Comprehensive Review of P2-Type Na2/3Ni1/3Mn2/3O2, a Potential Cathode for Practical Application of Na-Ion Batteries
P2-type Na2/3Ni1/3Mn2/3O2 is a promising cathode material for practical applications in Na-ion batteries, due to its high energy density, high volumetric capacity, excellent Na ion conductivity, ease of synthesis, and good stability in air. Yet, it is subject to structural rearrangements on charging...
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| Published in | ACS applied materials & interfaces Vol. 11; no. 25; pp. 22051 - 22066 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
26.06.2019
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1944-8244 1944-8252 1944-8252 |
| DOI | 10.1021/acsami.9b03937 |
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| Abstract | P2-type Na2/3Ni1/3Mn2/3O2 is a promising cathode material for practical applications in Na-ion batteries, due to its high energy density, high volumetric capacity, excellent Na ion conductivity, ease of synthesis, and good stability in air. Yet, it is subject to structural rearrangements on charging to high voltage/low Na content and Na+/vacancy ordering transitions, which lead to poor reversibility and dramatic capacity decay upon cycling. In this Review, we present the latest advances related to Na2/3Ni1/3Mn2/3O2, with a main focus on strategies to stabilize the structural framework and improve the electrochemical properties. Practical issues and challenges are also proposed on the basis of current research status and progress. |
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| AbstractList | P2-type Na₂/₃Ni₁/₃Mn₂/₃O₂ is a promising cathode material for practical applications in Na-ion batteries, due to its high energy density, high volumetric capacity, excellent Na ion conductivity, ease of synthesis, and good stability in air. Yet, it is subject to structural rearrangements on charging to high voltage/low Na content and Na⁺/vacancy ordering transitions, which lead to poor reversibility and dramatic capacity decay upon cycling. In this Review, we present the latest advances related to Na₂/₃Ni₁/₃Mn₂/₃O₂, with a main focus on strategies to stabilize the structural framework and improve the electrochemical properties. Practical issues and challenges are also proposed on the basis of current research status and progress. P2-type Na2/3Ni1/3Mn2/3O2 is a promising cathode material for practical applications in Na-ion batteries, due to its high energy density, high volumetric capacity, excellent Na ion conductivity, ease of synthesis, and good stability in air. Yet, it is subject to structural rearrangements on charging to high voltage/low Na content and Na+/vacancy ordering transitions, which lead to poor reversibility and dramatic capacity decay upon cycling. In this Review, we present the latest advances related to Na2/3Ni1/3Mn2/3O2, with a main focus on strategies to stabilize the structural framework and improve the electrochemical properties. Practical issues and challenges are also proposed on the basis of current research status and progress.P2-type Na2/3Ni1/3Mn2/3O2 is a promising cathode material for practical applications in Na-ion batteries, due to its high energy density, high volumetric capacity, excellent Na ion conductivity, ease of synthesis, and good stability in air. Yet, it is subject to structural rearrangements on charging to high voltage/low Na content and Na+/vacancy ordering transitions, which lead to poor reversibility and dramatic capacity decay upon cycling. In this Review, we present the latest advances related to Na2/3Ni1/3Mn2/3O2, with a main focus on strategies to stabilize the structural framework and improve the electrochemical properties. Practical issues and challenges are also proposed on the basis of current research status and progress. P2-type Na2/3Ni1/3Mn2/3O2 is a promising cathode material for practical applications in Na-ion batteries, due to its high energy density, high volumetric capacity, excellent Na ion conductivity, ease of synthesis, and good stability in air. Yet, it is subject to structural rearrangements on charging to high voltage/low Na content and Na+/vacancy ordering transitions, which lead to poor reversibility and dramatic capacity decay upon cycling. In this Review, we present the latest advances related to Na2/3Ni1/3Mn2/3O2, with a main focus on strategies to stabilize the structural framework and improve the electrochemical properties. Practical issues and challenges are also proposed on the basis of current research status and progress. |
| Author | Li, Baohua Wang, Wenhui Zhang, Jiaolong Wang, Wei Wang, Shuwei |
| AuthorAffiliation | Engineering Laboratory for the Next Generation Power and Energy Storage Batteries, Graduate School at Shenzhen Shenzhen Key Laboratory of Organic Pollution Prevention and Control, Environmental Science and Engineering Research Center |
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| Keywords | P2-Na2/3Ni1/3Mn2/3O2 Na+/vacancy ordering surface modification structural transformation cathode cation substitution Na-ion batteries |
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| Snippet | P2-type Na2/3Ni1/3Mn2/3O2 is a promising cathode material for practical applications in Na-ion batteries, due to its high energy density, high volumetric... P2-type Na₂/₃Ni₁/₃Mn₂/₃O₂ is a promising cathode material for practical applications in Na-ion batteries, due to its high energy density, high volumetric... |
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| Title | Comprehensive Review of P2-Type Na2/3Ni1/3Mn2/3O2, a Potential Cathode for Practical Application of Na-Ion Batteries |
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