction products are required. This paper presents the development of an analytical method, using solid-phase e...
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| Published in | Industrial & engineering chemistry research Vol. 49; no. 23; pp. 12311 - 12318 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Washington, DC
American Chemical Society
01.12.2010
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0888-5885 1520-5045 |
| DOI | 10.1021/ie101680s |
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| Abstract | Technologies and processes for lignocellulosic conversion in biorefineries are emergent subjects of research for which a reliable analysis of raw materials and quantification of yields of reaction products are required. This paper presents the development of an analytical method, using solid-phase extraction (SPE), for application to the reaction mixture of the oxidation of wood-derived lignin. The aim of the method is to extract the high value added aldehydes for quantification by high-performance liquid chromatography with ultraviolet detection (HPLC-UV). SPE and conventional liquid−liquid extraction (LLE) were evaluated and compared concerning recoveries and precision: (i) solutions of standard phenolic compounds (in alkaline medium and in lignin as matrix) and (ii) real samples and spiked real samples. The presence of lignin in the solutions decreases the recoveries of compounds from about 100% (no lignin) to 91% (for prepared solutions of lignin) and 94% (for real samples). This decrease was clearly evident with the increase of concentration of phenolic compounds in spiked real samples. The recovery averages and precision of SPE were higher than those of LLE and less affected by the presence of lignin. The results gathered and discussed in this work revealed SPE as an alternative to LLE: it is less time-consuming and has higher accuracy and precision for the quantification of phenolic compounds as reaction products of lignin oxidation. |
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| AbstractList | Technologies and processes for lignocellulosic conversion in biorefineries are emergent subjects of research for which a reliable analysis of raw materials and quantification of yields of reaction products are required. This paper presents the development of an analytical method, using solid-phase extraction (SPE), for application to the reaction mixture of the oxidation of wood-derived lignin. The aim of the method is to extract the high value added aldehydes for quantification by high-performance liquid chromatography with ultraviolet detection (HPLC-UV). SPE and conventional liquid−liquid extraction (LLE) were evaluated and compared concerning recoveries and precision: (i) solutions of standard phenolic compounds (in alkaline medium and in lignin as matrix) and (ii) real samples and spiked real samples. The presence of lignin in the solutions decreases the recoveries of compounds from about 100% (no lignin) to 91% (for prepared solutions of lignin) and 94% (for real samples). This decrease was clearly evident with the increase of concentration of phenolic compounds in spiked real samples. The recovery averages and precision of SPE were higher than those of LLE and less affected by the presence of lignin. The results gathered and discussed in this work revealed SPE as an alternative to LLE: it is less time-consuming and has higher accuracy and precision for the quantification of phenolic compounds as reaction products of lignin oxidation. |
| Author | da Silva, Eduardo A. Borges Rodrigues, Alírio Egídio Pinto, Paula C. Rodrigues |
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| Cites_doi | 10.1002/jssc.200900306 10.1002/cssc.200800050 10.1023/A:1021070006895 10.1080/02773818408070647 10.1016/j.aca.2009.10.004 10.1080/02773810903207762 10.1007/BF00766789 10.3390/molecules14010298 10.1016/S0021-9673(99)00832-8 10.1002/jctb.280640303 10.1016/j.cherd.2010.01.021 10.1021/ie0601697 10.1021/ac981175i 10.1007/BF02269916 10.1590/S0104-66322004000200010 10.1016/S0021-9673(00)00116-3 10.1016/j.ces.2007.02.018 10.1021/jf00003a012 10.1021/ie950267k 10.1007/BF02274608 10.1021/jf00088a036 10.1016/j.chemosphere.2007.03.025 10.1023/A:1010553118997 10.1021/op010087o 10.1016/S0021-9673(96)00583-3 10.1021/jf0013205 10.1007/978-3-642-74065-7_21 10.1021/ac00239a007 10.1016/j.talanta.2007.01.049 10.1016/j.indcrop.2004.04.022 10.1515/hfsg.1995.49.3.273 10.1007/BF02490996 10.1081/WCT-120013355 10.1081/WCT-120013356 10.1021/jf040466r 10.1016/j.trac.2005.01.012 10.1016/0926-6690(95)00038-0 10.1007/BF00702154 10.1023/B:KICA.0000038087.95130.a5 10.15376/biores.5.3.1509-1516 10.1016/j.cattod.2009.07.016 10.1021/op9900028 10.1002/jssc.200700261 10.1080/02773819708003131 10.1021/ac9600058 10.1007/BF02075847 10.1016/j.jcis.2008.04.005 10.1016/j.cherd.2009.05.008 10.1016/0038-0717(85)90040-9 10.1021/ie970812c 10.1007/s002260100089 |
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| References | Mateos R. (ref44/cit44) 2001; 49 Tarabanko V. E. (ref55/cit55) 2001; 72 Boeriu C. G. (ref3/cit3) 2004; 20 Villar J. C. (ref12/cit12) 2001; 35 Berrueta L. A. (ref38/cit38) 1995; 40 Robert D. (ref53/cit53) 1984; 4 Hennion M. C. (ref39/cit39) 1999; 856 Katahira R. (ref25/cit25) 2001; 47 (ref54/cit54) 2007 Galletti G. C. (ref30/cit30) 1991; 39 Silva A. A. (ref48/cit48) 2009; 32 Lora J. H. (ref2/cit2) 2002; 10 Bjørsvik H. R. (ref18/cit18) 2002; 6 Maman O. (ref36/cit36) 1996; 755 Silva E. A. B. (ref6/cit6) 2009; 87 ref20/cit20 Sjöström E. (ref1/cit1) 1981 Kogel I. (ref28/cit28) 1985; 17 ref21/cit21 Fontanals N. (ref41/cit41) 2005; 24 Galletti G. C. (ref29/cit29) 1989; 37 Fargues C. (ref13/cit13) 1996; 35 Mathias A. L. (ref15/cit15) 1995; 64 Marques A. P. (ref52/cit52) 2009; 29 Lobbes J. M. (ref32/cit32) 1999; 71 Christophoridou S. (ref45/cit45) 2005; 53 Tarabanko V. E. (ref11/cit11) 2004; 45 Santana C. M. (ref43/cit43) 2009; 14 Sales F. G. (ref9/cit9) 2006; 45 Fiehn O. (ref57/cit57) 1996; 68 Gun’ko V. M. (ref56/cit56) 2008; 323 Voitl T. (ref27/cit27) 2008; 1 Sales F. G. (ref8/cit8) 2007; 62 Masselter S. (ref35/cit35) 1995; 40 Villar J. C. (ref34/cit34) 1997; 17 Araújo J. D. P. (ref4/cit4) 2010; 88 Sun R. (ref31/cit31) 1995; 4 Mathias A. L. (ref16/cit16) 1995; 49 Lima D. L. D. (ref37/cit37) 2007; 72 Froass P. M. (ref50/cit50) 1998; 37 Tarabanko V. E. (ref14/cit14) 1995; 55 Gellerstedt G. (ref51/cit51) 1976; 79 Luo L. (ref17/cit17) 1990; 6 Wong Z. (ref5/cit5) 2010; 5 Lobo I. (ref33/cit33) 2002; 52 Araujo J. D. P. (ref7/cit7) 2009; 147 Rodríguez I. (ref40/cit40) 2000; 885 Hedges J. I. (ref24/cit24) 1982; 54 Pinto P. C. (ref26/cit26) 2002; 22 Tarabanko V. E. (ref22/cit22) 1995; 44 Bjørsvik H. R. (ref19/cit19) 1999; 3 Chen C.-L. (ref23/cit23) 1992 Nováková L. (ref42/cit42) 2009; 656 Pinto P. C. (ref49/cit49) 2002; 22 Lima D. L. D. (ref46/cit46) 2007; 69 Sales F. G. (ref10/cit10) 2004; 21 Stalikas C. D. (ref47/cit47) 2007; 30 |
| References_xml | – volume: 32 start-page: 3681 year: 2009 ident: ref48/cit48 publication-title: J. Sep. Sci. doi: 10.1002/jssc.200900306 – ident: ref20/cit20 – volume: 1 start-page: 763 year: 2008 ident: ref27/cit27 publication-title: ChemSusChem doi: 10.1002/cssc.200800050 – volume: 10 start-page: 39 year: 2002 ident: ref2/cit2 publication-title: J. Polym. Environ. doi: 10.1023/A:1021070006895 – volume: 4 start-page: 239 year: 1984 ident: ref53/cit53 publication-title: J. Wood Chem. Technol. doi: 10.1080/02773818408070647 – volume: 656 start-page: 8 issue: 1 year: 2009 ident: ref42/cit42 publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2009.10.004 – volume: 29 start-page: 337 year: 2009 ident: ref52/cit52 publication-title: J. Wood Chem. Technol. doi: 10.1080/02773810903207762 – volume: 47 start-page: 378 year: 2001 ident: ref25/cit25 publication-title: J. Wood Sci. doi: 10.1007/BF00766789 – volume: 14 start-page: 298 year: 2009 ident: ref43/cit43 publication-title: Molecules doi: 10.3390/molecules14010298 – volume: 856 start-page: 3 issue: 1 year: 1999 ident: ref39/cit39 publication-title: J. Chromatogr., A doi: 10.1016/S0021-9673(99)00832-8 – start-page: 1 volume-title: Kirk-Othmer Encyclopedia of Chemical Technology year: 2007 ident: ref54/cit54 – volume: 64 start-page: 225 year: 1995 ident: ref15/cit15 publication-title: J. Chem. Technol. Biotechnol. doi: 10.1002/jctb.280640303 – volume: 88 start-page: 1024 year: 2010 ident: ref4/cit4 publication-title: Chem. Eng. Res. Des. doi: 10.1016/j.cherd.2010.01.021 – volume: 45 start-page: 6627 year: 2006 ident: ref9/cit9 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie0601697 – volume: 71 start-page: 3008 year: 1999 ident: ref32/cit32 publication-title: Anal. Chem. doi: 10.1021/ac981175i – volume: 40 start-page: 474 year: 1995 ident: ref38/cit38 publication-title: Chromatographia doi: 10.1007/BF02269916 – volume-title: Wood Chemistry, Fundamentals and Applications year: 1981 ident: ref1/cit1 – volume: 21 start-page: 211 year: 2004 ident: ref10/cit10 publication-title: Braz. J. Chem. Eng. doi: 10.1590/S0104-66322004000200010 – volume: 885 start-page: 291 issue: 1 year: 2000 ident: ref40/cit40 publication-title: J. Chromatogr., A doi: 10.1016/S0021-9673(00)00116-3 – volume: 62 start-page: 5386 year: 2007 ident: ref8/cit8 publication-title: Chem. Eng. Sci. doi: 10.1016/j.ces.2007.02.018 – volume: 39 start-page: 490 year: 1991 ident: ref30/cit30 publication-title: J. Agric. Food Chem. doi: 10.1021/jf00003a012 – volume: 35 start-page: 28 year: 1996 ident: ref13/cit13 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie950267k – volume: 40 start-page: 51 year: 1995 ident: ref35/cit35 publication-title: Chromatographia doi: 10.1007/BF02274608 – volume: 37 start-page: 985 year: 1989 ident: ref29/cit29 publication-title: J. Agric. Food Chem. doi: 10.1021/jf00088a036 – volume: 69 start-page: 561 year: 2007 ident: ref46/cit46 publication-title: Chemosphere doi: 10.1016/j.chemosphere.2007.03.025 – volume: 72 start-page: 153 year: 2001 ident: ref55/cit55 publication-title: Kinet. Catal. Lett. doi: 10.1023/A:1010553118997 – volume: 6 start-page: 279 year: 2002 ident: ref18/cit18 publication-title: Org. Process Res. Dev. doi: 10.1021/op010087o – volume: 755 start-page: 89 issue: 1 year: 1996 ident: ref36/cit36 publication-title: J. Chromatogr., A doi: 10.1016/S0021-9673(96)00583-3 – volume: 49 start-page: 2185 year: 2001 ident: ref44/cit44 publication-title: J. Agric. Food Chem. doi: 10.1021/jf0013205 – start-page: 301 volume-title: Methods in Lignin Chemistry year: 1992 ident: ref23/cit23 doi: 10.1007/978-3-642-74065-7_21 – volume: 54 start-page: 174 year: 1982 ident: ref24/cit24 publication-title: Anal. Chem. doi: 10.1021/ac00239a007 – volume: 72 start-page: 1404 year: 2007 ident: ref37/cit37 publication-title: Talanta doi: 10.1016/j.talanta.2007.01.049 – volume: 20 start-page: 205 year: 2004 ident: ref3/cit3 publication-title: Ind. Crops Prod. doi: 10.1016/j.indcrop.2004.04.022 – volume: 49 start-page: 273 year: 1995 ident: ref16/cit16 publication-title: Holzforschung doi: 10.1515/hfsg.1995.49.3.273 – volume: 52 start-page: 727 year: 2002 ident: ref33/cit33 publication-title: Chromatographia doi: 10.1007/BF02490996 – ident: ref21/cit21 – volume: 22 start-page: 93 year: 2002 ident: ref26/cit26 publication-title: J. Wood Chem. Technol. doi: 10.1081/WCT-120013355 – volume: 22 start-page: 109 year: 2002 ident: ref49/cit49 publication-title: J. Wood Chem. Technol. doi: 10.1081/WCT-120013356 – volume: 53 start-page: 4667 year: 2005 ident: ref45/cit45 publication-title: J. Agric. Food Chem. doi: 10.1021/jf040466r – volume: 79 start-page: 537 year: 1976 ident: ref51/cit51 publication-title: Sven. Papperstidn. – volume: 24 start-page: 394 year: 2005 ident: ref41/cit41 publication-title: Trends Anal. Chem. doi: 10.1016/j.trac.2005.01.012 – volume: 4 start-page: 241 year: 1995 ident: ref31/cit31 publication-title: Ind. Crops Prod. doi: 10.1016/0926-6690(95)00038-0 – volume: 44 start-page: 367 year: 1995 ident: ref22/cit22 publication-title: Russ. Chem. Bull. doi: 10.1007/BF00702154 – volume: 45 start-page: 569 year: 2004 ident: ref11/cit11 publication-title: Kinet. Catal. doi: 10.1023/B:KICA.0000038087.95130.a5 – volume: 5 start-page: 1509 year: 2010 ident: ref5/cit5 publication-title: Bioresources doi: 10.15376/biores.5.3.1509-1516 – volume: 6 start-page: 53 year: 1990 ident: ref17/cit17 publication-title: Chem. React. Eng. Technol. – volume: 147 start-page: S330 year: 2009 ident: ref7/cit7 publication-title: Catal. Today doi: 10.1016/j.cattod.2009.07.016 – volume: 3 start-page: 330 year: 1999 ident: ref19/cit19 publication-title: Org. Process Res. Dev. doi: 10.1021/op9900028 – volume: 30 start-page: 3268 year: 2007 ident: ref47/cit47 publication-title: J. Sep. Sci. doi: 10.1002/jssc.200700261 – volume: 17 start-page: 259 year: 1997 ident: ref34/cit34 publication-title: J. Wood Chem. Technol. doi: 10.1080/02773819708003131 – volume: 68 start-page: 3083 year: 1996 ident: ref57/cit57 publication-title: Anal. Chem. doi: 10.1021/ac9600058 – volume: 55 start-page: 161 year: 1995 ident: ref14/cit14 publication-title: React. Kinet. Catal. Lett. doi: 10.1007/BF02075847 – volume: 323 start-page: 6 issue: 1 year: 2008 ident: ref56/cit56 publication-title: J. Colloid Interface Sci. doi: 10.1016/j.jcis.2008.04.005 – volume: 87 start-page: 1276 year: 2009 ident: ref6/cit6 publication-title: Chem. Eng. Res. Des. doi: 10.1016/j.cherd.2009.05.008 – volume: 17 start-page: 637 year: 1985 ident: ref28/cit28 publication-title: Soil Biol. Biochem. doi: 10.1016/0038-0717(85)90040-9 – volume: 37 start-page: 3388 issue: 8 year: 1998 ident: ref50/cit50 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie970812c – volume: 35 start-page: 245 year: 2001 ident: ref12/cit12 publication-title: Wood Sci. Technol. doi: 10.1007/s002260100089 |
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| Title | Comparative Study of Solid-Phase Extraction and Liquid−Liquid Extraction for the Reliable Quantification of High Value Added Compounds from Oxidation Processes of Wood-Derived Lignin |
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